Effect of NOx and RH on the secondary organic aerosol formation from toluene photooxidation

The secondary organic aerosol (SOA) formation mechanism and physicochemical properties can highly be influenced by relative humidity (RH) and NOx concentration. In this study, we performed a laboratory investigation of the SOA formation from toluene/OH photooxidation system in the presence or absence of NOx in dry and wet conditions. The chemical composition of toluene-derived SOA was measured using Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). It was found that the mass concentration of toluene decreased with increasing RH and NOx concentration. However, the change of SOA chemistry composition (f₄₄, O/C) with increased RH was not consistent in the condition with or without NOx. The light absorption and mass absorption coefficient (MAC) of the toluene-derived SOA only increased with RH in the presence of NOx. In contrast, MAC is invariant with RH in the absence of NOx. HR-ToF-AMS results showed that, in the presence of NOx, the increased nitro-aromatic compounds and N/C ratio concurrently caused the increase of SOA light absorption and O/C in wet conditions, respectively. The relative intensity of CHON and CHO_xN family to the total nitrogen-containing organic compounds (NOCs) increased with the increasing RH, and be the major components of NOCs in wet condition. This work revealed a synergy effect of NOx and RH on SOA formation from toluene photooxidation.     

化工型科研单位员工健康管理实践与对策

以某化工型科研单位为研究对象,分析评估化工型科研单位中存在的员工健康危害因素,阐述关于员工健康的管理实践与对策。通过健康风险识别与评估、健康危险因素监测与管理、劳动保护、工伤与疾病管理、健康保障、健康促进等形式开展员工健康管理,实现职业健康、身体健康、心理健康的全员健康、全面健康的"大健康"目标。     

Physicochemical analysis of individual atmospheric fine particles based on effective surface-enhanced Raman spectroscopy

Fine particles associated with haze pollution threaten the health of more than 400 million people in China. It is therefore of great importance to thoroughly investigate and understand their composition. To determine the physicochemical properties in atmospheric fine particles at the micrometer level, we described a sensitive and feasible surface-enhanced Raman scattering(SERS) method using Ag foil as a substrate. This novel method enhanced the Raman signal intensities up to 10,000 a.u. for ν(NO_3~-) in fine particles.The SERS effect of Ag foil was further studied experimentally and theoretically and found to have an enhancement factor of the order of ～10~4. Size-fractionated real particle samples with aerodynamic diameters of 0.4–2.5 μm were successfully collected on a heavy haze day,allowing ready observation of morphology and identification of chemical components, such as soot, nitrates, and sulfates. These results suggest that the Ag-foil-based SERS technique can be effectively used to determine the microscopic characteristics of individual fine particles, which will help to understand haze formation mechanisms and formulate governance policies.     

泄漏检测与修复技术实施水平量化评估简介

介绍了泄漏检测与修复(LDAR)及挥发性有机化合物(VOCs)控制相关标准、指南和文件。研究了泄漏检测与修复项目实施水平量化评估技术。其中,评估流程包括制定评估方案、收集评估资料,开展现场评估,编写评估报告;评估要素包括资料审核、现场审核、人员考察、现场抽检4方面内容;水平量化评估包括LDAR技术实施水平量化评估检查表、LDAR技术实施水平量化评分标准。本研究对评估企业实施LDAR过程合规性,检测数据有效性,以及实施技术水平的可比性具有指导意义。     

单次降水对高寒草地温室气体通量昼夜变化的影响研究

在全球变化背景下,青藏高原降水格局发生改变,并影响高寒草地温室气体排放.为了更好地认识降水变化与高寒草地温室气体排放的关系,在2015年7月24日,通过人工降水6.7 mm,研究了单次降水对高寒草地温室气体昼夜变化的影响.表明:(1)单次降水没有改变土壤温度,但显著增加了土壤湿度;(2)单次降水后24小时内,高寒草地CH4吸收量降低了2.46倍,CO2和N2 O排放量分别提高15.3%和98.9%;(3)单次降水弱化了高寒草地CH4和N2 O排放量与土壤温度的关系.     

