全文获取类型
收费全文 | 611篇 |
免费 | 3篇 |
国内免费 | 3篇 |
专业分类
安全科学 | 9篇 |
废物处理 | 43篇 |
环保管理 | 44篇 |
综合类 | 53篇 |
基础理论 | 129篇 |
环境理论 | 1篇 |
污染及防治 | 250篇 |
评价与监测 | 54篇 |
社会与环境 | 29篇 |
灾害及防治 | 5篇 |
出版年
2023年 | 6篇 |
2022年 | 21篇 |
2021年 | 30篇 |
2020年 | 12篇 |
2019年 | 14篇 |
2018年 | 21篇 |
2017年 | 27篇 |
2016年 | 31篇 |
2015年 | 27篇 |
2014年 | 36篇 |
2013年 | 59篇 |
2012年 | 57篇 |
2011年 | 59篇 |
2010年 | 34篇 |
2009年 | 29篇 |
2008年 | 31篇 |
2007年 | 29篇 |
2006年 | 27篇 |
2005年 | 17篇 |
2004年 | 13篇 |
2003年 | 5篇 |
2002年 | 6篇 |
2001年 | 4篇 |
2000年 | 1篇 |
1999年 | 6篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1994年 | 4篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1987年 | 1篇 |
1958年 | 3篇 |
排序方式: 共有617条查询结果,搜索用时 421 毫秒
101.
Ofelia Morton-Bermea Omar Amador-Muñoz Lida Martínez-Trejo Elizabeth Hernández-Álvarez Laura Beramendi-Orosco María Elena García-Arreola 《Environmental geochemistry and health》2014,36(5):987-994
The increase in platinum (Pt) in the airborne particulate matter with size ≤2.5 µm (PM2.5) in urban environments may be interpreted as result of the abrasion and deterioration of automobile catalyst. Nowadays, about four million vehicles in Mexico City use catalytic converters, which means that their impact should be considered. In order to evaluate the contribution of Pt to environmental pollution of the metropolitan area of Mexico City (MAMC), airborne PM2.5 was collected at five different sites in the urban area (NW, NE, C, SW, SE) in 2011 during April (dry-warm season), August (rainy season) and December (dry-cold season). Analytical determinations were carried out using a ICP-MS with a collision cell and kinetic energy discrimination. The analytical and instrument performance was evaluated with standard road dust reference material (BCR-723). Median Pt concentration in the analyzed particulate was is 38.4 pg m?3 (minimal value 1 pg m?3 maximal value 79 pg m?3). Obtained Pt concentrations are higher than those reported for other urban areas. Spatial variation shows that SW had Pt concentration significantly higher than NW and C only. Seasonal variation shows that Pt median was higher in rainy season than in both dry seasons. A comparison of these results with previously reported data of PM10 from 1991 and 2003 in the same studied area shows a worrying increase in the concentration of Pt in the air environment of MAMC. 相似文献
102.
Diego S. Fernández María E. Puchulu Sergio M. Georgieff 《Environmental geochemistry and health》2014,36(3):489-503
Landfills constitute potential sources of different pollutants that could generate human health and environmental problems. While some landfills currently work under the protection of a bottom liner with leachate collection, it was demonstrated that migration could take place even yet with these cautions. The purpose of this paper is to assess the pollution caused by a leachate plume from a municipal landfill that is affecting both groundwater and surface waters. The research was carried out at Pacará Pintado landfill in northwestern Argentina. Analysis of water samples indicates that leachate is affecting groundwater under the landfill area and an abandoned river channel hydraulically connected. In the center of the landfill area, the plume is anoxic and sulfate, nitrate, iron and manganese reduction zones were identified. Leachate plume presented high concentration of organic matter, Fe, Mn, NH4 +, Cl? and Cr reaching an extension of 900 m. The presence of a leachate plume in a landfill site with a single liner system implies that the use of this groundwater pollution control method alone is not enough especially if permeable sediments are present below. 相似文献
103.
Singlet molecular oxygen—mediated photooxidation of monochloro and mononitrophenols. A kinetic study
A kinetic and mechanistic study on the aerobic dye sensitized photooxidation of the mono—nitro and chlorophenols was carried out. A singlet molecular oxygen mechanism operates in the photooxidation. Solvent and substituent effects, suggest the intermediacy of a complex with partial charge transfer character, as has been postulated for other phenols. Chemical (reactive) and physical interactions of the substrates with singlet molecular oxygen were discriminated. Quantum yields for photooxidation (higher for the chlorophenols) range from 3 × 10‐2 to 2 × 10‐3, as measured by substrate or oxygen consumption. These values indicate the viability of a singlet molecular oxygen photooxidation as a way for the degradation of nitro and chlorophenol environmental contaminants. 相似文献
104.
E. T. Romero-Guzmán L. R. Reyes-Gutiérrez M. J. Marín-Allende Z. I. González-Acevedo M. T. Olguín-Gutiérrez 《Chemistry and Ecology》2013,29(5):459-475
Eichhornia crassipes (Ec) and Lemna minor (Lm) are aquatic plants. They are considered as weeds of the water and approach being a scourge in many parts of the world, choking waterways and hindering transport upon them. At the same time they are known to readily remove heavy metal ions from water. This paper considers the use of non-living plants as novel and inexpensive biosorbent for the removal of As(V) from watersheds. In the first place they were conditioned and characterised to determine their physicochemical and surface properties and in the second place their adsorption properties for As(V) from aqueous solution were evaluated considering the toxicity of this metalloid in the environment. It describes the methodology to prepare the non-living biomasses; the physicochemical characterisation by SEM, XRD, FTIR, TGA analyses and surface characterisation of Ec and Lm by specific surface, hydration kinetic, point of zero charge determination by mass titration, active site density and XPS analysis are described. Both studied biomasses were found to be potential bio-sorbents for arsenic ions from aqueous solution. According to their efficiency to remove arsenic, they can be used in a very low cost metalloid ions removal system. 相似文献
105.
José L. Mateos Paloma Fernández Del Pino Francisco J. Gutiérrez Mañero María Ruiz Palomino Juan J. Colon José A. Lucas García 《Chemistry and Ecology》2013,29(2):125-152
Microbial communities (phospholipid fatty acid pattern, bacterial growing strategies, eco-physiological index (EPI) and total bacteria counts, as a number of heterotrophic cuhurable bacteria), substrate-induced respiration (SIR), and nitrogen mineralization were studied in three Mediterranean soils at three different depth levels (A, B and C). