Polychlorinated Biphenyl Recovery Efficiency from Stack Gas and Ambient Air

Polychlorinated biphenyls (PCBs) are now recognized as presenting a severe environmental hazard because of their toxicity and persistence in the environment. High temperature combustion has been shown to be an effective method for destroying these compounds.¹ Unfortunately, few facilities are available for their destruction. As part of a feasibility study to convert a liquid-waste incinerator designed for waste fuel to a PCB waste, the sampling efficiency of toluene filled fritted impingers and Chromosorb 102 filled tubes was evaluated.     

Interaction of chemical cues from fish tissues and organophosphorous pesticides on Ceriodaphnia dubia survival

Cladocera are frequently used as test organisms for assessing chemical and effluent toxicity and have been shown to respond to stimuli and cues from potential predators. In this study, the interactive effects of visual and chemical cues of fish and two organophosphorous pesticides on survival of Ceriodaphnia dubia were examined. A significant chemical cue (homogenized Pimephales promelas) and malathion interaction was observed on C. dubia survival (P = 0.006). Chemical cue and 2.82 microg/L malathion resulted in a 76.0% reduction in survival compared to malathion alone (P < 0.01). Furthermore, potentiation of malathion toxicity varied based on the source of chemical cues (i.e., epithelial or whole body). It is unclear in this study whether these chemical cues elicited a predation-related stress in C. dubia. Future research should examine the mechanism of this interaction and determine what role, if any, stress responses by C. dubia might play in the interaction.     

Controlled application rate of water treatment residual for agronomic and environmental benefits

Water treatment residuals (WTR) are useful soil amendments to control excessive soluble phosphorus (P) in soils, but indiscriminate additions can result in inadequate control or excessive immobilization of soluble P, leading to crop deficiencies. We evaluated the influence of application rates of an Al-WTR and various P-sources on plant yields, tissue P concentrations, and P uptake and attempted to identify a basis for determining WTR application rates. Bahiagrass (paspalum notatum Fluggae) was grown in a P-deficient soil amended with four P-sources at two application levels (N- and P-based rates) and three WTR rates (0, 10, and 25 g kg(-1) oven dry basis) in a glasshouse pot experiment. The glasshouse results were compared with data from a 2-yr field experiment with similar treatments that were surface applied to an established bahiagrass. Soil P storage capacity (SPSC) values increased with application rate of WTR, and the increase varied with sources of P applied. Soil soluble P concentrations increased as SPSC was reduced, and a change point was identified at 0 mg kg(-1) SPSC in the glasshouse and the field studies. A change point was identified in the bahiagrass yields at a tissue P concentration of 2.0 g kg(-1), corresponding to zero SPSC. Zero SPSC was shown to be an agronomic threshold above which yields and P concentrations of plants declined and below which there is little or no yield response to increased plant P concentrations. Applying P-sources at N-based rates, along with WTR sufficient to give SPSC value of 0 mg kg(-1) SPSC, enhanced the environmental benefits (reduced P loss potential) without negative agronomic impacts.     

Land use and energy scenarios affecting the global carbon cycle

Past increase of atmospheric CO₂ involves significant contributions from both fossil and biospheric sources. The latter are controversial, partly because these CO₂ releases may be balanced by accelerated regrowth following clearing of some forests, while others were being converted to agricultural or other nonforest land. A simulation model was used to reconstruct changes since 1860 and project four hypothetical future scenarios of CO₂ injection to 2460. Nineteen compartments and their exchanges of carbon were considered. Areal extents of tropical forests, other wooded ecosystems, and nonforests were incorporated into the model. Rapidly and slowly exchanging pools of carbon per unit area were projected by integrating income-loss differential equations numerically. Estimated cumulative releases of CO₂ from fossil fuels (plus cement) near 120 Pg of carbon (1 Pg = 10¹⁵ g) from 1860 to 1970 were assumed to equal the prompt plus delayed releases due to forest clearing. Limits of exploitable forest area and biomass were evaluated and found to contribute much less future CO₂ than usable fossil fuels. Ultimate release from the latter (7500±2500 Pg C) could increase atmospheric CO₂ manyfold: doubling the assumed 1860 levels as early as (1) the year 2032 for assumed early fossil-use scenarios and (2) the year 2045 for late fossil-use scenarios. Depending on the poorly known parametes that were programmed to constrain the organic production rates, cumulative storage, and the response of plants and soils to enhanced atmospheric CO₂, biospheric storage might reach higher levels for all scenarios than the estimates given here. However, maximizing such storage in real life would require much closer understanding and wiser management of ecosystems than history has shown.     

