全文获取类型
收费全文 | 677篇 |
免费 | 48篇 |
国内免费 | 152篇 |
专业分类
安全科学 | 33篇 |
废物处理 | 55篇 |
环保管理 | 76篇 |
综合类 | 371篇 |
基础理论 | 77篇 |
污染及防治 | 178篇 |
评价与监测 | 33篇 |
社会与环境 | 24篇 |
灾害及防治 | 30篇 |
出版年
2024年 | 1篇 |
2023年 | 9篇 |
2022年 | 35篇 |
2021年 | 29篇 |
2020年 | 18篇 |
2019年 | 17篇 |
2018年 | 20篇 |
2017年 | 25篇 |
2016年 | 24篇 |
2015年 | 31篇 |
2014年 | 52篇 |
2013年 | 56篇 |
2012年 | 56篇 |
2011年 | 56篇 |
2010年 | 52篇 |
2009年 | 45篇 |
2008年 | 39篇 |
2007年 | 38篇 |
2006年 | 26篇 |
2005年 | 27篇 |
2004年 | 17篇 |
2003年 | 23篇 |
2002年 | 25篇 |
2001年 | 24篇 |
2000年 | 22篇 |
1999年 | 20篇 |
1998年 | 16篇 |
1997年 | 21篇 |
1996年 | 7篇 |
1995年 | 8篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 6篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1978年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有877条查询结果,搜索用时 859 毫秒
271.
The incomplete understanding of the processes which control aquatic nitrous oxide (N2O) production is partially due to a lack of onsite data with which to describe the temporal resolution of N2O production. To help resolve this, we directly measured the N2O saturation (relative to atmospheric partial pressure) on an hourly basis over two survey periods (July and September 2003) in Lake Taihu, a large eutrophic lake in eastern China. July N2O saturations displayed a distinct diurnal pattern, opposite to those observed by others in subtropical streams, but similar to N2O emissions observed from incubated estuarine sediments. Correlative analyses indicate that biogeochemical processes operate as important controls on N2O production over very short time scales. Nitrous oxide production processes are not only regulated by O2 dynamics related to microalgal photosynthesis, but also closely related to organic matter decay at the sediment-water interface. While large-scale changes (approximately 25-fold) in N2O fluxes in Lake Taihu are a function of variable N loading, biogeochemical processes concerning O2 and N transformation at the sediment-water interface have significant (-twofold) impacts on the regulation of N2O production over very short time scales. Further, high temporal resolution research focused on developing a comprehensive understanding of lacustrine N2O production, including natural and anthropogenic loading and biogeochemical transformation processes, is clearly needed. 相似文献
272.
273.
Leakage of saline-alkaline tank waste solutions often creates a serious environmental contamination problem. To better understand the mechanisms controlling the fate of such waste solutions in the Hanford vadose zone, we simulated reactive transport in columns designed to represent local site conditions. The Pitzer ion interaction module was used, with principal geochemical processes considered in the simulation including quartz dissolution, precipitation of brucite, calcite, and portlandite, multi-component cation exchange, and aqueous complexation reactions. Good matches were observed between the simulated and measured column data at ambient temperature ( approximately 21 degrees C). Relatively good agreement was also obtained at high temperature ( approximately 70 degrees C). The decrease of pH at the plume front is examined through formation of secondary mineral phases and/or quartz dissolution. Substantial formation of secondary mineral phases resulting from multi-component cation exchange suggests that these phases are responsible for a decrease in pH within the plume front. In addition, a sensitivity analysis was conducted with respect to cation exchange capacity, selectivity coefficient, mineral assemblage, temperature, and ionic strength. This study could serve as a useful guide to subsequent experimental work, to thermodynamic models developed for the concentrated solutions at high ionic strength and to other types of waste plume studies. 相似文献
274.
在氰基硼氢化钠存在的弱酸性条件下将6-去氧-6-甲酰基-α-环糊精接枝到壳聚糖纤维上,制备了α-环糊精接枝壳聚糖纤维.测定了不同温度和时间下,α-环糊精接枝壳聚糖纤维对对硝基酚(PNP)的包合吸附与释放性能,及其包合稳定性常数和热力学参数.结果表明,α-环糊精接枝壳聚糖纤维是一种高效的PNP分离剂,对PNP具有良好的分子识别、包合吸附和释放性能,其PNP包合吸附容量可达到2.93 mg/g,318 K时PNP释放度可达到70%左右,并可反复包合吸附与释放;该包合反应为放热反应,分子间的范德华力起主导作用;包合物的稳定性受温度影响较大,低于298 K时较稳定,318 K时PNP释放达到平衡;在同一温度下,PNP释放度随时间的增加而提高. 相似文献
275.
