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591.
Demonstrating Contaminant Degradation at an MGP Site With Metabolic Gas Flux and Radio Carbon Dating 下载免费PDF全文
Sean M. Carroll Aaron D. Peacock Julio Zimbron Kenneth N. Alepidis Jeffrey A. Clock 《补救:环境净化治理成本、技术与工艺杂志》2017,27(2):51-64
Obtaining lines of evidence indicating that contamination in sediment environments is degrading and being transformed to less toxic forms is an important component of building support for a monitored natural recovery remedy for contaminated sediments. This project was a field demonstration of manufactured gas plant contaminant degradation in river sediments using metabolic gas flux and was performed in an urban area section of a river in northeastern Indiana. CO2 sorbent traps were deployed to measure CO2 flux from the river sediments. Sediment samples were collected and analyzed for polycyclic aromatic hydrocarbon (PAH) concentrations and for microbial community composition using molecular techniques. The results showed that the deployment was successful, measuring CO2 flux at all sediment locations and demonstrating that microbial contaminant degrading activity was occurring in the sediments. Radio carbon dating showed a significant portion of the CO2 being generated (approximately 19–27 percent) was the result of fossil fuel degradation. Molecular results showed that the microbial community consisted of phylotypes known to be associated with monocyclic aromatic and PAH degradation. ©2017 Wiley Periodicals, Inc. 相似文献
592.
Contaminant mass flux and forensic assessment of polycyclic aromatic hydrocarbons: Tools to inform remediation decision making at a contaminated site in Canada 下载免费PDF全文
Tony R. Walker N. Devin MacAskill Andrew H. Thalheimer Lanying Zhao 《补救:环境净化治理成本、技术与工艺杂志》2017,27(4):9-17
Polycyclic aromatic hydrocarbons (PAHs) and metal(loid) mass flux estimates and forensic assessment using PAH diagnostic ratios were used to inform remediation decision making at the Sydney Tar Ponds (STPs) and Coke Ovens cleanup project in eastern Canada. Environmental effects monitoring of surface marine sediments in Sydney Harbor indicated significantly higher PAH concentrations during the first year of remediation monitoring compared to baseline. This was equivalent to PAH loadings of ~2,000 kg over a 15‐month period. Increases in sediment PAH concentrations raised serious concerns for regulators, who requested cessation of remediation activities early in the $400 M (CAD) project. Historically, the STPs were reported as the primary source of PAH contamination in Sydney Harbor with estimated discharges of 300 to 800 kg/year between 1989 and 2001. Mass flux estimates of PAHs and metal(loid)s and PAH diagnostic ratios were used to evaluate if increases in PAH concentrations in marine sediments were the result of the STPs remediation activities. PAH mass flux estimates approximated that 17 to 97 kg/year were discharged from the STPs during three years of remediation and were corroborated by an independent PAH flux estimate of 119 kg in year 1. PAH fluxes to the Sydney Harbor were mostly surface water derived, with groundwater contributing negligible quantities (0.002–0.005 kg/year). Fluxes of metal(loid)s to harbor sediments were stable or declining across all years and were mirrored in sediment metal(loid) concentrations, which lacked temporal variation, unlike total PAH concentrations. Flux results were also corroborated using PAH diagnostic ratios, which found a common source of PAHs. Coal combustion was likely the principal source of PAHs and not migration from the STPs during remediation. Although short‐term residual sediment PAH increases during onset of remediation raised concerns for regulators, calls for premature cessation of remediation early in the project were unwarranted based on only one year of monitoring data. Mass flux estimates and forensic assessments using PAH diagnostic ratios proved useful tools to inform remediation decision making that helped environmental protection and reduced costs associated with lost cleanup time. 相似文献
593.