Mobility of acid-treated carbon nanotubes in water-saturated porous media

The production, use, and disposal of nanomaterials may inevitably lead to their appearance in water. With the development of new industries around nanomaterials, it seems necessary to be concerned about the transport of nanomaterials in the environment. In this paper, the transport of acid-treated carbon nanotubes (CNTs) in porous media was investigated. Before the mobility investigation, the stability of acid-treated CNT dispersions was studied using ultraviolet-visible spectra and it was indicated that, under the chemical conditions employed in this work, there was no apparent aggregation. The mobility investigation showed that transport of acid-treated CNTs increased with treatment time due to increase in particle zeta potential. Carbon nanotubes treated with nitric acid for 2, 6, and 12 h possessed measured zeta potentials of -30.0, -43.0, and -48.5 mV, respectively. Utilizing clean-bed filtration theory, we showed that acid-treated CNTs have the potential to migrate 3.28, 5.67, and 7.69 m in saturated glass beads, respectively. We showed that solution ionic strength and pH have important effects on the mobility of acid-treated CNTs. Increasing the pH from 6.0 to 7.9 resulted in an increase in migration potential from 2.96 to 10.86 m. Increasing the ionic strength from 0.005 to 0.020 M resulted in a decrease in CNT migration potential from 5.67 to 1.42 m.     

Lake area changes in the middle Yangtze region of China over the 20th century

The Jianghan Plain and the Dongting lake area, located in the middle reaches of the Yangtze River are famous for their abundant freshwater lakes. The lakes have undergone changes in size and number over thousands of years due to natural causes and human activities. The 20th century particularly, witnessed dramatic changes in the freshwater resources of this region. This paper traces and analyzes lake evolution in the middle reaches of the Yangtze River over the past century. Lakes greater than 0.1 km(2) in size are mapped using Geographic Information System. Data is acquired and integrated from drainage network maps, relief maps, historical maps and remotely sensed images for different time periods. The results indicate that while there has been little change in the number of lakes over the past century, the lake area has experienced a dramatic decrease of 58.06%. The paper also examines the natural processes and human activities that may have contributed to the decrease in lake area. The results show that the decrease in total lake area appears to coincide with periods of rapid land reclamation in the middle reaches of the Yangtze River. Moreover, uncontrolled land reclamation activities can create an increase in sediment deposition in lakes thereby further reducing the lake size. Reduction of the lake area directly affects flood-control and has a negative ecological impact on the environment and on human life and property.     

抗高温环保钻井液体系研究

文章选择清洁环保的钻井液处理剂进行抗高温钻井液体系实验研究与评价,对包被增粘剂、降失水剂等进行优选,对抗高温环保钻井液配方进行评价,研究出无毒、无害,抗温能力强、流变性好,失水较低的钻井液体系,现场应用满足高温深井的钻井生产要求。     

南四湖流域水污染防治存在的问题及对策

南四湖通过采用"治、用、保"并举的流域污染综合治理措施,把污染治理与水资源循环利用相结合,取得了明显的成效,但仍面临工业结构性污染严重、城市基础设施建设滞后、面源污染突出等问题。根据南四湖实际情况,可从加大资金筹措力度、继续实施流域综合治理、整合现有港口资源、开展生态养殖、加强执法等方面入手,解决流域水污染防治存在的问题。     

陕西省精细化地质灾害气象预报预警研究

在黄土高原和秦巴山区地质灾害与降水相关特征分析基础上,介绍了陕西省气象台精细化地质灾害气象预报预警模型与业务系统.利用新一代多普勒天气雷达和自动气象站加密资料实现了综合雨量的精细估计,结合GIS地形地貌信息和历史灾害风险分析确定出降水影响系数后,通过计算指标量与灾害临界阈值判断实现了陕西省l 915个乡镇地质灾害的逐日...