A semianalytical soil-pesticide transport model is formulated based on a compartmental approach to determine spatial and temporal variations of pesticide residues across a soil profile. The compartmental model is implemented by drawing an analogy between a series of continuous-flow stirred tank reactors and a soil horizon that consists of multiple perfectly mixed compartments. The analogy is strengthened by exploiting a relation between the compartment series and the conventional convective-dispersive equation (CDE) for vertical transport in the soil. Consequently, the number of compartments in the model formulation is not free, but dictated as a function of transport parameters. The model formulation allows consideration of arbitrary boundary value specifications and also, for some cases, spatially varying initial concentration profiles. Sorption kinetics is represented via a two-site model that involves a linear sorption isotherm and a first-order irreversible sorption or a radial diffusive penetrating model. For these three cases, analysis of the compartmental model allows the resultant concentration profiles to be expressed in terms of the Poisson distribution. When a nonlinear kinetic sorption model is used to simulate the sorption processes, an analytical solution is not found and a numerical approach is required. 相似文献
The high pollutant load of sanitary landfill leachates poses a huge challenge in the search for efficient and environment friendly solutions for their treatment. The objective of this work was to study an integrated solution of environmentally friendly technologies — immediate one-step lime precipitation (IOSLP), carbonation (CB), and phytoremediation (Phyt) — to treat a sanitary landfill leachate. In the leachate sample treatment by IOSLP, the influence of CaO concentration (18.2–33.3 gCaO L?1) and stirring time (2–60 min) on the sludge sedimentability and pollutant removal was studied. Organic load and ammonia nitrogen (AN) removal increases with CaO added, as well as sludge volume. Stirring time has a small influence on organic load and AN removal, presenting a minimum for sludge volume. Thus, the best operational conditions were chosen as 27.6 gCaO L?1, and 40-min stirring time, with 64% chemical oxygen demand (COD) removal. Sludge humidity was 2.1%, making dewatering needless. IOSLP supernatant was submitted to CB by atmospheric CO2, and 100% removals in AN and hardness were attained. Effluents from IOSLP and IOSLP?+?CB were utilized in Phyt tests, with Vetiver (Chrysopogon zizanioides (L.) Roberty). The best COD removal (37%) during Phyt was attained for the samples treated by IOSLP?+?CB.
In this study, 79 bulk precipitation samples were collected at two sampling sites near Büyükçekmece Lake, one of the important drinking water sources of Istanbul, for the period of October 2001 to July 2002. The study comprised the determination of trace and toxic metals concentrations in rain water. The concentrations of the metals in this study were found to be higher than those reported by other researchers around the world. The solubility of toxic metals was found in the order of Cd > Cu > V > Zn > Ni > Pb > Cr. Solubility of metals under acidic conditions (pH < 5.5) was approximately five times higher than those under neutral conditions with Cd as the most soluble metal (50% soluble). Statistical evaluations including seasonal variations, crustal enrichment factors, and correlation matrix were discussed to identify the possible sources of these pollutants. The study revealed that anthropogenic elements were highly enriched especially for Cd > Cu > Pb which were found to be highly enriched. Significant portion of Cu and Pb could be increased by the effect of local sources like cement industry in the area; however, the rest of the investigated trace metals could be brought to the sampling site by long-range transport to the Büyükçekmece Lake watershed area. 相似文献
Forest management practices alter forest structure quantified with ecosystem characteristics and values. In this paper, we utilized a forest management simulation model to assess the effects of three forest management strategies focusing on timber production, carbon sequestration, oxygen production, soil erosion, and water production of a forest management unit in Turkey. A forest simulation model “ETÇAPSimülasyon” was developed and used to project forest ecosystem development over 100 years under three forest management policies of timber-oriented forest management (TFM), multipurpose forest management (MFM), and no intervention (NI). The results showed that TFM strategy produced more timber and its net present value than MFM and NI strategies did. The amount of carbon sequestration and oxygen production potential was also found to be the highest with TFM strategy than with the MFM and NI strategies. Compared with the other strategies, however, NI strategy produced the highest amount of water production and soil losses over the planning horizon. The effects of a forest management strategy depend mainly on the initial forest structure, the rate of development and the level of forest management interventions. Therefore, forest dynamics under various management strategies should be explained before the final management decision. Understanding long-term effects of any management strategies on forest structure will provide the basis for better reaching the management objectives. 相似文献
Environmental Science and Pollution Research - The present work investigates the use of Agave americana fibers (AGF) as a precursor for activated carbon (AC) preparation via chemical activation... 相似文献
Environmental Science and Pollution Research - Turkey is one of the major plastic pollution sources in the Mediterranean and the Black Sea. This review summarizes present information, data, and... 相似文献
A Penicillium camemberti strain isolated in our laboratory has been studied for its ability to degrade chlorinated pulping wastes, presumably containing a variety of chlorinated polyphenols. In batch tests, the highest removals (76% AOX, 61% color and 65% TOC) were obtained with 0.2 g/l feed acetate concentration. The tendency of the fungus to dechlorinate bleachery effluents better under non-shaking conditions and to attach onto surfaces suggested the use of immobilized cells rather than freely suspended ones in further exploitation of the process. An upflow glass wool packed column reactor established with this fungus could be operated for nearly two years in the laboratory. At best around 70% AOX could be removed from chlorinated pulping wastes in 7.3 h of contact with no aeration and with a minimal amount of carbon supplement (0.2 g/l). Finally, an asymptotic mathematical formula for determining Michaelis-Menten kinetic rates has been derived. The kinetic rates K(m) (the Michaelis constant or saturation constant for the substrate) and V(m) (the product of maximum rate for the enzymatic reaction and biomass concentration) were then calculated as 126.386 mg/l and 2.83017 mg/lh, respectively. 相似文献