276.
In order for local community views to be incorporated into new development initiatives, their perceptions need to be clearly understood and documented in a format that is readily accessible to planners and developers. The current study sought to develop a predictive understanding of how the Punan Pelancau community, living in a forested landscape in East Kalimantan, assigns importance to its surrounding landscapes and to present these perceptions in the form of maps. The approach entailed the iterative use of a combination of participatory community evaluation methods and more formal modeling and geographic information system techniques. Results suggest that landscape importance is largely dictated by potential benefits, such as inputs to production, health, and houses. Neither land types nor distance were good predictors of landscape importance. The grid-cell method, developed as part of the study, appears to offer a simple technique to capture and present the knowledge of local communities, even where their relationship to the land is highly complex, as was the case for this particular community. 相似文献
277.
The adsorption/desorption behavior of copper and cadmium on soils was investigated in this study. The adsorption isotherm of copper and cadmium conformed to Langmuir equation better than Freundlich equation. The effect of ionic strength, pH, and organic acid, including ethylenediamine tetraacetic disodium acid salt (EDTA), citric acid, oxalic acid and tartaric acid, on the desorption of copper and cadmium was studied. The desorption of copper and cadmium increased with the increase of ionic strength, while the desorption decreased with the rise of pH. The desorption of copper and cadmium enhanced by organic acids was influenced by pH. EDTA showed excellent enhancement on the desorption of both copper and cadmium; citric acid demonstrated great enhancement on the desorption of copper but negligible enhancement on the desorption of cadmium; oxalic acid enhanced the desorption of copper only at pH around 6.4 and enhanced the desorption of cadmium in the pH range from 6.4 to 10.7; tartaric acid slightly enhanced the desorption of copper but negligibly enhanced the desorption of cadmium. The desorption mechanism in the presence of organic acids were explained as the competition of complexation, adsorption and precipitation. The net effect determined the desorption efficiency. This study provided guidance for the selection of organic acids to enhance the electrokinetic (EK) remediation of copper and cadmium from contaminated soils. 相似文献
278.
毛乌素沙漠东部边缘中β尺度暴雨和冰雹综合分析 总被引:2,自引:1,他引:1
利用多普勒雷达资料、Micaps系统提供的常规观测资料和物理量场,对2006年9月20日发生在毛乌素沙漠东部边缘的一次强对流天气过程进行了分析。结果表明:冰雹和暴雨是由两块呈块状的中β尺度强对流单体造成的;地面能量比中α尺度"Ω"系统的生成,为能量的积聚和集中释放提供了有利条件;地面能量比中β尺度能量比低值舌的生成,为强对流天气的发生提供了抬升触发机制;冰雹和暴雨发生前,涡度场和散度场的耦合、影响雹暴区次级环流的形成,为雹暴的发生维持提供了动力机制;850 hPa等压面上湿正压场和湿斜压场的配合、以及湿位涡的三维空间结构,对雹暴的发生及落区有指示意义;在多普勒雷达径向速度场上,雹暴运动的前方对流层低层有中气旋生成,雹暴运动的后方对流层低层有中反气旋生成,而对流层中高层有辐散生成,且超级单体特征明显。 相似文献
279.
在西部大开发中 ,能源占有举足轻重的作用。我国西部的塔里木、准噶尔、吐 -哈、柴达木、鄂尔多斯、四川等六大含油气盆地含有丰富的天然气资源 ,储量大于 5 0 0× 10 8m3的 9个大气田中 ,西部就占 7个。中国天然气预测资源总量为 38× 10 12 m3,其中西部天然气预测资源量为 2 2 .4× 10 12 m3,占天然气预测资源总量的 5 8.9%。仅就西部的塔里木盆地而言 ,剩余可采储量为 3397× 10 8m3,按年产 12 0× 10 8m3计算 ,储采比为 2 8,塔里木盆地天然气有动态稳产 30年的储量保证 ,这对于“西气东输”工程的实施、西部经济的腾飞和可持续发展具有重要意义 相似文献
280.