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891.
公共事务的积累只是为制度化解决提供了必要性,当政者维护政权的根本利益需要决定了公共事务处理的优先序列。客观问题的属性和解决的迫切程度只有在政府最高层统治集团认为维系权力存续的手段具备充分的支撑条件时,才会愿意在正式制度上进行调整,为解决问题提供制度供给。新中国成立后很长一段时间内,我国环境问题并不突出,中央政府根据社会主要矛盾需要制定了以发展经济为重心的制度体系。这种制度结构使地方政府和辖区企业形成了利益共容关系。为适应竞争的需要,地方政府庇护辖区企业环境行为,机会主义地执行环境管理制度,使环境问题积累成为影响安全价值的显著因素。在国内外政治压力下,中央政府最终做出了战略调整,地方政府在中央政府制度调控下,自发地合作治理环境问题。 相似文献
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893.
Yabusaki SB Fang Y Williams KH Murray CJ Ward AL Dayvault RD Waichler SR Newcomer DR Spane FA Long PE 《Journal of contaminant hydrology》2011,126(3-4):271-290
Three-dimensional, coupled variably saturated flow and biogeochemical reactive transport modeling of a 2008 in situ uranium bioremediation field experiment is used to better understand the interplay of transport and biogeochemical reactions controlling uranium behavior under pulsed acetate amendment, seasonal water table variation, spatially variable physical (hydraulic conductivity, porosity) and geochemical (reactive surface area) material properties. While the simulation of the 2008 Big Rusty acetate biostimulation field experiment in Rifle, Colorado was generally consistent with behaviors identified in previous field experiments at the Rifle IFRC site, the additional process and property detail provided several new insights. A principal conclusion from this work is that uranium bioreduction is most effective when acetate, in excess of the sulfate-reducing bacteria demand, is available to the metal-reducing bacteria. The inclusion of an initially small population of slow growing sulfate-reducing bacteria identified in proteomic analyses led to an additional source of Fe(II) from the dissolution of Fe(III) minerals promoted by biogenic sulfide. The falling water table during the experiment significantly reduced the saturated thickness of the aquifer and resulted in reactants and products, as well as unmitigated uranium, in the newly unsaturated vadose zone. High permeability sandy gravel structures resulted in locally high flow rates in the vicinity of injection wells that increased acetate dilution. In downgradient locations, these structures created preferential flow paths for acetate delivery that enhanced local zones of TEAP reactivity and subsidiary reactions. Conversely, smaller transport rates associated with the lower permeability lithofacies (e.g., fine) and vadose zone were shown to limit acetate access and reaction. Once accessed by acetate, however, these same zones limited subsequent acetate dilution and provided longer residence times that resulted in higher concentrations of TEAP reaction products when terminal electron donors and acceptors were not limiting. Finally, facies-based porosity and reactive surface area variations were shown to affect aqueous uranium concentration distributions with localized effects of the fine lithofacies having the largest impact on U(VI) surface complexation. The ability to model the comprehensive biogeochemical reaction network, and spatially and temporally variable processes, properties, and conditions controlling uranium behavior during engineered bioremediation in the naturally complex Rifle IFRC subsurface system required a subsurface simulator that could use the large memory and computational performance of a massively parallel computer. In this case, the eSTOMP simulator, operating on 128 processor cores for 12h, was used to simulate the 110-day field experiment and 50 days of post-biostimulation behavior. 相似文献
894.
A rapid and high-throughput quantum dots bioassay for monitoring of perfluorooctane sulfonate in environmental water samples 总被引:1,自引:0,他引:1
Zhang J Wan Y Li Y Zhang Q Xu S Zhu H Shu B 《Environmental pollution (Barking, Essex : 1987)》2011,159(5):1348-1353
Currently HPLC/MS is the state of the art tool for environmental/drinking water perfluorooctane sulfonate (PFOS) monitoring. PFOS can bind to peroxisomal proliferator-activated receptor-alpha (PPARα), which forms heterodimers with retinoid X receptors (RXRs) and binds to PPAR response elements. In this bioassay free PFOS in water samples competes with immobilized PFOS in ELISA plates for a given amount of PPARα-RXRα. It can be determined indirectly by immobilizing PPARα-RXRα-PFOS complex to another plate coated with PPARα antibody and subsequent measuring the level of PPARα-RXRα by using biotin-modified PPARα-RXRα probes-quantum dots-streptavidin detection system. The rapid and high-throughput bioassay demonstrated a detection limit of 2.5 ng L−1 with linear range between 2.5 ng L−1 and 75 ng L−1. Detection results of environmental water samples were highly consistent between the bioassay and HPLC/MS. 相似文献
895.
Naile JE Khim JS Wang T Wan Y Luo W Hu W Jiao W Park J Ryu J Hong S Jones PD Lu Y Giesy JP 《Environmental pollution (Barking, Essex : 1987)》2011,159(4):907-917
Polychlorinated-dibenzo-p-dioxins and -dibenzofurans (PCDD/Fs) were measured in soils and sediments from the Yellow Sea region. Korean soils and sediments mostly contained detectable PCDD/Fs and showed a widespread distribution among locations. Soil and sedimentary PCDD/Fs from China were comparable to or less than those in Korea. The patterns of relative concentrations of individual congeners in soils were different between the two countries, but similar in sediments. Sources of PCDD/Fs in China and Korea were found to be independent of each other and their distributions reflected matrix-dependent accumulation. Spatial distribution indicated some point sources in Korea while Chinese sources were more widespread and diffuse. PCDD/Fs measured in the coastal areas of the Yellow Sea were comparable to or less than those previously reported in for eastern Asia. However, ∑TEQs in soils and sediments were near to or, in some cases exceeded environmental quality guidelines. 相似文献
896.
Wu R Ma G Long Y Yu J Li S Jiang H 《Environmental science and pollution research international》2011,18(5):800-810
Purpose
The performance of nature reserves depends on the degree to which they represent a region's full biodiversity. Here, we conducted a study on Hainan Island, China, to assess how well Hainan's biodiversity features were captured by existing nature reserves. We also explored the driving forces behind the current protection pattern so as to provide guidelines for improving the island's conservation system. 相似文献897.
在两点进水的条件下采用A2/O工艺处理化工园区废水厌氧水解出水,分析配水比对A2/O工艺处理效果的影响,以及在最优配水条件下,各类A2/O工艺处理废水的实际效果。结果表明,在厌氧段-缺氧段的配水比为30%~70%时,A2/O工艺的处理效果最好。在两点进水条件下的各类A2/O工艺中,倒置A2/O和改良A2/O比常规A2/O工艺具有更好的废水处理效果。 相似文献
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899.
900.
以钛酸四丁酯为钛源,硫脲为掺硫前驱物,采用聚乙二醇辛基苯基醚(Triton X-100)/正己醇/环己烷/氨水的微乳液体系合成了掺硫的纳米TiO2粉体;对其结构进行了表征,以甲基橙为目标降解物考察了其光催化性能.烧结温度通过影响TiO2的晶型转变和颗粒尺寸来影响其光催化性能,随着烧结温度的升高,TiO2的光催化性能先是... 相似文献