Modification of CeO2-ZrO2 catalyst by potassium for NOx-assisted soot oxidation

Potassium-modified ceria-zirconia catalyst was synthesized by wetness impregnation method.The ageing treatment was performed in static air at 800°C for 20 hr to evaluate the thermal stability of the catalyst.The catalysts were characterized by X-ray diffraction,BET surface area,oxygen storage capacity,NOx-temperature programmed desorption and soot-temperature programmed oxidation measurements.By introduction of potassium,the maximum soot oxidation rate temperature(Tm) of the ceria-zirconia based catalyst de...     

锡林郭勒盟农村牧区饮用水水质现状

根据锡林郭勒盟环境保护监测站2010年,对全盟13个旗县市区所辖农村牧区的42个饮用水供水点水质监测结果,进行单因子评价和综合评价,研究分析锡盟农村牧区饮用水水质现状及饮用水水质超标的主要原因,提出了相应的改善措施与保护对策。     

N-2运行方式在宁夏电力通信业务中的应用

针对220 kV及以上线路保护、安稳等重要业务通道路由于关联性增加,无法满足运行要求的问题,对现有N-1通信网络运行方式进行分析,提出N-2通信网络路由运行方式安排,以确保安稳及保护等重要业务通道迂回路径的合理性。应用结果表明:N-2运行方式有效降低了宁夏电网安稳及保护通道运行风险,符合目前网络安全稳定运行要求。     

International trade,Chinese foreign direct investment and green innovation impact on consumption-based CO2 emissions: empirical estimation focusing on BRI countries

Environmental Science and Pollution Research - Recently, The literature has directed concern towards the consumption-based carbon emission (CCE), which is adjusted for trade. This study aims to...     

北京市园林植物吸附PM_(10)与SO_2总量及其健康效益

PM10和SO2是目前城市主要的大气污染物,严重危害居民健康。城市园林植物通过叶片和枝干表面能有效吸附大气污染物。采用大气污染物干沉降通量模型和暴露-反应关系模型定量评估了2003年北京市园林植物吸附PM10与SO2总量及其健康效益。北京市园林植物2003年吸附PM1030,415,563～38,019,454kg和SO23,057,173～3,821,466kg,导致减少死亡312～390人,呼吸系统入院286～357.5人,折合经济价值约为280,265,180～350,331,475元,约占国民生产总值的0.7‰～1.0‰。     

壬基酚对多刺裸腹溞连续世代的毒性效应

为探讨典型环境激素壬基酚(nonylphenol,NP)对枝角类浮游动物多刺裸腹溞连续世代的毒性效应,在实验室条件下,暴露连续3个世代(F0、F1、F2)多刺裸腹溞于0.02~0.10 mg·L-1的NP。15 d后测定成体死亡率、首胎繁殖时间、后代数目、成体蜕皮次数以及终点体长。研究结果表明,NP对F0代多刺裸腹溞具有很高的致死率;随着世代的增加,在相同NP质量浓度暴露下,与母代成体的死亡率相比,子代多刺裸腹溞成体的死亡率增高,致死毒性放大;NP对多刺裸腹溞连续3个世代的繁殖力都有显著抑制作用(P0.05),并随着世代递增,NP对子代繁殖力的抑制增强;在NP暴露下,多刺裸腹溞F0首胎繁殖时间明显推迟,NP暴露浓度与延迟程度呈正相关,呈现出剂量-效应关系,首胎繁殖时间延迟的趋势也存在于F1、F2世代中且存在放大效应;但是连续3个世代多刺裸腹溞成体的蜕皮次数都不受NP暴露影响;F0和F1世代多刺裸腹溞终点体长降低,并呈现明显的剂量-效应关系,但与F1相比,F2低浓度处理组受试个体终点体长呈增加趋势。对结果进行分析,认为多刺裸腹溞在NP暴露后的母代DNA或DNA完整性遭到破坏导致子代在相同NP质量浓度暴露下更容易受到NP致死性的影响;NP化合物具有的苯酚结构抑制枝角类体内葡萄糖、硫酸盐与类固醇的结合,从而引起体内荷尔蒙水平异常,最终对诸如生殖等生理行为造成不利影响;多刺裸腹溞成体的蜕皮次数都不受NP暴露影响表明蜕皮激素系统未受到干扰,且NP对生长的影响显然存在蜕皮外的其他作用机制。     

