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461.
氢化物发生原子荧光法测定地表水和饮用水中的痕量砷、汞、硒 总被引:3,自引:0,他引:3
文章研究了用SK-2002 AFS analyser氢化物发生原子荧光法测定地表水和饮用水中的砷、汞、硒的测定。在5%的酸度条件下加入5%硫脲+5%抗坏血酸,20g/L的硼氢化钾为还原剂,调整仪器的空气和辅气流量及分析条件为文中条件,取水样中分别添加砷,汞,硒,使它们的浓度分别为2μg/L,0.4μg/L,4μg/L,连续测定12次,以砷,汞,硒的相对标准偏差分别为0.4%,1.1%,1.2%。取水样加入As,Hg,Se标准分别为2.0ng,0.6ng,4.0ng,测定的添加标准回收率分别为99.5%,97.5%,95.8%。研究结果表明,该方法操作简便,快速,灵敏,干扰少,检出限低等特点,适合于测定地表水和饮用水中砷,汞,硒的测定。 相似文献
462.
不同污染区对绿化树种游离脯氨酸含量的影响 总被引:3,自引:0,他引:3
为了解兰州市大气污染的情况,选择兰州市的主要绿化树种为研究对象,对叶片中的脯氨酸含量进行了测定,并且运用Statistica6.0软件进行分析.结果表明同一树种在不同污染区的脯氨酸含量不同,存在极显著性的差异,同一污染区的各种绿化植物的脯氨酸含量也存在显著性的差异.5种绿化树种的抗污染能力为杨树>小叶黄杨>椿树>国槐>圆柏,兰州市7个污染区的污染程度为兰炼厂区>兰化厂区>橡胶厂>西关>西站>交大>兴隆山.研究结果可以为兰州市的大气污染治理提供理论和实践依据. 相似文献
463.
内置渗透墙型生态塘处理农村生活污水的研究 总被引:1,自引:0,他引:1
通过在传统的生态塘中增设了一道活性渗透墙而改造成的内置渗透墙型生态塘。结果表明,内置渗透墙型生态塘对生活污水具有良好的处理效果,在水力负荷为0.05~0.1m^3/m^2·d之间时,即水力停留时间在10d~20d时,它对COD的去除率在60%以上,对TN的去除率在50%以上,对TP的去除率在75%以上。大大减轻了后序工艺的负担,减少了后序处理设施。从而缩小了整个生态塘系统的占地面积,节省了基建投资,是一种高效的适合农村生活污水处理的技术。 相似文献
464.
465.
Effects of 5-year application of municipal solid waste compost on the distribution and mobility of heavy metals in a Tunisian calcareous soil 总被引:2,自引:0,他引:2
Walid Ben Achiba Noureddine Gabteni Abdelbasset Lakhdar Gijs Du Laing Marc Verloo Naceur Jedidi Tahar Gallali 《Agriculture, ecosystems & environment》2009,130(3-4):156-163
It is obvious that the application of solid waste compost improves the soil fertility. These wastes, however, may also have some negative effects on the agricultural environment due to their metal content. This research aimed at evaluating the influence of Tunisian municipal solid waste compost and farmyard manure on some chemical properties and the distribution of heavy metals in a calcareous Tunisian soil (clayey–loamy soil). A field plot experiment, without vegetation, was installed since 1999 at the experimental farm of the Agronomic National Institute of Tunis (INAT) in the region of Mornag (20 km south of Tunis, Tunisia). During 5 years, the field received yearly the following treatments: 0, 40, 80 and 120 t/ha of municipal solid waste compost and 0, 40 and 120 t/ha of manure. The fractionation of heavy metals in the soil was evaluated after 5 years using a sequential extraction procedure. The application of the two amendments was found to increase the content of organic matter, the total nitrogen content and the electrical conductivity, whereas it slightly decreased the soil pH. The addition of manure did not have a significant effect on the accumulation of heavy metals in the soil, whereas compost application increased the total concentration of heavy metals in the soil. The distribution of heavy metals between the different fractions in untreated and treated soils showed the residual fraction to be dominant, followed by the fraction bound to Fe and Mn oxides. The amount of Cu bound to the organic fraction increased with the application rate, which is probably caused by the formation of organic complexes. For the other metals, the increase of the association with organic matter is very limited. The application of compost moreover increases the amount of Zn associated with Fe and Mn oxides. The “Mobility Factor (MF)” was quite low and did not change after the 5-year application of the two organic amendments. It always remained lower than 10%, although for Cd it amounted to 17%. 相似文献
466.
