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171.
Ferric citrate-induced photodegradation of dyes in aqueous solutions   总被引:1,自引:0,他引:1  
Deng Nansheng  Wu Feng  Luo Fan  Xiao Mei 《Chemosphere》1998,36(15):3101-3112
The photooxidation of dye solutions containing Fe(III)-citrate complexes was studied. The photodegradation under near-UV light of the five dyes, C. I. reactive red 2, C. I. reactive blue 4, C. I. reactive black 8, C. I. basic red 13 and C. I. basic yellow 2, in aqueous solutions at pH2.0 containing Fe(III)-citrate complexes was found to follow pseudo-first order kinetics. The photodegradation rates of the dye, C. I. reactive red 2, decreased with increasing the initial dye concentration in range of 20 – 60 mg/L . A comparatively higher photodegradation efficiency of the dye was gained under the condition of pH2.0 and the Fe(III) to citrate ratio 1:2.  相似文献   
172.
还原铁粉/紫外光体系对活性艳红X-3B溶液的脱色   总被引:8,自引:0,他引:8  
研究了在紫外杀菌灯(λmax=253.7nm,30W)照射下,添加还原铁粉的活性艳红X-3B水溶液的脱色作用。当pH=3.5,铁粉投加量为2.0g/L时,20mg/L活性艳红X-3B溶液在光照180min后的脱色率为79%。脱色为动力学零级反应。染料溶液的pH、铁粉投加量、活性艳红初始浓度对脱色有影响。初步探讨了脱色反应的机理。  相似文献   
173.
龙口褐煤对Ni^2+,Mn^2+,Hg^2+等重金属离子的吸附特性   总被引:5,自引:0,他引:5  
邓昌亮  王鲁敏 《环境化学》1999,18(2):178-182
本文以龙口褐煤作吸附剂,对重金属离子Ni^2,Mn^2+,Hg^2+的单组分水溶液进行吸附研究,探讨了吸附剂的吸附性能,影响吸附的因素和吸附机理。结果表明:褐煤对Ni^2+,Mn^2+,Hg^2+的吸附均表现出Langmuir特征,PH值是影响吸附的一个重要因素。  相似文献   
174.
Environmental Chemistry Letters - About one tenth of humans are impacted by water shortages around the globe. Water resilience is worsening under climate change because intensifying weather...  相似文献   
175.
Drying experiments of dewatered sewage sludge (DSS) were conducted on a agitated paddle dryer, and the effects of additive agents, i.e., CaO, pulverized coal (PC), heavy oil (HO), and dried sludge ("DS" through back mixing) on the agitated drying characteristics of DSS were investigated. The results indicated that CaO can significantly increase the drying rate of DSS. The drying rate at CaO/DSS (mass ratio) = 1/100 was 135% higher than that of CaO/DSS = 0. Pulverized coal has no obvious effect on drying rate, but the increase of PC/DSS can promote breaking up of sludge lump. Heavy oil was found to be slightly effective in improving the drying rate of DSS in the examined experimental range of HO/DSS = 0-1/20. It is also found thatHOcan reduce the torque of the dryer shaft, due to its lubrication effect. Back mixing of DS was found to be effective in alleviating the unfavorable effect of the lumpy phase by improving the mixing effect of the paddle dryer. There was a marked increase of drying rate with an increase of the DS/DSS in the experimental range of DS/DSS = 0-1/3.  相似文献   
176.
The electrokinetic removal of chromium and copper from contaminated soils by adding lactic acid in cathode chamber as an enhancing reagent was evaluated. Two sets of duplicate experiments with chromium contaminated kaolinite and with a silty soil sampled from a supeffund site in Califomia of USA and polluted by Cr and Cu, were carried out in a constant current mode. Changes of soil water content and soil pH before and after the electrokinetic experiments, and variations of voltage drop and electroosmosis flow during the treatments were examined. The results indicated that Cr, spiked as Cr(Ⅵ) in the kaolinite, was accumulated mainly in the anode chamber, and some of Cr and metal hydroxides precipitated in the soil sections in contact with the cathode, which significantly increased electrical energy consumption. Treatment of the soil collected from the site showed accumulation of large amounts of Cr and Cu in the anode chamber while none was detected in the cathode one. The results suggested that the two metals either complexed with the injected lactic acid at the cathode or existed as negatively charged complex, and electromigrated toward the anode under a voltage gradient.  相似文献   
177.
邓万涛  黄典剑 《安全》2010,31(6):1-2
突发事件应对工作,是关系国家经济社会发展全局和人民群众生命财产安全的大事,是全面贯彻落实科学发展观、构建社会主义和谐社会的重要内容。《中华人民共和国突发事件应对法》为处置突发事件提供了法律依据,标志着应急管理工作步入法制化轨道。为了增强突发事件的应对能力,  相似文献   
178.

Microbial communities are important for high composting efficiency and good quality composts. This study was conducted to compare the changes of physicochemical and bacterial characteristics in composting from different raw materials, including chicken manure (CM), duck manure (DM), sheep manure (SM), food waste (FW), and vegetable waste (VW). The role and interactions of core bacteria and their contribution to maturity in diverse composts were analyzed by advanced bioinformatics methods combined sequencing with co-occurrence network and structural equation modeling (SEM). Results indicated that there were obviously different bacterial composition and diversity in composting from diverse sources. FW had a low pH and different physiochemical characteristics compared to other composts but they all achieved similar maturity products. Redundancy analysis suggested total organic carbon, phosphorus, and temperature governed the composition of microbial species but key factors were different in diverse composts. Network analysis showed completely different interactions of core bacterial community from diverse composts but Thermobifida was the ubiquitous core bacteria in composting bacterial network. Sphaerobacter and Lactobacillus as core genus were presented in the starting mesophilic and thermophilic phases of composting from manure (CM, DM, SM) and municipal solid waste (FW, VW), respectively. SEM indicated core bacteria had the positive, direct, and the biggest (>?80%) effects on composting maturity. Therefore, this study presents theoretical basis to identify and enhance the core bacteria for improving full-scale composting efficiency facing more and more organic wastes.

  相似文献   
179.
Environmental Science and Pollution Research - To explore the mechanism of Phanerochaete chrysosporium (P. chrysosporium) inoculation driving the humification process of maize straw composting, the...  相似文献   
180.
厌氧工艺对含铬(Ⅵ)废水处理效果初探   总被引:2,自引:0,他引:2  
以砂石和活性炭作为填料,自制厌氧生物滤床系统,并对系统进行驯化,发现完成驯化后的稳定系统具有良好的去铬(Ⅵ)能力.废水在系统中经过2 h运行,加入碳源的试验组与不加碳源的对照组的铬(Ⅵ)去除率分别为87.33%和66.31%.恒流泵最佳流量为47 mL/min,外加碳源后,铬(Ⅵ)的浓度由60 mg/L左右降到0.5 mg/L以下,需要4 h,而对照组需要14 h,铬(Ⅵ)浓度由64.66 mg/L提高到 75.53 mg/L时,对本系统负面影响甚微,提高到95.47 mg/L时,系统出水达标所需时间延长到7.5 h.本系统具有耐受一定程度的浓度冲击以及进一步驯化、提高处理负荷的潜力.  相似文献   
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