Sonocatalytic degradation of butylparaben in aqueous phase over Pd/C nanoparticles

Environmental Science and Pollution Research - In the present work, the sonocatalytic degradation of butylparaben was investigated using Pd immobilized on carbon black as the sonocatalyst. The...     

Modeling of non-point source pollution in a Mediterranean drainage basin

SWAT ver. 2000 was used to predict hydrographs, and sediment, nitrate and total phosphorus loadings from a 1349 km² mountainous/agricultural watershed in Northern Greece. The model was calibrated and verified using continuous meteorological data from eight stations within the drainage area, and runoff, sediment and nutrient concentrations measured at nine stations located within the main tributaries of the watershed, for the time period from May 1st, 1998 to January 31st, 2000. Model validation methodology and resulting input parameters appropriate for Mediterranean drainage basins are presented. Predicted by the model hydrographs, sedimentographs and pollutographs are plotted against observed values and show good agreement. Model performance is evaluated using the root mean square error computation and scattergrams of predicted versus observed data. The validated model is also used to test the effectiveness of three alternative cropping scenarios in reducing nutrient loadings from the agricultural part of the watershed. The study showed that this model, if properly validated, can be used effectively in testing management scenarios in Mediterranean drainage basins.     

INTEGRATING HUMANS IN ECOSYSTEM MANAGEMENT USING MULTI‐CRITERIA DECISION MAKING1

ABSTRACT: The Ecosystem Management (EM) process belongs to the category of Multi‐Criteria Decision Making (MCDM) problems. It requires appropriate decision support systems (DSS) where “all interested people” would be involved in the decision making process. Environmental values critical to EM, such as the biological diversity, health, productivity and sustainability, have to be studied, and play an important role in modeling the ecosystem functions; human values and preferences also influence decision making. Public participation in decision and policy making is one of the elements that differentiate EM from the traditional methods of management. Here, a methodology is presented on how to quantify human preferences in EM decision making. The case study of the National Park of River Nestos Delta and Lakes Vistonida and Ismarida in Greece, presented as an application of this methodology, shows that the direct involvement of the public, the quantification of its preferences and the decision maker's attitude provide a strong tool to the EM decision making process. Public preferences have been given certain weights and three MCDM methods, namely, the Expected Utility Method, Compromise Programming and the Analytic Hierarchy Process, have been used to select alternative management solutions that lead to the best configuration of the ecosystem and are also socially acceptable.     

Assessment of Aquifer Vulnerability in an Agricultural Area in Spain Using the DRASTIC Model

The assessment of aquifer vulnerability is a very important task, especially in agricultural areas because the quality and availability of groundwater affects both the sustainability of agriculture and the quality of life. In this study, an integrated approach is considered, with the use of the generic and agricultural DRASTIC models as well as a geographic information system (GIS), to assess groundwater vulnerability in the agricultural area of Barrax, in the province of Albacete, in Spain. Seven parameters—depth to water, net recharge, aquifer media, soil media, topography, impact of vadose zone media, and hydraulic conductivity of the aquifer (DRASTIC)—have been considered as weighted layers to enable an accurate groundwater risk mapping. The results of the generic DRASTIC model indicated very low vulnerability to contamination for Barrax groundwater due to limited urban and industrial development in the wider area. However, agricultural activities impose pressure to groundwater resources and the results of the agricultural DRASTIC model show that 6.86% of the study area is characterized by very high, 2.29% by high, 47.28% by medium, 38.28% by low, and the remaining 5.29% by no vulnerability to groundwater contamination. The distribution of nitrate concentration in groundwater in the area under study is quite well correlated with the agricultural DRASTIC vulnerability index. Sensitivity analysis was also performed to acknowledge statistical uncertainty in the estimation of each parameter used, to assess its impact, and thus to identify the most critical parameters that require further investigation. Depth to water and impact of vadose zone are the parameters that had the most noticeable impact on the generic DRASTIC vulnerability index followed by the soil media and topography. In contrast, the agricultural DRASTIC method is more sensitive to the removal of the depth to water parameter followed by the topography and the soil media parameters.     

Sediment and Suspended Matter Lead Contamination in the Gulf of Kavala, Greece

Sediment and suspended particulate matter samples from 24 stations in the Gulf of Kavala have been examined for lead contamination. Grain size analysis and organic matter content were also performed. Total – anthropogenic sediment lead concentrations and enrichment factors at stations close to harbors and chemical industries were found higher (up to 209–135μg/g and 4.12 respectively), in relation to concentrations from the rest of the coastal zone. In the above areas, increased suspended particulate lead in the bottom of the water column was also recorded (up to 109μg/g). Total sediment lead concentrations composed of high natural Pb background increased with decreasing grain size, suggesting their association with the fine fractions of the sediments (31.1–66.0% mud presence) and the organic matter content (6–9% higher values). Overall, higher total lead concentrations in the sediments, determined by this work, appear to be significantly different from those reported for the Gulf of Kavala in previous studies and similar to those detected in other highly contaminated eastern Mediterranean coastal areas.     

Effects of low concentration biodiesel blend application on modern passenger cars. Part 1: Feedstock impact on regulated pollutants, fuel consumption and particle emissions

Five biodiesels from different feedstocks (rapeseed, soy, sunflower, palm, and used fried oils) blended with diesel at 10% vol. ratio (B10), were tested on a Euro 3 common-rail passenger car. Limited effects (−2% to +4%) were observed on CO₂ emissions. CO and HC emissions increased between 10% and 25% on average, except at high speed - high power where emissions were too low to draw conclusions. NOx emissions increased by up to 20% for two out of the five blends, decreased by up to 15% for two other blends, and remained unchanged for one blend. Particulate matter (PM) was reduced for all blends by up to 25% and the reductions were positively correlated with the extent of biodiesel saturation. PM reductions are associated with consistent reductions in non-volatile particle number. A variable behaviour in particle number is observed when volatile particles are also accounted.     

Short-term exposure of the European sea bass Dicentrarchus labrax to copper-based antifouling treated nets: Copper bioavailability and biomarkers responses

We studied if the levels of copper released from antifouling treated nets used in finfish mariculture could affect the immune defense mechanism and/or induce oxidative stress in Dicentrarchus labrax, after short term exposure in laboratory experiments. Dissolved copper concentration released from the treated nets, copper bioavailability and a set of biomarkers responses were measured. Biomarkers included hemoglobin concentration, activities of lysozyme, total complement, respiratory burst, glutathione S-transferase and acetycholinesterase and concentration of thiobarbituric acid reactive substances. Results indicated elevated copper concentration in seawater (184 μg L⁻¹) but low concentration in muscle (1.5 μg g⁻¹) and liver (117 μg g⁻¹). Copper bioavailability was independent of copper complexes with dissolved organic carbon. However, formation of copper complexes with other matrices could neither be excluded nor justified. The released copper from the treated nets did not induce oxidative stress but affected the immediate immune defense mechanism of the exposed fish making them more easily vulnerable to diseases. Consequently, copper-based antifouling treated nets could be a risk factor for D. labrax health.     

Suspended particulate matter estimates using optical and acoustic sensors: application in Nestos River plume (Thracian Sea,North Aegean Sea)

The present study investigates the use of combined methods of optical and acoustic sensors, in collaboration with direct in situ measurements, for the calibration and validation of a model transforming acoustic backscatter intensity series into suspended particulate matter (SPM) concentration datasets. The model follows previously elaborated techniques, placing particular attention to the parameterization of the acoustic absorption index as a function of water physical properties. Results were obtained from the annual deployment (during 2007–2008) of an upward-facing acoustic Doppler current profiler (ADCP) (307 kHz), equipped with a Wave Array, and an optical backscatter sensor (OBS), at the bottom of Thassos Passage near Nestos River plume (Thracian Sea, Northern Greece). The OBS was calibrated through linear regression, using 2007 and 2012 field sampling data, exhibiting an error of 13–14 % due to chlorophyll presence. The ADCP signal was calibrated through simultaneous measurements of backscatter intensity and turbidity profiles. Harmonic analysis on the model-produced SPM concentrations explained the tidal influence on their variability, especially during the summer. Empirical orthogonal functions analysis revealed the impact of waves and wave-induced currents on SPM variability. Finally, Nestos River sediment load was found uncorrelated to the SPM change in Thassos Passage, due to the dispersal and sediment deposition near the river mouth.     

Influence of Building Density and Roof Shape on the Wind and Dispersion Characteristics in an Urban Area: A Numerical Study

The Computational Fluid Dynamics code CFX-TASCflow is used for simulating the wind flow and pollutant concentration patterns in two-dimensional wind-tunnel models of an urban area. Several two-dimensional multiple street canyon configurations are studied corresponding to different areal densities and roof shapes. A line source of a tracer gas is placed at the bottom of one street canyon for modelling street-level traffic emissions. The flow fields resulting from the simulations correspond to the patterns observed in street canyons. In particular and in good agreement with observations, a dual vortex system is predicted for a deep flat-roof street canyon configuration, while an even more complex vortex system is evidenced in the case of slanted-roof square street canyons. In agreement with measurement data, high pollutant concentration levels are predicted either on the leeward or the windward side of the street canyon, depending on the geometrical details of the surrounding buildings.     

Effect of first-flush device,roofing material,and antecedent dry days on water quality of harvested rainwater

Environmental Science and Pollution Research - Two rainwater harvesting systems, which included first-flush diversion devices, connected to the roofs of two adjacent buildings, were monitored for...