Yuan-Na Xing Ying Guo Mei Xie Ru-Lang Shen 《Environmental pollution (Barking, Essex : 1987)》2009,157(4):1382-1387
A solid-phase microextration-based sampling method was employed to determine the concentrations of 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane (DDT) and its metabolites, 1,1-dichloro-2,2-bis(p-chlorophenyl)ethane (DDD), 1,1-dichloro-2,2-bis(p-chlorophenyl)ethene (DDE) and 1-chloro-2,2-bis(p-chlorophenyl)ethene (DDMU), in two estuarine bays, Daya Bay and Hailing Bay, of South China. Six DDT components including p,p′-DDT, o,p′-DDD, p,p′-DDD, o,p′-DDE, p,p′-DDE, and p,p′-DDMU were detected in Hailing Bay, while only p,p′-DDD was found in Daya Bay. p,p′-DDD was the most abundant DDT component in both bays, sharply different from the previous finding in the water column of the Palos Verdes Shelf, California, USA that p,p′-DDE was prevalent. In addition, the occurrence of p,p′-DDMU (with a range of 0.047-0.21 ng/L in Hailing Bay) has not been reported around the globe, and its presence in our study region appeared to stem from dehydrochlorination of p,p′-DDD, favored under aerobic conditions, but further investigations are clearly needed to confirm the mechanism for generation of DDMU in estuarine environments. 相似文献
594.
Part V—sorption of pharmaceuticals and personal care products 总被引:5,自引:0,他引:5
Background, aim, and scope Pharmaceuticals and personal care products (PPCPs) including antibiotics, endocrine-disrupting chemicals, and veterinary pharmaceuticals
are emerging pollutants, and their environmental risk was not emphasized until a decade ago. These compounds have been reported
to cause adverse impacts on wildlife and human. However, compared to the studies on hydrophobic organic contaminants (HOCs)
whose sorption characteristics is reviewed in Part IV of this review series, information on PPCPs is very limited. Thus, a
summary of recent research progress on PPCP sorption in soils or sediments is necessary to clarify research requirements and
directions.
Main features We reviewed the research progress on PPCP sorption in soils or sediments highlighting PPCP sorption different from that of
HOCs. Special function of humic substances (HSs) on PPCP behavior is summarized according to several features of PPCP–soil
or sediment interaction. In addition, we discussed the behavior of xenobiotic chemicals in a three-phase system (dissolved
organic matter (DOM)–mineral–water). The complexity of three-phase systems was also discussed.
Results Nonideal sorption of PPCPs in soils or sediments is generally reported, and PPCP sorption behavior is relatively a more complicated
process compared to HOC sorption, such as the contribution of inorganic fractions, fast degradation and metabolite sorption,
and species-specific sorption mechanism. Thus, mechanistic studies are urgently needed for a better understanding of their
environmental risk and for pollution control.
Discussion Recent research progress on nonideal sorption has not been incorporated into fate modeling of xenobiotic chemicals. A major
reason is the complexity of the three-phase system. First of all, lack of knowledge in describing DOM fractionation after
adsorption by mineral particles is one of the major restrictions for an accurate prediction of xenobiotic chemical behavior
in the presence of DOM. Secondly, no explicit mathematical relationship between HS chemical–physical properties, and their
sorption characteristics has been proposed. Last but not least, nonlinear interactions could exponentially increase the complexity
and uncertainties of environmental fate models for xenobiotics. Discussion on proper simplification of fate modeling in the
framework of nonlinear interactions is still unavailable.
Conclusions Although the methodologies and concepts for studying HOC environmental fate could be adopted for PPCP study, their differences
should be highly understood. Prediction of PPCP environmental behavior needs to combine contributions from various fractions
of soils or sediments and the sorption of their metabolites and different species.
Recommendations and perspectives More detailed studies on PPCP sorption in separated soil or sediment fractions are needed in order to propose a model predicting
PPCP sorption in soils or sediments based on soil or sediment properties. The information on sorption of PPCP metabolites
and species and the competition between them is still not enough to be incorporated into any predictive models. 相似文献
595.
J.M. Zhang T. Wang A.J. Ding X.H. Zhou L.K. Xue C.N. Poon W.S. Wu J. Gao H.C. Zuo J.M. Chen X.C. Zhang S.J. Fan 《Atmospheric environment (Oxford, England : 1994)》2009,43(2):228-237
Knowledge on atmospheric abundance of peroxyacetyl nitrate (PAN) is important in assessing the severity of photochemical pollution, and for understanding chemical transformation of reactive odd nitrogen and its impact on the budget of tropospheric ozone (O3). In summer 2006, continuous measurements of PAN were made using an automatic GC–ECD analyzer with an on-line calibrator at a suburban site of Lanzhou (LZ) and a remote site of Mt. Waliguan (WLG) in western China, with concurrent measurements of O3, total reactive nitrogen (NOy) and carbon monoxide (CO). At LZ, several photochemical episodes were observed during the study, and the average mixing ratio of PAN (plus or minus standard deviation) was 0.76 (±0.89) ppbv with the maximum value of 9.13 ppbv, compared to an average value of 0.44 (±0.16) ppbv at remote WLG. The PAN mixing ratios in LZ exhibited strong diurnal variations with a maximum at noon, while enhanced concentrations of PAN were observed in the evening and a minimum in the afternoon at WLG. The daily O3 and PAN concentration maxima showed a strong correlation (r2 = 0.91) in LZ, with a regression slope (PAN/O3) of 0.091 ppbv ppbv?1. At WLG, six well-identified pollution plumes (lasting 2–8 h) were observed with elevated concentrations of PAN (and other trace gases), and analysis of backward particle release simulation shows that the high-PAN events at WLG were mostly associated with the transport of air masses that had passed over LZ. 相似文献
596.
