Characterization,source apportionment and risk assessment of PAHs in urban surface dust in Shenyang city,China

Environmental Geochemistry and Health - Characteristics, profile composition, ecological and human health risk of polycyclic aromatic hydrocarbons in surface dust collected from Shenyang city,...     

Environmental performance evaluation of agro-industrial innovations – part 1: Ambitec-Life Cycle,a methodological approach for considering life cycle thinking

As sustainability considerations increasingly dominate the technology development debate worldwide, practical approaches to assess environmental performance of innovations have been warranted. The present study (Part 1) introduces Ambitec-Life Cycle, a method derived from Ambitec-Agro for considering life cycle thinking in the environmental performance evaluation (EPE) of agro-industrial innovations. An agro-industrial innovation case study related to residue recycling is presented, revealing steps in the product life cycle where opportunities are best for technological improvements. In Part 2 (this issue) of this study, a methodological approach for considering the environmental vulnerability of watersheds and to integrate this analysis in EPE methods is presented. This approach is applied to Ambitec-Life Cycle and to the same residue case study, allowing the identification of performance indicators with greater potential to cause impacts at the studied watersheds.     

RIPARIAN ZONE CLASSIFICATION FOR MANAGEMENT OF STREAM WATER QUALITY AND ECOSYSTEM HEALTH1

ABSTRACT: Riparian zones perform a variety of biophysical functions that can be managed to reduce the effects of land use on instream habitat and water quality. However, the functions and human uses of riparian zones vary with biophysical factors such as landform, vegetation, and position along the stream continuum. These variations mean that “one size fits all” approaches to riparian management can be ineffective for reducing land use impacts. Thus riparian management planning at the watershed scale requires a framework that can consider spatial differences in riparian functions and human uses We describe a pilot riparian zone classification developed to provide such a framework for riparian management in two diverse river systems in the Waikato region of New Zealand. Ten classes of riparian zones were identified that differed sufficiently in their biophysical features to require different management. Generic “first steps” and “best practical” riparian management recommendations and associated costs were developed for each riparian class. The classification aims to not only improve our understanding of the effectiveness of riparian zone management as a watershed management tool among water managers and land owners, but to also provide a basis for deciding on management actions.     

Satellite Rainfall Estimates Over South America – Possible Applicability to the Water Management of Large Watersheds1

Pereira Filho, Augusto J., Richard E. Carbone, John E. Janowiak, Phillip Arkin, Robert Joyce, Ricardo Hallak, and Camila G.M. Ramos, 2010. Satellite Rainfall Estimates Over South America – Possible Applicability to the Water Management of Large Watersheds. Journal of the American Water Resources Association (JAWRA) 46(2):344-360. DOI: 10.1111/j.1752-1688.2009.00406.x Abstract: This work analyzes high-resolution precipitation data from satellite-derived rainfall estimates over South America, especially over the Amazon Basin. The goal is to examine whether satellite-derived precipitation estimates can be used in hydrology and in the management of larger watersheds of South America. High spatial-temporal resolution precipitation estimates obtained with the CMORPH method serve this purpose while providing an additional hydrometeorological perspective on the convective regime over South America and its predictability. CMORPH rainfall estimates at 8-km spatial resolution for 2003 and 2004 were compared with available rain gauge measurements at daily, monthly, and yearly accumulation time scales. The results show the correlation between satellite-derived and gauge-measured precipitation increases with accumulation period from daily to monthly, especially during the rainy season. Time-longitude diagrams of CMORPH hourly rainfall show the genesis, strength, longevity, and phase speed of convective systems. Hourly rainfall analyses indicate that convection over the Amazon region is often more organized than previously thought, thus inferring that basin scale predictions of rainfall for hydrological and water management purposes have the potential to become more skillful. Flow estimates based on CMORPH and the rain gauge network are compared to long-term observed average flow. The results suggest this satellite-based rainfall estimation technique has considerable utility. Other statistics for monthly accumulations also suggest CMORPH can be an important source of rainfall information at smaller spatial scales where in situ observations are lacking.     