Factor demand flexibility in the primary aluminium industry: Evidence from stagnating and expanding regions

The purpose of the paper is to analyse and compare short-run factor demand responses to price changes in the primary aluminium industry in Western Europe and the Africa-Middle East (AME) region. We outline a Translog variable cost function model, which is estimated employing a panel data set at the individual smelter level over the time period 1990-2003. The empirical results show evidence of limited - but far from insignificant - price-induced factor demand responses in the short-run. Overall aluminium smelters in the AME-region show evidence of higher estimated short-run own- and cross-price elasticities than their competitors in Western Europe, at least when it comes to labour and electricity demand. One important reason for this result is the greater number of pot lines with slightly different technologies at each smelter as well as the more intense use of the Prebake technology in the AME-region making retrofits in existing plants less costly than in Western Europe. The results also suggest that in both regions the demand for electricity has over time become less sensitive to short-run price changes, while the labour and material demand responses to price changes have increased but only in the AME-region. The liberalisation of the Western European electricity markets in combination with the rigid labour markets in this part of the world suggest that the shift in production capacity from the western world to the AME-region as well as China may continue.     

Benthic macrofaunal compositional variations in the northern Bering Sea

Point sampling of soft-sediment macrofauna provided a regional-scale analysis of species composition, diversity, and demographic distributions in the northern Bering Sea (61°0??C65°30??N Lat) in spring 2006. Taxonomic differences distinguished subregions north and south of St. Lawrence Island (P?<?0.1%). High compositional variability occurred within and between sites, with higher variability among northern sites. One to two species dominated most assemblages, with moderately common or rare species. Ampeliscid amphipods characterized the north, and bivalves the south. Bivalves (Macoma calcarea Gmelin, Nuculana radiata Krause, Ennucula tenuis Montagu) were commonly widespread, in varied abundances and sizes. Overall, the extensive soft-sediment habitat supports a varied fauna composition with location, in species dominance, abundance, and size-class. This spatially heterogeneous regional structure is important in assessing ecosystem performance related to secondary production, biogeochemistry, bioturbation, top predator feeding strategy, recruitment, and in measuring change.     

Policy roots of land degradation in the arid region of the United States: An overview

The roots of land degradation in the arid region of the United States are set firmly in the era of open range conditions that led to the depletion of rangeland resources in the late 19th and early 20th centuries. Upon closure of the open range and establishment of the U.S. Forest Service and the Bureau of Land Management, public lands in the arid region were protected from the classic tragedy of the commons. Private lands, in turn, fell under the stewardship guidance of such organizations as the Soil Conservation Service, the Agricultural Stabilization and Conservation Service, and the Cooperative Extension Service. Despite these institutional protections, arid land degradation continues at an ecologically and socially unacceptable rate. The most likely explanation for this degradation resides in the institutions and public policies that shape and control livestock grazing. Flaws and disincentives endemic to the grazing permit system have encouraged destructive grazing. Federal subsidies to public- and private-land ranchers have encouraged rangeland stocking rates in excess of carrying capacity on economically and ecologically marginal lands and consistently favored unsound land management practices over superior ones. Policy-generated distortions of market forces have lead to unanticipated and environmentally undesirable land use outcomes. Land management, technical support, and educational institutions have also inadvertently contributed to land degradation in the arid region. Reversing the trend of land degradation in an advanced country like the United States demands that we understand the role of public policy in land use outcomes and that we structure future public policies in accordance with the lessons of recent history.