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691.
Novel catalytic nano-sized materials based on LaCoO(x) perovskite nanoparticles incapsulated in the mesoporous matrix of zirconia were prepared, characterized by physicochemical methods and tested in complete methanol oxidation. LaCoO(x) nanoparticles were prepared inside the mesopores of ZrO(2) by decomposition of bimetallic La-Co glycine precursor complexes. The catalysts have been studied by diffuse-reflectance FTIR-spectroscopy using such probe molecules as CO, CD(3)CN and CDCl(3) to test low-coordinated metal ions. At low temperatures of decomposition of complexes (up to 400°C), low-coordinated Co(3+) ions predominate in the LaCoO(x) nanoparticles, whereas basically Co(2+) ions are found upon increasing the decomposition temperature to 600°C. The novel nano-sized perovskite catalysts exhibit a very high catalytic activity in the abatement of volatile organic compounds present in air, like methanol and light hydrocarbons. 相似文献
692.
Gebbink WA Letcher RJ Burgess NM Champoux L Elliott JE Hebert CE Martin P Wayland M Weseloh DV Wilson L 《Environment international》2011,37(7):1175-1182
In the present study, we identified and examined the spatial trends, sources and dietary relationships of bioaccumulative perfluorinated sulfonate (PFSA; C(6), C(8), and C(10) chain lengths) and carboxylate (PFCA; C(6) to C(15) chain lengths) contaminants, as well as precursor compounds including several perfluorinated sulfonamides, and fluorotelomer acids and alcohols, in individual eggs (collected in 2008) from four gull species [glaucous-winged (Larus glaucescens), California (Larus californicus), ring-billed (Larus delawarensis) and herring (Larus argentatus) gulls] from 15 marine and freshwater colony sites in provinces across Canada. The pattern of PFSAs was dominated by perfluorooctane sulfonate (PFOS; >89% of ΣPFSA concentration) regardless of egg collection location. The highest ΣPFSA concentrations were found in the eggs collected in the urbanized areas in the Great Lakes and the St. Lawrence River area [Big Chicken Island 308 ng/g ww, Toronto Harbour 486 ng/g ww, and Ile Deslauriers (HG) 299 ng/g ww]. Also, eggs from all freshwater colony sites had higher ΣPFSA concentrations, which were significant (p<0.05) in many cases, compared to the marine sites with the exception of the Sable Island colony in Atlantic Canada off the coast of Nova Scotia. C(6) to C(15) chain length PFCAs were detected in the eggs, although the pattern was variable among the 15 sites, where PFUnA and PFTrA dominated the pattern for most colonies. Like the ΣPFSA, the highest concentrations of ΣPFCA were found in the eggs from Big Chicken Island, Toronto Harbour, Ile Deslauriers (HG), and Sable Island, although not all freshwater sites had higher concentrations compared to marine sites. Dietary tracers [δ(15)N and δ(13)C stable isotopes (SIs)] revealed that PFSA and PFCA exposure is colony dependent. SI signatures suggested that gulls from most marine colony sites were exposed to PFCs via marine prey. The exception was the Mandarte Island colony in Pacific British Columbia, where PFSA and PFCA exposure appeared to be via terrestrial and/or freshwater prey consumption. The same was true for the freshwater sites where egg SIs suggested both aquatic and terrestrial prey consumption as the source for PFC exposure depending on the colony. Both aquatic (marine and freshwater) and terrestrial prey are likely sources of PFC exposure to gulls but exposure scenarios are colony-specific. 相似文献
693.
van Wezel AP Morinière V Emke E ter Laak T Hogenboom AC 《Environment international》2011,37(6):1063-1067
The application of engineered nanomaterials increases strongly. Development of analytical techniques and their application to environmental samples is essential for human and environmental risk assessment of the nanoparticles. The objective of this study was to develop a sensitive analytical method to quantify nC(60) in water, using accurate mass screening liquid chromatography-hybrid linear ion trap Orbitrap mass spectrometry. nC(60) can be transformed by oxidation, reduction and photochemical reaction. Therefore, the formation of some transformation products of nC(60) was studied as well. Finally, the developed analytical method was applied to surface water samples from several locations in the Netherlands. The developed method enabled to detect and quantify aqueous concentrations of the summed nC(60) and its transformation products as low as 5 ng/L. It was observed that nC(60) transformation products exceed quantities of the parent C(60). Despite the high sensitivity of the developed method, no nC(60) or transformation products were detected in an array of Dutch surface waters. This might be due to low emissions, losses in the aqueous phase by sedimentation, sorption or further transformation processes. 相似文献
694.