Evaluation of Cyto- and Genotoxicity of Poly(lactide-co-glycolide) Nanoparticles

This work reports on an analysis of the cyto- and genotoxicity of poly(lactide-co-glycolide) polymer nanoparticles, in an attempt to evaluate their mutagenic effects. Fibroblast (3T3) and human lymphocyte cell cultures were exposed to solutions containing three different concentrations of nanoparticles (5.4, 54 and 540 μg/mL, polymer mass/volume of solution). The nanoparticles were characterized in terms of their hydrodynamic diameters, zeta potentials and polydispersity indices. The morphology of the particles was determined by atomic force microscopy. The PLGA nanospheres presented a size of 95 nm, a zeta potential of −20 mV and a spherical morphology. Cellular viability assays using fibroblast cells showed no significant alterations compared with the negative control. A cytogenetic analysis of human lymphocyte cells showed no significant changes in the mitotic index in relation to the control, indicating that in the concentration range tested, the particles used in the experimental models did not present cyto- or genotoxicity. For the tests conducted in this work we can conclude that biodegradable and biocompatible PLGA nanospheres are not toxic in the cell cultures tested (fibroblast and lymphocyte cells) and in the range of concentrations employed. The results provide new information concerning the toxic effects of particles produced using PLGA.     

Incorporating connectivity into conservation planning for the optimal representation of multiple species and ecosystem services

Conservation planning tends to focus on protecting species’ ranges or landscape connectivity but seldom both—particularly in the case of diverse taxonomic assemblages and multiple planning goals. Therefore, information on potential trade-offs between maintaining landscape connectivity and achieving other conservation objectives is lacking. We developed an optimization approach to prioritize the maximal protection of species’ ranges, ecosystem types, and forest carbon stocks, while also including habitat connectivity for range-shifting species and dispersal corridors to link protected area. We applied our approach to Sabah, Malaysia, where the state government mandated an increase in protected-area coverage of approximately 305,000 ha but did not specify where new protected areas should be. Compared with a conservation planning approach that did not incorporate the 2 connectivity features, our approach increased the protection of dispersal corridors and elevational connectivity by 13% and 21%, respectively. Coverage of vertebrate and plant species’ ranges and forest types were the same whether connectivity was included or excluded. Our approach protected 2% less forest carbon and 3% less butterfly range than when connectivity features were not included. Hence, the inclusion of connectivity into conservation planning can generate large increases in the protection of landscape connectivity with minimal loss of representation of other conservation targets.     

Identification of redundant air quality measurements through the use of principal component analysis

This study aims to show how principal component analysis (PCA) can be used to identify redundant measurements in air quality monitoring networks. The minimum number of air quality monitoring sites in Oporto Metropolitan Area (Oporto-MA) was evaluated using PCA and then compared to the one settled by the legislation. Nine sites, monitoring NO₂, O₃ and PM₁₀, were selected and the air pollutant concentrations were analysed from January 2003 to December 2005. PCA was applied to the data corresponding to the first two years that were divided into annual quarters to verify the persistence of the PCA results. The number of principal components (PCs) was selected by applying two criteria: Kaiser (PCs with eigenvalues greater than 1) and ODV₉₀ (PCs representing at least 90% of the original data variance). Each pollutant was analysed separately. The two criteria led to different results. Using Kaiser criterion for the eight analysed periods, two PCs were selected in: (i) five periods for O₃ and PM₁₀; and (ii) six periods for NO₂. These PCs had important contributions of the same groups of monitoring sites. The percentage of the original data variance contained in the selected PCs using this criterion was always below 90%. Thus, the results obtained using ODV₉₀ were considered with more confidence. Using this criterion, only five monitoring sites for NO₂, three for O₃ and seven for PM₁₀ were needed to characterize the region. The number of monitoring sites for NO₂ and O₃ was in agreement with what was established by the legislation. However, for PM₁₀, Oporto-MA needed two more monitoring sites. To validate PCA results, statistical models were determined to estimate air pollutant concentrations at removed monitoring sites using the concentrations measured at the remaining monitoring sites. These models were applied to a year's data. The good performance obtained by the models showed that the monitoring sites selected by the procedure presented in this study were enough to infer the air pollutant concentrations in the region defined by the initial monitoring sites. Additionally, the air pollutant analysers corresponding to the redundant measurements can be installed in non-monitored regions, allowing the enlargement of the air quality monitoring network.