Determination of dissolved selenium species in environmental samples

This article reports on the technique for the determination of selenium at ppt level and the procedure for the speciation of dissolved selenium in the environmental samples. By combining the high-performance liquid chromatography (HPLC) and a fluorescent detector (FLD), this technique permits the determination of selenium at 0.001 μg/L for Se(IV) and 0.005 μg/L for Se(VI) and the total concentration of selenium for a sample volume of 20 ml. In the speciation procedure, Se(IV) is firstly determined based on the selectivity of 2, 4 - diaminonaphthalene (DAN), the Se (VI) and the total element concentration are determined after reduced to Se(IV) by boiling in 4 mol/L HCl and by digesting in HNO3-HClO4 mixture, respectively. Discussions are given on the relationship between selenium speciation in waters and soil water extract and solution pH, EH and total organic carbon concentration (TOC).     

南水北调湖北库区水污染防治对策研究

进行了南水北调湖北库区水污染防治对策研究，结果认为，库区主要环境问题是ＣＯＤ及富营养化物质污染，个别河流存在，着汞污染问题，综合整 重点是加强重点工业源ＣＯＤ治理与生活污水集中处理，通过协调上下游关系解决汞污染问题；在工程治理的基础上尚需加强管理，推行总量控制排污许可证制度使库区各河流满足中线工程提出的水质标准。     

新藏公路(新疆段)沿线道路病害及成因初析

新藏公路新疆段横跨塔里木盆地与昆仑山两大地貌单元，沿线泥石流、滑坡、水毁、崩塌、坍塌、碎落、雪害、涎流冰、翻浆和多年冻土等道路病害类型多样，发生频繁，不时断道阻车，严重影响着新藏公路的通行。该段沿线地质构造错综复杂，新构造运动和地震活动强烈，地形起伏大，地貌类型多样，气候条件多变，冰川作用强烈，以及人为不合理的建设活动和现有道路设计标准低、承灾能力差等，促进了各类道路病害的形成和发展。随着全球气候变暖、太阳活动和地震活动的加强，道路病害将进人新的活跃期，防灾形势十分严峻。     

MODIS_NDVI在白洋淀蝗虫害监测中的应用

运用不同年份蝗虫发育过程中的遥感影像。结合实地调查反映资料，研究了MODIS归一化植被指数(NDVI)在监测蝗虫害中的应用。结果表明，该指数不仅能反映芦苇地蝗虫害的是否发生。还能反映不同区域蝗虫害的发生程度。在蝗虫卵孵化期的MODIS—NDVI图像上。指数值介于0．425～0．567的区域为蝗虫最适宜孵化区，高于0．732的区域则不利于蝗虫卵的孵化。这些研究结果为监测和预警农业蝗虫害的发生提供重要的依据。     

不同紫云英基因型对难溶性磷吸收利用的影响

通过石英砂培养试验,研究了不同基因型对紫云英（Astragalus sinicus）吸收和利用难溶性磷酸盐（Al-P和Fe-P）的影响。结果表明,紫云英在不同磷源中的生长性状、生物量以及植株不同部位的吸磷量有很大差异。从株高、茎粗、分枝数性状方面来看,均表现为K-P〉Al-P〉Fe-P〉CK,且两种难溶性磷处理之间差异达到显著或极显著水平。对大多数紫云英基因型来说Al-P的地上部、地下部及总干物质量都显著大于Fe-P,说明紫云英更容易活化和吸收Al-P。闽紫6号和闽紫1号在利用难溶性磷时都显著高于余江大叶和弋江籽。不同紫云英基因型在不同磷源中,地上部、地下部吸磷量及总吸磷量也均表现为K-P〉Al-P〉Fe-P〉CK,即对不同磷源的吸收能力均以K-P最高,Al-P大于Fe-P。闽紫6号和闽紫1号对难溶性磷的吸收量均高于其它3个品种,表明闽紫6号和闽紫1号对难溶性磷具有较强的溶解吸收能力。从植株吸磷量与生物量关系可以看出,紫云英植株地上部、地下部干物质量及总干物质量、鲜质量增加时,植株吸收磷的养分质量分数也随着增加,呈显著正相关。CK和Al-P处理总干物质量与总吸磷量拟合回归关系显著,但对水溶性K-P和Fe-P处理相关回归关系效果不明显,说明紫云英对难溶性磷吸收利用时,对Al-P吸收富集优于Fe-P。     

有机工业废水中常见污染物结构与活性关系专家系统研究

应用专家系统方法对88种有机工业废水中常见污染物的构效关系进行深入研究。结果表明,对学习集中68种化合物的正确分类率达到95％,对其余20种化合物的正确预报率达到90％。并应用量子化学方法对专家系统推理过程中所采用的部分构效关系规律进行解释。     

