全氟辛烷磺酸在大连区域环境多介质中的归趋模拟

阐明污染物的环境归趋对于其污染控制和生态风险评价具有重要意义。本文构建了三级环境多介质逸度模型,研究全氟辛烷磺酸(PFOS)在大连区域环境多介质中的分布及其迁移规律。结果表明,PFOS在大气、水、土壤和沉积物相的模拟浓度分别为5.10 pg·m-3、22.60 ng·L-1、2.25μg·kg-1和0.34μg·kg-1,与实测值较为一致。环境相间的迁移主要是大气向土壤中迁移和土壤向水中的迁移,水和土壤是大连区域PFOS的主要的汇。PFOS在大气和水相的平流输入为主要的污染来源,而大气的平流输出是其主要的输出途径。灵敏度分析表明,有机碳分配系数、溶解度、水和气相平流输入、土壤中水的径流速率以及温度是影响模型结果的主要参数。不确定分析则表明,整体参数的变化对水体输出结果影响最大,对沉积物影响最小。本研究较好地模拟了PFOS在大连区域环境多介质中的迁移和归趋,可为其污染控制和生态风险评价提供科学依据。     

盐酸-次氯酸钙氧化法去除贫泥磷中的黄磷

分别采用次氯酸钙单一体系和盐酸-次氯酸钙复合体系对贫泥磷中的黄磷进行氧化处理,重点考察了盐酸浓度、次氯酸钙加入量、反应温度和反应时间等因素对贫泥磷中黄磷去除率的影响。实验结果表明:与单一次氯酸钙体系相比,盐酸的加入有效地破除了贫泥磷中的胶质结构,盐酸-次氯酸钙复合体系能有效地去除贫泥磷中的黄磷;在反应温度为60℃、盐酸浓度为2.4 mol/L、破胶反应时间为30 min、次氯酸钙加入量为250 g/L、氧化反应时间为3 h的最佳条件下,黄磷的去除率达到99.6%以上。     

Evaluation of leachate recirculation on nitrous oxide production in the Likang Landfill,China

Landfill leachate recirculation is efficient in reducing the leachate quantity handled by a leachate treatment plant. However, after land application of leachate, nitrification and denitrification of the ammoniacal N becomes possible and the greenhouse gas nitrous oxide (N2O) is produced. Lack of information on the effects of leachate recirculation on N2O production led to a field study being conducted in the Likang Landfill (Guangzhou, China) where leachate recirculation had been practiced for 8 yr. Monthly productions and fluxes of N2O from leachate and soil were studied from June to November 2000. Environmental and chemical factors regulating N2O production were also accessed. An impermeable top liner was not used at this site; municipal solid waste was simply covered by inert soil and compacted by bulldozers. A high N2O emission rate (113 mg m-2 h-1) was detected from a leachate pond purposely formed on topsoil within the landfill boundary after leachate irrigation. A high N2O level (1.09 micrograms L-1) was detected in a gas sample emitted from topsoil 1 m from the leachate pond. Nitrous oxide production from denitrification in leachate-contaminated soil was at least 20 times higher than that from nitrification based on laboratory incubation studies. The N2O levels emitted from leachate ponds were compared with figures reported for different ecosystems and showed that the results of the present study were 68.7 to 88.6 times higher. Leachate recirculation can be a cost-effective operation in reducing the volume of leachate to be treated in landfill. However, to reduce N2O flux, leachate should be applied to underground soil rather than being irrigated and allowed to flow on topsoil.     

珍稀濒危植物保护政策初探

本文根据我国珍稀濒危植物的保护现状和管理工作中存在的问题,系统地探讨了加强我国珍稀濒危植物和野生植物资源保护的政策措施。文中提出一系列具体、有效的政策构思,以及建立政府有关主管部门对珍稀濒危植物协调管理的体制等。     

蒽醌染料生产废水处理工艺研究

采用脱硫、混合初沉、微电解、中和沉淀、催化氧化、混凝沉淀、生化工艺，可以对蒽醌染料生产废水进行有效的处理，COD（平均值）可从66000mg/L以上降至96mg/L左右，色度（平均值）可从8000倍降至90倍以下，基本可以实现达标排放。     

Global Trade in GM Food and the Cartagena Protocol on Biosafety: Consequences for China

