Maßnahmen zur Dioxinminderung an Müllverbrennungsanlagen

The 17th BlmSchV fixed the emission limit of 0.1 ng TE/m_n ³ for PCDD/F’s produced as a result of waste- and special waste incinerators. This article introduces the different measures implemented to uphold this limit, and discusses their advantages and disadvantages. Methods of optimising the incineration conditions are among the primary measures. Different geometry’s for conventional oven incineration rooms were discussed, and an effective modernisation method was introduced (Temelli nozzles). The chemical and technical basis of an often discussed gasification method, as well as the characteristics of three specialised techniques (Coke Burn technique, Thermo-Select technique and Noell-DBI technique) are explained in this article. Alongside the secondary measures of hot-dust filtration and inhibition being added to the washers in an attempt to achieve PCDD/F adsorption. The most important tertiary measures, namely the SCR technique, along with a variety of coke adsorption techniques are introduced, with their advantages and disadvantages. New techniques such as DeDioxin and Medisorbon are also addressed.     

Numerical modelling of multiphase flow and transport processes in landfills.

Waste material in municipal landfills can be described as heterogeneous porous media, where flow and transport processes of gases and liquids are combined with local material degradation. This paper deals with the basic formulation of a multiphase flow and transport model applicable to the numerical analysis of coupled transport and reaction processes inside landfills. The transport model treats landfills within the framework of continuum mechanics, where flow and transport processes are described on a macroscopic level. The composition of organic and inorganic matter in the solid phase and its degradation are modelled on a microscopic scale. The degradation model captures the different reaction schemes of various microbial activities. Subsequently, transport and reaction processes have to be coupled, since emissions at the surface and from the drainage layer depend on the flow of leachate and gas, the transport of various substances and heat, and the biodegradation of organic matter. The theoretical considerations presented here are fundamental to the development of numerical models for the simulation of multiphase flow and transport processes inside landfills coupled with biochemical reactions and heat generation. The implicit modelling of leachate and gas flows including growth and decay of micro-organisms are innovative contributions to landfill modelling