化学氮肥对蔬菜硝酸盐污染影响的研究

蔬菜是一种容易富集硝酸盐的作物,菜农为了获得高产,而超量施用化学氮肥,致使蔬菜硝酸盐累积量剧增,品质恶化。研究表明：筛选出氯化铵和硫酸铵两种氮肥;施氮剂量每hm²以200kg为临界值;施氮安全始期,以追氮后8天上市为宜;化学氮肥与厩肥、土杂肥配用,能有效控制和降低蔬菜硝酸盐的累积分别达67.4％和45.7％。硝酸盐是亚硝胺的前体物,应减轻其对人体健康的潜在危害,并提高蔬菜品质。     

酸性淋溶对铅锌尾矿金属行为的影响及植物毒性

露天存放的铅锌尾矿受到自身酸化和酸雨的双重影响,从而加剧尾矿对环境的影响。因此,研究尾矿在酸性条件下的重金属行为及其植物毒性,对植物在铅锌尾矿地的自然定居有非常重要的意义。将铅锌尾矿砂装柱,用pH2～7溶液淋溶50天的结果表明,酸度的提高可以显著地增加尾矿砂中重金属（Pb、Zn、Cu和Cd）的溶出。而随着时间的延长,Zn的溶出量明显增高,Pb和Cu的溶出则逐渐降低。在pH值＜3时,Cd的溶出逐渐升高,pH值＞3时,Cd的溶出也呈下降趋势。酸度对重金属溶出的影响由大至小依次为Zn＞Cd＞Cu＞Pb。渗滤液对植物的毒性随着起始淋溶酸度的提高与时间的推移而加剧     

Climate capacity:the measurement for adaptation to climate change

This article proposed the concept of"climate capacity"as a way of measuring human’s adaptiveness to climate change.This article also focused on the related concepts like ecological carrying capacity,water resources carrying capacity,land carrying capacity as well as population carrying capacity.The concept of climate capacity was articulated against a background of global climate and environmental change.Essentially,China’s efforts to adapt to climate change was a matter of improving climate capacity,which is the ecosystem as well as the frequency,the intensity and the scale of human’s social activities that the climatic resources of a particular geographic area were supposed to support.The climate capacity has two components.One is the natural climate capacity,which includes temperature,sunlight,precipitation,extreme climatic events,etc.The other is the derived climate capacity,which includes water resources,land resources,ecological systems,climatic risks,etc.The climate capacity can be developed or be transferred between regions by taking engineering,technology or regime-based adaptive measures.However,these adaptive measures must be implemented under the principle of economic rationalism,ecological integrity,climate protection,and social justice.It is expected that by combining the climate capacity and its threshold value with the assessment of climate change risks,we are able to predict the optimal population carrying capacity and the scale of socioeconomic development,and furthermore,provide policy support for the socioeconomic development strategy and adaptive planning.In the regions with high climate capacity,there is a symbiotic relationship between adaptation and socioeconomic development.But,in the regions with limited climate capacity,irrational development may further damage the environment.Taking the Yangtze River delta,a region with high climate capacity,and a region of Ningxia,a region with limited climate capacity,as illustrative examples,the authors of this article analyzed the policy implications of climate capacity and further made suggestions on the problems of capacitylimited adaptation and development-driven adaptation.This article argued that the concept of climate capacity can not only be used as an analytical instrument of climate change economics,but also it can provide research support for planning regional adaptation and development with climate change impact and risk assessments.     

两座高原水库蓝藻群落结构与微囊藻毒素的分布对比研究

为了了解贵州高原水库蓝藻群落组成特征和微囊藻毒素分布,于2009年10月对贵州高原2座水库——万峰湖和百花湖采样调查。结果表明:万峰湖以蓝藻为主要优势藻,蓝藻中的拟柱孢藻(Cylindrospermopsis sp.)占绝对优势,浮游植物丰度在13.05×104～55.80×104 cells.L-1之间,蓝藻的丰度值占到了总量的82.55%,6个采样点中有3个(大坝、野鸭滩和革布)检出了微囊藻毒素MC-RR,且有1个点(革布)质量浓度超标,另外3个点(坝艾、坝达章和九里堡)未检出;百花湖以蓝藻、绿藻和硅藻共同构成优势藻,蓝藻中的假鱼腥藻(Pseudanabaena limnetica)是主要优势藻,浮游植物丰度在6.16×104～65.00×104 cells.L-1之间,蓝藻的丰度值在总体中所占比例为33.25%,3个采样点(大坝、岩脚寨和码头)均未检出微囊藻毒素。形成2个高原水库蓝藻群落结构和微囊藻毒素分布差异的原因可能是:2个水库中氮、磷营养盐水平不同引起浮游植物群落组成不同,进而导致了微囊藻毒素的分布出现差异。