全文获取类型
收费全文 | 4953篇 |
免费 | 139篇 |
国内免费 | 61篇 |
专业分类
安全科学 | 270篇 |
废物处理 | 168篇 |
环保管理 | 1255篇 |
综合类 | 537篇 |
基础理论 | 1358篇 |
环境理论 | 8篇 |
污染及防治 | 999篇 |
评价与监测 | 328篇 |
社会与环境 | 175篇 |
灾害及防治 | 55篇 |
出版年
2023年 | 59篇 |
2022年 | 55篇 |
2021年 | 55篇 |
2020年 | 63篇 |
2019年 | 69篇 |
2018年 | 122篇 |
2017年 | 134篇 |
2016年 | 180篇 |
2015年 | 121篇 |
2014年 | 163篇 |
2013年 | 409篇 |
2012年 | 235篇 |
2011年 | 306篇 |
2010年 | 203篇 |
2009年 | 239篇 |
2008年 | 262篇 |
2007年 | 258篇 |
2006年 | 229篇 |
2005年 | 196篇 |
2004年 | 180篇 |
2003年 | 149篇 |
2002年 | 140篇 |
2001年 | 87篇 |
2000年 | 96篇 |
1999年 | 69篇 |
1998年 | 75篇 |
1997年 | 61篇 |
1996年 | 63篇 |
1995年 | 78篇 |
1994年 | 75篇 |
1993年 | 66篇 |
1992年 | 58篇 |
1991年 | 39篇 |
1990年 | 38篇 |
1989年 | 36篇 |
1988年 | 31篇 |
1987年 | 39篇 |
1986年 | 40篇 |
1985年 | 39篇 |
1984年 | 44篇 |
1983年 | 44篇 |
1982年 | 52篇 |
1981年 | 43篇 |
1980年 | 31篇 |
1979年 | 15篇 |
1978年 | 29篇 |
1977年 | 16篇 |
1976年 | 14篇 |
1972年 | 7篇 |
1971年 | 9篇 |
排序方式: 共有5153条查询结果,搜索用时 378 毫秒
801.
Structure elucidation of four possible biogenic organohalogens using isotope exchange mass spectrometry 总被引:2,自引:0,他引:2
The molecular structures of four unknown bioaccumulating halogenated compounds, C10H6N2Br3Cl3, C10H6N2Br4Cl2, C10H6N2Br5Cl, and C10H6N2Br6 were characterized using isotope exchange positive chemical ionization (IE-PCI) mass spectrometry (MS) and identified by comparison to synthesized standards. NH3 and ND3 were used as reagent gases for the IE-PCI-MS experiment. The shift in mass of the quasimolecular ion between the NH3 and ND3 PCI obtained spectra indicated the number of exchangeable hydrogens attached to the two nitrogen atoms in C10H6N2Br4Cl2, and thus the type of amines present (primary, secondary, or tertiary). 19 compounds (13 amines of varying degree of substitution; six containing no nitrogen) were used as reference compounds and controls in the experiment to validate the IE-PCI technique. The results of the IE-PCI-MS indicated the presence of two tertiary amine functional groups. The molecular structures of the four hexahalogenated compounds were then proposed to be 1,1'-dimethyl-3,3',4,-tribromo-4',5,5'-trichloro-2,2'-bipyrrole, 1,1'-dimethyl-3,3',4,4'-tetrabromo-5,5'-dichloro-2,2'-bipyrrole, 1,1'-dimethyl-3,3',4,4',5-pentabromo-5'-chloro-2,2'-bipyrrole, and 1,1'-dimethyl-3,3',4,4',5,5'-hexabromo-2,2'-bipyrrole and subsequently synthesized. Comparison of retention times and electron capture negative ionization (ECNI) full scans on various gas chromatography (GC) columns between the synthesized bipyrroles and the corresponding unknown compounds in biota indicated that three of the unknown compounds--possible marine natural products--were the proposed halogenated dimethyl bipyrroles. The placement of the halogen atoms on the fourth compound, C10H6N2Br3Cl3 could not be unequivocally determined since the synthesized standard could not be fully characterized. 相似文献
802.
ABSTRACTThe environmental justice (EJ) literature can benefit from comparative analysis that helps to identify conditions for more and less successful outcomes. A data set of 50 EJ cases in the U.S. was developed with high and low remediation as the outcome. Causal conditions were selected on theoretical grounds, and included five mobilizing strategies (local and state government coalitions, federal government attention, civil disobedience, litigation, and national NGO support) and three general conditions (absence of industry counter-mobilization, presence of water pollution, and proposed or new siting). Qualitative comparative analysis and other analyses indicated that all causal conditions were found in the high-remediation cases but that some conditions (water pollution and local–state coalitions) were more consistently associated with the high-remediation outcome. The analysis points to the value of systematic studies of the factors that affect local EJ outcomes and to the need for better case study collections. 相似文献
803.
