Calibration and validation of an integrated nitrate transport model within a well capture zone

Groundwater contamination by nitrate was investigated in an agricultural area in southern Quebec, Canada, where a municipal well is the local source of drinking water. A network of 38 piezometers was installed within the capture zone of the municipal well to monitor water table levels and nitrate concentrations in the aquifer. Nitrate concentrations were also measured in the municipal well. A Water flow and Nitrate transport Global Model (WNGM) was developed to simulate the impact of agricultural activities on nitrate concentrations in both the aquifer and municipal well. The WNGM first uses the Agriflux model to simulate vertical water and nitrate fluxes below the root zone for each of the seventy agricultural fields located within the capture zone of the municipal well. The WNGM then uses the HydroGeoSphere model to simulate three-dimensional variably-saturated groundwater flow and nitrate transport in the aquifer using water and nitrate fluxes computed with the Agriflux model as the top boundary conditions. The WNGM model was calibrated by reproducing water levels measured from 2005 to 2007 in the network of piezometers and nitrate concentrations measured in the municipal well from 1997 to 2007. The nitrate concentrations measured in the network of piezometers, however, showed greater variability than in the municipal well and could not be reproduced by the calibrated model. After calibration, the model was validated by successfully reproducing the decrease of nitrate concentrations observed in the municipal well in 2006 and 2007. Although it cannot predict nitrate concentrations in individual piezometers, the calibrated and validated WNGM can be used to assess the impact of changes in agricultural practices on global nitrate concentrations in the aquifer and in the municipal well.     

Effects of long exposure to low temperatures on nitrifying biofilm and biomass in wastewater treatment

Attached growth biological treatment systems are a promising solution to ammonia removal in cold-temperature climates. Environmental scanning electron microscopy (ESEM) and confocal laser scanning microscopy in combination with fluorescent in situ hybridization (FISH) was used to investigate the effects of 4 months of exposure to 4 degrees C on nitrifying biofilm and biomass. These molecular and microscopic methods were modified to minimize loss of mass and distortion of in situ perspectives. Environmental scanning electron microscopy revealed that nitrifying biofilm did not exhibit significant changes in volume with exposure to 4 degrees C. Confocal laser scanning microscopy in combination with FISH showed that the number of ammonia-oxidizing bacteria (AOB) cells present in the biofilm was statistically consistent during exposure to 4 degrees C. The RNA content of AOB cells remained sufficient for FISH enumeration. The number of nitrite-oxidizing bacteria cells remained steady during exposure to 4 degrees C; however, the RNA content of the cells appeared to decrease with exposure to 4 degrees C, thereby preventing their enumeration using FISH.     

Uranium bioaccumulation and biological disorders induced in zebrafish (Danio rerio) after a depleted uranium waterborne exposure

Because of its toxicity and its ubiquity within aquatic compartments, uranium (U) represents a significant hazard to aquatic species such as fish. In a previous study, we investigated some biological responses in zebrafish either exposed to depleted or to enriched U (i.e., to different radiological activities). However, results required further experiments to better understand biological responses. Moreover, we failed to clearly demonstrate a significant relationship between biological effects and U radiological activity. We therefore chose to herein examine U bioaccumulation and induced effects in zebrafish according to a chemical dose-response approach. Results showed that U is highly bioconcentrated in fish, according to a time- and concentration-dependent model. Additionally, hepatic antioxidant defenses, red blood cells DNA integrity and brain acetylcholinesterase activity were found to be significantly altered. Generally, the higher the U concentration, the sooner and/or the greater the effect, suggesting a close relationship between accumulation and effect.     

Degradation in an Inert Solid Medium of Poly(Lactic Acid) Polymeric Material by Kibdelosporangium aridum

The aim of this work was to estimate the biodegradation of a poly(lactic acid) polymeric material by the actinomycetes Kibdelosporangium aridum using a vermiculite based inert solid medium which could simulate compost medium and enable us to achieve complete carbon balances. The mineralisation rate at the end of the test was compared to those obtained for two basal media. It was shown that cumulative mineralisation after 45 days of degradation was greater (70%) in vermiculite with a basal medium containing gelatin than in vermiculite with a basal medium containing glucose (20%).     