Dane Westerdahl Xing Wang Xiaochuan Pan K. Max Zhang 《Atmospheric environment (Oxford, England : 1994)》2009,43(3):697-705
In this paper, we report the results and analysis of a recent field campaign in August 2007 investigating the impacts of emissions from transportation on air quality and community concentrations in Beijing, China. We conducted measurements in three different environments, on-road, roadside and ambient. The carbon monoxide, black carbon and ultrafine particle number emission factors for on-road light-duty vehicles are derived to be 95 g kg?1-fuel, 0.3 g kg?1-fuel and 1.8 × 1015 particles kg?1-fuel, respectively. The emission factors for on-road heavy-duty vehicles are 50 g kg?1-fuel, 1.3 g kg?1-fuel and 1.1 × 1016 particles kg?1-fuel, respectively. The carbon monoxide emission factors from this study agree with those derived from remote sensing and on-board vehicle emission testing systems in China. The on-road black carbon and particle number emission factors for Chinese vehicles are reported for the first time in the literature. Strong traffic impacts can be observed from the concentrations measured in these different environments. Most clear is a reflection of diesel truck traffic activity in black carbon concentrations. The comparison of the particle size distributions measured at the three environments suggests that the traffic is a major source of ultrafine particles. A four-day traffic control experiment conducted by the Beijing Government as a pilot to test the effectiveness of proposed controls was found to be effective in reducing extreme concentrations that occurred at both on-road and ambient environments. 相似文献
597.
J.W.S. Longhurst J.G. Irwin T.J. Chatterton E.T. Hayes N.S. Leksmono J.K. Symons 《Atmospheric environment (Oxford, England : 1994)》2009,43(1):64-78
This paper considers the evolution of attempts to control and manage air pollution, principally but not exclusively focussing upon the challenge of managing air pollution in urban environments. The development and implementation of a range of air pollution control measures are considered. Initially the measures implemented primarily addressed point sources, a small number of fuel types and a limited number of pollutants. The adequacy of such a source-control approach is assessed within the context of a changing and challenging air pollution climate. An assessment of air quality management in the United Kingdom over a 50-year timeframe exemplifies the range of issues and challenges in contemporary air quality management. The need for new approaches is explored and the development and implementation of an effects-based, risk management system for air quality regulation is evaluated. 相似文献
598.
T.G. Soares Neto J.A. Carvalho C.A.G. Veras E.C. Alvarado R. Gielow E.N. Lincoln T.J. Christian R.J. Yokelson J.C. Santos 《Atmospheric environment (Oxford, England : 1994)》2009,43(2):438-446
Biomass consumption and CO2, CO and hydrocarbon gas emissions in an Amazonian forest clearing fire are presented and discussed. The experiment was conducted in the arc of deforestation, near the city of Alta Floresta, state of Mato Grosso, Brazil. The average carbon content of dry biomass was 48% and the estimated average moisture content of fresh biomass was 42% on wet weight basis. The fresh biomass and the amount of carbon on the ground before burning were estimated as 528 t ha?1 and 147 t ha?1, respectively. The overall biomass consumption for the experiment was estimated as 23.9%. A series of experiment in the same region resulted in average efficiency of 40% for areas of same size and 50% for larger areas. The lower efficiency obtained in the burn reported here occurred possibly due to rain before the experiment. Excess mixing ratios were measured for CO2, CO, CH4, C2–C3 aliphatic hydrocarbons, and PM2.5. Excess mixing ratios of CH4 and C2–C3 hydrocarbons were linearly correlated with those of CO. The average emission factors of CO2, CO, CH4, NMHC, and PM2.5 were 1,599, 111.3, 9.2, 5.6, and 4.8 g kg?1 of burned dry biomass, respectively. One hectare of burned forest released about 117,000 kg of CO2, 8100 kg of CO, 675 kg of CH4, 407 kg of NMHC and 354 kg of PM2.5. 相似文献
599.