The potential of TNT to accumulate in aquatic organisms was assessed by determining bioconcentration factors for TNT and TNT biotransformation products using two benthic invertebrates (Chironomus tentans and Lumbriculus variegatus), and by determining the bioaccumulation factor of TNT and TNT biotransformation products due to TNT exposure via feeding for channel catfish (Ictalurus punctatus). In all three species, TNT was rapidly biotransformed resulting in minimal accumulation. The bioconcentration factors for parent TNT ranged from 3 to 4 ml g(-1) for the invertebrates studied, while the TNT bioaccumulation factor for catfish via oral exposure of food pellets was 2.4x10(-5) g g(-1) based on the concentration of TNT in the food pellet. As indicated by this small bioaccumulation factor, TNT accumulation in channel catfish through trophic transfer would be negligible compared to aqueous exposure (previously reported BCF of 0.79 ml g(-1)). TNT extractable biotransformation products accumulated to a greater degree than parent TNT for all three species. In addition, a large fraction of the radioactivity within all three species resisted solvent extraction. The highest bioconcentration factors occurred in L. variegatus with extractable radioactivity measuring 76 ml g(-1) and total radioactivity measuring 216 ml g(-1). Because the bioaccumulation of TNT is very low compared to the bioaccumulation of its biotransformation products, further research including identifying and determining the relative toxicities of these biotransformation products is necessary to fully evaluate the environmental risk posed by exposure to TNT. 相似文献
804.
805.
Sources of metals in New York City wastewater 总被引:1,自引:0,他引:1
L A Klein M Lang N Nash S L Kirschner 《Journal - Water Pollution Control Federation》1974,46(12):2653-2662
806.
Nimmermark SA Jacobson LD Schmidt DR Gay SW 《Journal of the Air & Waste Management Association (1995)》2005,55(9):1306-1314
A comparison between predicted and observed odor intensities at 20 neighborhood residences in the vicinity of seven various livestock farms in five different Minnesota counties was made to evaluate the Odor From Feedlots, Setback Estimation Tool (OFFSET) developed by the University of Minnesota. Observations by neighborhood monitors suggest that the OFFSET-predicted separation distances for annoyance-free frequencies of 99, 98, and 97% are large enough. The observations additionally indicate that predicted distances to obtain 94 and 91% annoyance-free frequencies may be large enough for some farms, but for other farms, greater distances may be needed. For two farms in the study, no significant difference between all of the observed and predicted intensities could be found. At four sites, a significant difference was found, and at three of these the difference was considerable. Odor emission rates used in the OFFSET model seem to describe the average emission fairly well for many odor sources, but improvement may be needed for some types of sources. Possible reasons for observations of annoying odor when not predicted include fluctuations in the odor emissions, wind speed fluctuations, topographic variation between sites, sensitivity differences by neighborhood monitors, and background emissions from other sources. 相似文献
807.
Frederick Bloetscher James D Englehardt David A Chin Joan B Rose George Tchobanoglous Vincent P Amy Sinem Gokgoz 《Water environment research》2005,77(5):480-490
A comparative assessment of the risks of three effluent disposal alternatives currently available to wastewater utilities in Southeast Florida is presented in this paper. The alternatives are: deep well injection and ocean outfalls following secondary treatment, and surface water (canal) discharges following secondary wastewater treatment, filtration and nutrient removal. Water quality data, relative to disposal of wastewater treatment plant effluent were gathered, along with water quality data on the receiving waters, from utilities. Comparisons and conclusions regarding potential health concerns associated with the three disposal alternatives are presented. The results indicated that health risks associated with deep wells were generally lower than those of the other two alternatives. The proximity of injection wells to aquifer storage and recovery wells was a determining factor relative to injection well risk. Urban ecological risks were also indicated to be lower, though impacts of urban water use/reuse to the Everglades were not studied. Additional data collection and analysis were recommended to understand the effects of wastewater management on the cycling of water, nutrients and other constituents on southeast Florida. In particular, it was recommended that monitoring of effluents for nitrosamines and pharmaceutically active substances be implemented on a broad scale. 相似文献
808.
809.
Open-focused microwave-assisted extraction and ICP-OES determination of As, Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn from surface sediments of the estuary of Bilbao (Basque Country, North of Spain) was carried out. All the samples were collected at three different tributaries of the estuary (Asua, Galindo and Nerbioi-Ibaizabal) every two months during 1999. The digestion procedure was proposed from the conclusions of a fractionated factorial design, and the precision and accuracy of the method was verified using a certified reference sediment (RTC008-050). The results of the analysis were statistically treated by means of principal component analysis and correlation analysis. The principal component analysis of sediment data (32 samples × 9 metals) indicated different patterns of contamination regarding the tributary and sampling station. The two main patterns observed were a steady increment of the metal concentration along all the campaigns in the samples collected in the Galindo River and a seasonal variation in the Nerbioi-Ibaizabal River, with higher metallic content during summertime and lower content during wintertime. 相似文献
810.
Laboratory leaching studies of oryzalin and diuron through three undisturbed vineyard soil columns 总被引:1,自引:0,他引:1
The leaching of diuron and oryzalin through undisturbed soil columns was studied in the laboratory using three vineyard soils from Vosne-Romanée (Burgundy): a rendosol, a calcosol and a vegetated calcosol. After 845 mm of simulated rainfall in 15 days, soil leachates contained higher amounts of diuron (3.2%, 11.8% and 18.8% of applied diuron, respectively) than oryzalin (0.2%, 4.9%, 3.7%, respectively). A greater proportion of soil extractable residues was obtained for diuron (42.5%, 26.8% and 32.2%, respectively) than for oryzalin (14.7%, 12% and 15.5%, respectively). The greater mobility of diuron might be related to its higher water solubility (36.4 mgl(-1) compared with 2.6 mgl(-1) for oryzalin) and smaller adsorption coefficient (400 lkg(-1), compared with 700-1100 lkg(-1) for oryzalin). The mobility of the two herbicides was greater in the two calcosols than in the rendosol, not only due to different organic carbon contents but also different soil textures and structures. 相似文献