全文获取类型
收费全文 | 144篇 |
免费 | 9篇 |
国内免费 | 51篇 |
专业分类
安全科学 | 7篇 |
废物处理 | 8篇 |
环保管理 | 18篇 |
综合类 | 72篇 |
基础理论 | 35篇 |
污染及防治 | 39篇 |
评价与监测 | 9篇 |
社会与环境 | 7篇 |
灾害及防治 | 9篇 |
出版年
2023年 | 2篇 |
2022年 | 3篇 |
2021年 | 7篇 |
2020年 | 3篇 |
2019年 | 4篇 |
2018年 | 7篇 |
2017年 | 10篇 |
2016年 | 7篇 |
2015年 | 7篇 |
2014年 | 14篇 |
2013年 | 9篇 |
2012年 | 12篇 |
2011年 | 19篇 |
2010年 | 10篇 |
2009年 | 9篇 |
2008年 | 5篇 |
2007年 | 9篇 |
2006年 | 8篇 |
2005年 | 3篇 |
2004年 | 8篇 |
2003年 | 9篇 |
2002年 | 4篇 |
2001年 | 7篇 |
2000年 | 1篇 |
1999年 | 3篇 |
1998年 | 2篇 |
1997年 | 6篇 |
1996年 | 7篇 |
1995年 | 4篇 |
1993年 | 1篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1987年 | 1篇 |
排序方式: 共有204条查询结果,搜索用时 31 毫秒
71.
72.
Determination of polybrominated diphenyl ethers (PBDEs) in fish samples from rivers and estuaries in Taiwan 总被引:2,自引:0,他引:2
Polybrominated diphenyl ethers (PBDEs) have been used extensively over the past two decades as flame retardants in many types of polymers, and have been found to be a class of contaminants of concern. Measurements of PBDEs in various environmental matrices from Sweden, Holland, Japan, North America, and elsewhere have been reported. We report data of PBDEs in fish samples taken from six rivers and three estuaries in Taiwan. Seven PBDE congeners were observed in all sixty samples. BDE-47 was found to be the dominant congener in all waters, and BDE-154 contributed more than BDE-99 and BDE-100. Nonetheless, BDE-154 and BDE-183 were the predominant congeners in some species studied. These results are somewhat different from those from other countries, where the pattern is typically BDE-47 > 99 >100 >154, 153, and is postulated to be due to the extensive use of octa-BDE rather than penta-BDE in Taiwan. The average concentration distribution across all samples of the sum of PBDE congeners ranged from 30.6 ng/g lipid to 281 ng/g lipid. The concentrations of PBDEs in fishes reported here are higher than those reported from European countries, but lower than those from the United States. 相似文献
73.
Copper uptake by four Elsholtzia ecotypes supplied with varying levels of copper in solution culture 总被引:5,自引:0,他引:5
The effects of copper (Cu) on the yield and Cu uptake of three ecotypes of Elsholtzia splendens and one of Elsholtzia argyi were studied using solution culture. Three Cu concentrations were compared: 0.31 (control), 50 and 100 micromol L(-1). Although E. argyi took up more Cu in the aboveground parts, typical visual symptoms of Cu toxicity appeared when the plants grew in 50 and 100 micromol Cu L(-1). In contrast, plants from all three populations of E. splendens showed high Cu tolerance and substantial shoot Cu accumulation of 58-144 mg kg(-1). Shoot Cu concentrations were about 16-27 times higher than root Cu concentrations. Root-to-shoot ratio of the E. argyi ecotype was halved when Cu was supplied at a level of 100 mg L(-1) compared to the control (0.31 mg L(-1)) but the ratio increased by 6-47% in the three E. splendens ecotypes. The increase in root-to-shoot ratio in E. splendens may be a mechanism by which the plants can tolerate high Cu concentrations. There were few differences in morphology among the three E. splendens ecotypes in response to added Cu. The results are discussed in relation to the possible use of E. splendens as a pioneer species in the phytostabilization of Cu-contaminated soils. 相似文献
74.
本文论述了中国水利水电工程开发与区域可持续发展的关系,并提出了中国实现可持续的水利水电工程开发的主要对策。 相似文献
75.
76.