467.
468.
The UV/Ag-TiO2/O3 process was investigated for ballast water treatment using Dunaliella salina as an indicator. Inactivation curves
were obtained, and the toxicity of e uent was determined. Compared with individual unit processes using ozone or UV/Ag-TiO2, the
inactivation e ciency of D. salina by the combined UV/Ag-TiO2/O3 process was enhanced. The presence of ozone caused an immediate
decrease in chlorophyll a (chl-a) concentration. Inactivation e ciency and chl-a removal e ciency were positively correlated with
ozone dose and ultraviolet intensity. The initial total residual oxidant (TRO) concentration of e uent increased with increasing ozone
dose, and persistence of TRO resulted in an extended period of toxicity. The results suggest that UV/Ag-TiO2/O3 has potential for
ballast water treatment. 相似文献
469.
The biosorption characteristics of Cs(I) ions from aqueous solution using exopolymers (PFC02) produced from Pseudomonas
fluorescens C-2 were investigated as a function of pH, biosorbent dosage, contact time and initial concentration. pH played a major role
in the adsorption process, and the optimum pH for the removal of Cs(I) was 8.0. Langmuir, Freundlich and Dubinin-Radushkevich (D-R)
models were applied to describe the biosorption isotherm of the Cs(I) ions by PFC02. The Lagergren first-order, pseudo second-order
kinetic and intraparticle diffusion models were used to test the kinetic data. Langmuir model and D-R model fitted the equilibrium data
better than the Freundlich isotherm. The monolayer adsorption capacities of PFC02 as obtained from Langmuir isotherm at 25°C was
found to be 32.63 mg/g. From the D-R isotherm model, the mean free energy was calculated as 26.73 kJ/mol, indicating that the
biosorption of cesium was chemisorption. The biosorption process was rapid, and the kinetic rates were best fitted to the pseudo
second-order model, which indicated the biosorption process operated through chemisorption mechanism. FT-IR analysis of PFC02
showed the possible functional groups responsible for cesium adsorption were hydroxyl, carboxyl, carbonyl and sulphonate groups.
SEM analysis showed the porous structure of the material while EDX analysis confirmed the adsorption of Cs(I) on PFC02. Cesium
adsorbed onto the PFC02 could be desorbed efficiently using 1 mol/L HNO3, and the enrichment factor was 50.0. Furthermore, PFC02
could be reused five times with only about 8.25% regeneration loss. The developed method was successfully utilized for the removal of
Cs(I) ions from aqueous solution. 相似文献
470.
A numerical study of Reciprocating Superadiabatic Combustion of Premixed gases in porous media (hereafter, referred to as RSCP) is performed. In this system the transient combustion of methane-air mixture is stabilized in a porous media combustor by periodically switching flow directions. The mass, momentum, energy and species conservation equations are solved using a two-dimensional control volume method. Local thermal non-equilibrium between the gas and the solid phases is considered by solving separate energy equations for the two phases and coupling them through a convective heat transfer coefficient. The porous media is assumed to emit, absorb and isotropically scatter radiation. The influences of the dominating operating parameters, such as filtration velocity, equivalence ratio and half cycle on the temperature profile, heat release rate, radiant flux, radiant efficiency and combustion efficiency are discussed. The results show that coupling calculating of flow field, combustion reaction and volume radiation of the optically thick media is successively achieved and heat radiation plays an important role in the overall performance of the burner. The temperature profile inside the RSCP combustor has a typical trapezoidal shape and the profile of radiation flux is similar to sinusoidal shape. Compared with the conventional premixed combustion in porous medium, combustion behavior in RSCP combustor is superior, such as better thermal structure and higher radiation efficiency and combustion efficiency. 相似文献