Sarah B. Gewurtz Nilima Gandhi Guttorm N. Christensen Anita Evenset Dennis Gregor Miriam L. Diamond 《Environmental science and pollution research international》2009,16(2):176-190
Background, aim, and scope
Lake Ellasjøen, located in the Norwegian high arctic, contains the highest concentrations of polychlorinated biphenyls (PCBs) ever recorded in fish and sediment from high arctic lakes, and concentrations are more than 10 times greater than in nearby Lake Øyangen. These elevated concentrations in Ellasjøen have been previously attributed, in part, to contaminant loadings from seabirds that use Ellasjøen, but not Øyangen, as a resting area. However, other factors, such as food web structure, organism growth rate, weight, lipid content, lake morphology, and nutrient inputs from the seabird guano, also differ between the two systems. The aim of this study is to evaluate the relative influence of these factors as explanatory variables for the higher PCB fish concentrations in Ellasjøen compared with Øyangen, using both a food web model and empirical data.Methods
The model is based on previously developed models but parameterized for Lakes Ellasjøen and Øyangen using measured data wherever possible. The model was applied to five representative PCB congeners (PCB 105, 118, 138, 153, and 180) using measured sediment and water concentrations as input data and evaluated with previously collected food web data.Results
Modeled concentrations are within a factor of two of measured concentrations in 60% and 40% of the cases in Lakes Ellasjøen and Øyangen, respectively, and within a factor of 10 in 100% of the cases in both lakes. In many cases, this is comparable to the variability associated with the data as well as the efficacy of the predictions of other food web model applications.Discussion
We next used the model to quantify the relative importance of five major differences between Ellasjøen and Øyangen by replacing variables representing each of these factors in the Ellasjøen model with those from Øyangen, in separate simulations. The model predicts that the elevated PCB concentrations in Ellasjøen water and sediment account for 49%–58% of differences in modeled fish PCB concentrations between lakes. These elevated sediment and, to a lesser extent, water concentrations in Ellasjøen are due to PCB loadings from seabird guano. However, sediment–water fugacity ratios of PCBs are consistently greater in Ellasjøen compared with Øyangen, which suggests that internal lake processes also contribute to differences in sediment and water concentrations. We hypothesize that the nutrients associated with guano influence sediment–water fugacity ratios of PCBs by increasing the stock of pelagic algae. As both these algae and the guano settle, their organic carbon content is degraded faster than PCBs, which causes an extra magnification step in Ellasjøen before these detrital particles are consumed by benthic organisms, which are in turn consumed by fish. The model predicts that the remaining ~50% of the differences in PCB concentrations observed between the fish of these lakes are due to other subtle differences in their food web structures.Conclusions
In conclusion, based on the results of a food web model, we found that the most dominant factors influencing the higher PCB fish concentrations in Lake Ellasjøen compared with Øyangen are the higher sediment and water concentrations in Ellasjøen, caused by seabird guano. Together, sediment and water are predicted to account for 49%–58% of differences in fish concentrations between lakes. Although seabird guano provides a source of nutrients to the lake, in addition to contaminants, empirical data and indirect model results suggest that nutrients are not leading to decreased bioaccumulation, in contrast to what has been observed in temperate, pelagic food webs.Recommendations and perspectives
The results of this study emphasize the importance of considering even small differences in food web structure when comparing bioaccumulation in two lakes; although the food web structures of Ellasjøen and Øyangen differ only slightly, the model predicts that these differences account for most of the remaining ~50% of the differences in PCB fish concentrations between the two lakes. This study further demonstrates the utility of food web models as we were able to predict and tease apart the influence of various factors responsible for the elevated concentrations in the fish from Lake Ellasjøen, which would have been difficult using the field data alone. 相似文献600.
Chemical, biological, and ecotoxicological assessment of pesticides and persistent organic pollutants in the Bahlui River, Romania 总被引:1,自引:0,他引:1
Mariana Neamtu Ioan M. Ciumasu Naela Costica Mihai Costica Magda Bobu Mircea N. Nicoara Cezar Catrinescu Kristin Becker van Slooten Luiz F. De Alencastro 《Environmental science and pollution research international》2009,16(Z1):76-85