The UN Cartagena Protocol onBiosafety adopted in Montreal, 29 January, 2000and opened for signature in Nairobi, 15–26 May,2000 will exert a profound effect oninternational trade in genetically modifiedorganisms (GMOs) and their products. In thispaper, the potential effects of variousarticles of the Protocol on international tradein GMOs are analyzed. Based on the presentstatus of imports of GMOs and domestic researchand development of biotechnology in China,likely trends in imports of foreign GM food andrelated products after China accedes to WTO isexplored. Also, China's potentialcountermeasures to control and regulate importsof GMOs in line with implementation of theProtocol are discussed. China, in recent times,has increased its food and agricultural importssubstantially from USA and Canada. Chinaimported soybean 10.42 mill. tons in 2000 andabout 15 mill tons in 2001, of which majorityare from USA where GM soybean accounts for60%. The plantation of US Monsanto'stransgenic Bt cotton was increased to more than1 million ha in China in 2001. Though China haspaid great attention to develop biotechnology,it appears to have little scope to export GMOsand GM products. So China may consider a rangeof administrative measures to implement theCartagena Protocol and to regulate its importof GMOs and GM agricultural products.Consequently, the Regulation on Safety ofAgri-GMOs was issued on June, 2001 and followedthree detailed rules issued in Jan. of 2002,with a priority to limit foreign GMOs importingby safety certification and labeling system.These were outlined taking into accountpolicies adopted in Western countries such asgreen barriers to international trade.     

机组行为、时间余量与飞行安全间的关系探讨

探讨机组行为、时间余量与飞行安全间的关系，为航空公司的机组训练和避免飞行事故及飞行事故征候的发生提供帮助。利用1996—2000年中国民用航空总局航空安全办公室下发的“飞行事故、航空地面事故和飞行事故征候统计的通知”中的资料，找出因机组行为错误导致的、与解决问题的时间余量关系密切的飞行事故和飞行事故征候案例。与飞行专家进行研讨和分析，探求飞行事故及其征候的发生与机组行为和时间余量间的关系。找出了因机组行为错误导致的、与解决问题的时间余量关系密切的飞行事故11起和飞行事故征候133起。其中因机组疏于监控飞机设备和状况、未发现问题存在或未明确所发生的问题的性质而无作为，使得解决问题的时间余量为零或接近零，从而无时间解决出现的问题，导致飞行事故3起和飞行事故征候96起；因机组发现问题存在并在明确所发生的问题的性质后，在一定时间余量内未能突破思维惯性的影响，做出了错误的决策，未能解决所发现的问题，导致飞行事故8起和飞行事故征候37起。飞行事故和飞行事故征候的发生与机组行为和时间余量的关系是，机组行为可以决定时间余量剩余的多少，时间余量的多少反过来决定机组采取何种措施解决当前的问题才能避免飞行事故和飞行事故征候的发生。     

温室效应与全球变化（三）：全球碳循环与人为二氧化碳排放的控制

本文综述了全球碳循环的现状及人类活动对它的影响，指出人为释放大量的二氧化碳又不使大气中二氧化碳浓度升高是不可能的，人为促进海洋光合作用的增加和在陆地上植树造林在控制大气二氧化碳浓度上升上所能起的作用也是有限的。只有在不放慢经济发展的速度，不降低能源总有效消费量的情况下，努力减少人为二氧化碳的排放才是现实的。本文探讨了这一途径在技术上的可能性。     

温室效应与全球变化（四）：通过国际谈判与合作减少全球人为二氧化碳的排放

在限制人为二氧化碳的排放以控制全球变化的问题上，发达国家与发展中国家之间存在着尖锐的利益冲突。目前，大气中人为增加的二氧化碳绝大中份是发达国家在过去１５０年内排放的。它们目前的排放量仍占全球人为排放量的四分之三。发展中国家在经济发展过程中不可避免地要增加二氧化碳的排放量，这是它们正当的发展权利。作者讨论了各种限制人为二氧化碳排放的国际协定方案，认为可交易的二氧化碳排放许可证制度是比较现实的方案。     

井下作业清洁生产的影响因素及综合治理措施

以江苏油田为例,从油水井维修前期、维修中期、污染物后续处理等方面分析了影响井下作业清洁生产的主要因素,介绍了该油田井下作业实施清洁生产的综合措施及井下作业清洁生产新工艺、新技术的基本原理。该油田在井下作业中实施了污油污水资源化处理技术,取得了较好的效果。此项技术对于石油企业推行清洁生产具有借鉴意义与推广价值。