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696.
Thaddeus Chidi Nzeadibe Chukwuedozie K. Ajaero 《Environment, Development and Sustainability》2011,13(1):163-177
Solid waste management (SWM) in many low- and middle-income countries is sometimes driven by the informal sector. Unfortunately,
contributions of the sector to SWM are not acknowledged in many developing countries. This situation often arises from inadequate
awareness and lack of advocacy for these development contributions. This article reports on the impact of a study conducted
by final-year geography undergraduates on the informal waste management sector in Nsukka urban area, Nigeria. The purposes
of this exercise were to stimulate development intervention on behalf of the sector to improve perceptions, attitudes and
performance, to impart a range of development research skills and to expose the students to the business opportunities provided
by SWM and recycling. Informal waste sector workers and government officials responsible for SWM were interviewed, and some
commercial data on recycling operations were collected. Findings of this study indicate that such advocacy initiatives were
effective in increasing students’ awareness of opportunities and interest in working in the informal waste sector to promote
better SWM and development in Nigeria. Lessons from this university case study are also drawn for other developing countries
struggling to achieve the poverty reduction and job creation Millennium Development Goals (MDGs). 相似文献
697.
Julius H. Kotir 《Environment, Development and Sustainability》2011,13(3):587-605
Sub-Saharan Africa has been portrayed as the most vulnerable region to the impacts of global climate change because of its
reliance on agriculture which is highly sensitive to weather and climate variables such as temperature, precipitation, and
light and extreme events and low capacity for adaptation. This article reviews evidence on the scope and nature of the climate
change challenge; and assesses the impact of climate change on agriculture and food security in Sub-Saharan Africa. From the
review, it is apparent that the climate in Africa is already exhibiting significant changes, evident by changes in average
temperature, change in amount of rainfall and patterns and the prevalence of frequency and intensity of weather extremes.
The review also revealed that although uncertainties exist with regards to the magnitude of impacts, climate will negatively
affect agricultural production in Sub-Saharan Africa. Specifically, as result of current and expected climate change, the
area suitable for agriculture, the length of growing seasons and yield potential, particularly along the margins of semi-arid
and arid areas, are expected to decrease. These impacts will affect all components of food security: food availability, food accessibility, food utilisation and food stability and hence increase the risk of hunger in the region. The review thus confirms the general consensus that Sub-Saharan Africa
is the most vulnerable region to climate change. It suggests that, policymakers and development agencies should focus on formulating
and implementing policies and programmes that promote farm level adaptation strategies currently being practiced by farmers
across the region. 相似文献
698.
V. V. Rozhnov E. Yu. Zvychainaya A. N. Kuksin A. D. Poyarkov 《Russian Journal of Ecology》2011,42(6):439-444
Molecular genetic methods were used to perform the species and individual identification of 117 samples of hair and feces
of carnivores collected in natural habitats. The species were identified for 85.5% of the samples. The analysis of the nucleotide
sequences of the cytochrome b mitochondrial gene was used to identify the samples of hair and feces of snow leopards (Uncia uncia, 40%), red foxes (Vulpes vulpes, 48%), wolves (Canis lupus, 6%), and lynx (Lynx lynx, 5%). The analysis of eight microsatellite loci allowed the genotypes of 13 snow leopards to be described. The sex of 11
animals was identified. 相似文献
699.
M. D. Yevdokimenko 《Russian Journal of Ecology》2011,42(3):205-210
Consideration is given to the results of studies on the postfire dynamics of Transbaikal forests, which are formed under conditions
of highly arid climate and extreme pyrological regime. Data are presented on tree die-off and recruitment in naturally burned
forests and in test stands affected by creeping fires differing in intensity. The hydrothermal regime of soils, precipitation
runoff, and its multifactor models are discussed. It is shown that fires aggravate moisture deficiency on mountain slopes,
impair the productivity of tree stands, and cause their digression. The statistics of forest fires and the risk of lightning
fires are analyzed. 相似文献
700.
The states of the populations of five dominant species of predatory mammals living in the area affected by the Kalinin Nuclear
Power Plant (NPP) and in remote districts of Tver’ oblast have been compared. A total of 1120 skulls, including 708 skulls
from the vicinity of the NPP, have been examined. The data on parameters characterizing similarities between the samples,
the degree and structure of intrapopulation diversity, and ontogenetic stability suggest with a high probability that the
Kalinin NPP has no effect on wild populations of predatory mammals. 相似文献