Watering techniques and zero-valent iron biochar pH effects on As and Cd concentrations in rice rhizosphere soils, tissues and yield 总被引:1,自引:0,他引:1
Md Shafiqul Islam Yali Chen Liping Weng Jie M Zulqarnain Haider Khan Zhongbin Liao Abdoul Salam Issiaka Abdoul Magi Yongtao Li 《环境科学学报(英文版)》2021,33(2):144-157
Zero-valent iron amended biochar (ZVIB) has been proposed as a promising material in immobilizing heavy metals in paddy fields. In this study, the impacts of pH of ZVIB (pH 6.3 and pH 9.7) and watering management techniques (watering amount in the order of CON (control, 5/72)>3/72>1–3/72>3/100>1/72, with 5/72, for example, representing irrigation given to 5 cm above soil surface in 72 hr regular interval) on As and Cd bioavailability for rice and its grain yield (YieldBR) were investigated in a pot experiment. Brown rice As (AsBR) content was irrelative to the watering treatments, while significantly decreased (>50%) with the addition of both ZVIB materials. The diminutions of brown rice Cd (CdBR) content as well as the YieldBR were highly dependent on both the soil amendment materials’ pH and watering amount. Among all the watering treatments, 3/72 treatment (15% less irrigation water than the CON) with ZVIB 6.3 amendment was the optimum fit for simultaneous reduction of AsBR (50%) and CdBR contents (19%) as well as for significant increment (12%) of the YieldBR. Although high pH (9.7) ZVIB application could also efficiently decrease As and Cd contents in brown rice, it might risk grain yield lost if appropriate (e.g. 3/72 in our study) watering management technique was not chosen. Therefore, ZVIB would be an environmentally friendly option as an amendment material with proper selection of watering management technique to utilize As and Cd co-contaminated arable soils safely for paddy cultivation. 相似文献
77.
Selective catalytic reduction(SCR) with urea catalyzed by Cu-SAPO-34 is an effective method to eliminate NO_x from diesel exhaust. However, urea-related deposits may form during cold-start and urban driving due to low exhaust temperatures. The activity of CuSAPO-34 at 175°C is significantly degraded by urea exposure, and 300°C is required for regeneration. Through in-situ diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS) and temperature-programmed hydrolysis studies, the dominant stable deposit at 175°C is identified as biuret, which can be eliminated at 300°C. The urea-derived deactivation and regeneration mechanisms of Cu-SAPO-34 were compared with those of anatase-supported catalysts. 相似文献
78.
The catalytic activity and durability of Rh/ZrO_2 catalyst were investigated compared with Rh/Al_2O_3 catalyst under diverse aging atmospheres, including lean, rich and lean–rich cyclic aging atmospheres, to simulate the real working conditions of three-way catalyst.Oxidation states and microstructures of rhodium species were investigated to correlate with the catalytic performance of the catalysts. The catalytic performance and durability of the Rh catalyst under diverse aging atmospheres were drastically enhanced by ZrO_2 support. ZrO_2 support was confirmed to be able to effectively inhibit rhodium sintering even under diverse aging conditions. It can also successfully keep Rh species in an active low-valence state on the surface of the catalyst. The superiority of ZrO_2 support compared to Al_2O_3 was verified by the Rh-based monolith catalyst. 相似文献
79.
Nathan Dunkin ShihChi Weng Joseph G. Jacangelo Kellogg J. Schwab 《Food and environmental virology》2017,9(4):473-486
One key assumption impacting data quality in viral inactivation studies is that reduction estimates are not altered by the virus seeding process. However, seeding viruses often involves the inadvertent addition of co-constituents such as cell culture components or additives used during preparation steps which can impact viral reduction estimates by inducing non-representative oxidant demand in disinfection studies and fouling in membrane assessments. The objective of this study was therefore to characterize a mammalian norovirus surrogate, murine norovirus (MNV), and bacteriophage MS2 at sequential stages of viral purification and to quantify their potential contribution to artificial oxidant demand and non-representative membrane fouling. Our results demonstrate that seeding solvent extracted and 0.1 micron filtered MNV to ~105 PFU/mL in an experimental water matrix will result in additional total organic carbon (TOC) and 30 min chlorine demand of 39.2 mg/L and 53.5 mg/L as Cl2, respectively. Performing sucrose cushion purification on the MNV stock prior to seeding reduces the impacts of TOC and chlorine demand to 1.6 and 0.15 mg/L as Cl2, respectively. The findings for MNV are likely relevant for other mammalian viruses propagated in serum-based media. Thus, advanced purification of mammalian virus stocks by sucrose cushion purification (or equivalent density-based separation approach) is warranted prior to seeding in water treatment assessments. Studies employing bacteriophage MS2 as a surrogate virus may not need virus purification, since seeding MS2 at a concentration of ~106 PFU/mL will introduce only ~1 mg/L of TOC and ~1 mg/L as Cl2 of chlorine demand to experimental water matrices. 相似文献
80.
Potassium-modified ceria-zirconia catalyst was synthesized by wetness impregnation method.The ageing treatment was performed in static air at 800°C for 20 hr to evaluate the thermal stability of the catalyst.The catalysts were characterized by X-ray diffraction,BET surface area,oxygen storage capacity,NOx-temperature programmed desorption and soot-temperature programmed oxidation measurements.By introduction of potassium,the maximum soot oxidation rate temperature(Tm) of the ceria-zirconia based catalyst de... 相似文献