Dynamic risk assessment of oil spill scenario for Three Gorges Reservoir in China based on numerical simulation

A novel method for dynamic risk assessment of oil spill accidents based on numerical simulation was presented in this paper. The dynamic risk assessment model was developed consisting of a comprehensive list of caused consequences like environmental damage, asset loss, health impact and social effect as well as emergency actions preventing these losses. Contributing events in the Mater Logic Diagram (MLD) of the dynamic risk assessment model were valued based on the simulated evolvement of oil contaminants under spill scenario on quasi-static fluid, which was obtained by coupling an oil spill model with hydrodynamic module in Jialing river of Three Gorges Reservoir in China after the impoundment of the reservoir to 175 m water level in 2010. Calculated result of dynamic risk as grade IV indicated that the assessed oil spill was not as catastrophic as we thought because of the slow transport of oil fractions on water surface and absence of dispersed oil in water body due to the quasi-static fluid, very gentle wind and effective emergency actions, as well as by the reason that rare agriculture or industrial crops exist in spill adjacent area.     

三峡库区新生消落区沉积物磷形态分析

通过分析三峡库区新生典型消落区上覆水及沉积物中磷的赋存形态,揭示消落区沉积物中磷的分布特征和释放规律. 结果表明,不同类型的新生消落区沉积物磷的分布特征与消落区类型、原有使用背景、临时性使用情况等因素有关. 消落区类型对消落区上覆水ρ(总磷)的影响较弱. 消落区沉积物w(活性磷)与淹没状态相关,由露出到淹没状态活性磷逐渐减少,沉积物中w(钙磷)和w(闭蓄态磷)相对较恒定. 受水陆交替非稳态环境因素的影响,水陆交替沉积物w(总磷)相对较低. 消落区沉积物与上覆水中磷的迁移、转化主要以活性磷的释放和沉积为主.      

Fenton氧化法处理生物性污染废水

采用Fenton氧化法对经化学混凝沉淀处理后的生物性污染废水进行深度处理,通过正交试验和单因素实验,研究H2O2投加量、溶液pH值、反应时间和H2O2/Fe2+2(摩尔比)四个主要因素对有机污染物去除效果的影响.实验结果表明H2O2投加量的影响明显高于其它三个因素,影响能力从大到小依次排序为:H2O2投加量＞溶液pH＞反应时间＞H2O2/Fe2+,反应的最佳工艺条件为:H2O2投加量为0.088mol.l-1,溶液pH值在3.5左右,反应时间为4h,H2O2/Fe2+为20:1.在此条件下,经Fenton氧化法深度处理后的出水细菌总数和三磷酸腺苷均未检出,保障出水的生物卫生安全性;同时其相对抑光率为10%,属低水平毒性.此外,其化学需氧量小于76mg·l-1,氨氮、总氮、总磷分别为1.10mg·l-1,2.92mg·l-1和0.002mg·l-1,出水满足<城镇污水处理厂污染物排放标准(GB8918-2002)>一级B标准.     

重金属含量对城市土壤真菌群落结构的影响

作为土壤微生物系统的一个重要组成部分,真菌可以明显地对土壤环境的变化起到指示作用;城市中的人为活动很容易影响到土壤状况,因此城市土壤往往有人为重金属富集现象的出现.对城市内部不同功能区土壤中的真菌群落结构进行分析,旨在探明城市内部不同功能区中重金属含量对土壤真菌群落结构的影响,为城市土壤生态系统的修复与保护和城市环境质...