Trapping efficiencies of cultivated and natural riparian vegetation of northern Laos

In northern Laos, intensification of cultivation on sloping land leads to accelerated erosion processes. Management of riparian land may counteract the negative impacts of higher sediment delivery rates on water quality. This study assessed water and sediment concentration trapping efficiencies of riparian vegetation in northern Laos and the effect of cultivation of riparian land on water quality. Runoff flowing in and out of selected riparian sites was monitored by means of open troughs. In 2005, two native grass, two bamboo, and two banana sites were monitored. In 2006, adjacent to steep banana, bamboo, and native grass sites, three upland rice sites were established and monitored. Water trapping efficiency (WTE) and sediment concentration trapping efficiency (SCTE) were calculated on an event basis; means and 95% confidence intervals (CIs) were estimated with a bootstrapping approach. Confidence intervals were large and overlapping among sites. Seepage conditions severely limited trapping efficiency. Native grass resulted in the highest WTE (95% CI, -0.10 to 0.23), which was not significantly different from zero. Banana resulted in the highest SCTE (95% CI, 0.06-0.40). Bamboo had negative WTE and SCTE. Median outflow runoff from rice sites was nine times the inflow. Median outflow sediment concentration from rice sites was two to five times that of their adjacent sites and two to five times the inflow sediment concentration. Although low-tillage banana plantation may reduce sediment concentration of runoff, cultivation of annual crops in riparian land leads to delivery of turbid runoff into the stream, thus severely affecting stream water quality.     

Exposure assessment of French women and their newborns to tetrabromobisphenol-A: occurrence measurements in maternal adipose tissue, serum, breast milk and cord serum

A French monitoring study was initiated to evaluate the exposure of fetus and newborn to brominated flame retardants (BFR). A previously developed multi-residue analytical method was used for measuring the main classes of BFR (tetrabromobisphenol-A, and tri- to decabomodiphenyl ethers) in various human biological matrices. Analyzed samples (maternal and cord serum, adipose tissue and breast milk) were collected from 93 volunteer women during caesarean deliveries. TBBPA was detected in 44% of the analyzed breast milk samples, at levels varying from 0.06 to 37.34 ng g(-1) lipid weight, but was not detected in adipose tissue. This compound was also detected in 30% of the analyzed serum samples, with similar average values in maternal and cord serum (154 pg g(-1) fresh weight versus 199 pg g(-1) fresh weight, respectively). The interpretation of the collected data permitted the demonstration of (1) a significant exposure to TBBPA both for mothers and fetuses and (2) a possible risk of overexposure of newborns through breastfeeding.     

Comparison of oxygen-transfer measurement methods under process conditions.

The objective of this paper is to compare the following four methods of measuring oxygen transfer in wastewater treatment plants under process conditions: the offgas, hydrogen peroxide (H2O2), reaeration, and in situ oxygen uptake rate (OUR) methods. Comparative tests were performed under controlled conditions in a pilot column and in six full-scale oxidation ditches equipped with fine-bubble diffusers and slow-speed mixers. The offgas and H2O2 methods give similar results (differences between the oxygen-transfer coefficients under field conditions [k(L)a(f)] from each method lower than 10%). The reaeration procedure gives more random results (differences from -5 to -43% compared with values obtained using the offgas method). The in situ OUR method, in the presence of a horizontal flow of mixed liquor, leads to an estimate of k(L)a(f) to within 15% of the offgas value.     

Electric load management in developing countries

Energy planners in developing countries have traditionally sought to meet their nations' growing electricity demands by adding more generation and transmission capacity. But as the foreign investment situation became critical in the 1980s, private investment and system efficiency improvement programmes began to garner interest. One of the most promising system efficiency improvement options is load management, which uses a variety of techniques to utilize the electricity system's existing capacity more efficiently. However, to date, only three countries have seriously considered implementing large load management programmes: Pakistan, Peru and Costa Rica. This paper describes a 1987-89 load control demonstration programme in Costa Rica, sponsored by the US Agency for International Development (AID), in which participating industries were able to reduce their peak demand by 14%.     

Evaluation of the effect of a cover layer on radon exhalation from uranium mill tailings: transient radon flux analysis

An experimental study concerning the transport of 222Rn in uranium mill tailings (UMTs) and in the cover layer was launched in 1997 with the participation of the French uranium mining company (COGEMA). Evaluation of the cover layer's effectiveness in reducing 222Rn flux emanating from UMTs was one of its objectives. In the first phase, the 222Rn flux densities were measured regularly on a UMT layer. In the second phase, the UMT was covered with a one-meter layer of compacted material consisting of crushed waste rock derived from mining activities. Radon-222 flux was then measured at the surface of this cover layer. Observations were compared with radon flux calculated using TRACI, a model for vertical water and gas flow and radon transport. The results show that the calculations bear a fair resemblance to the observations in both cases. They also show that the effectiveness of the cover layer calculated with TRACI, using the thickness and textural properties of the cover material, is very close to the measured effectiveness.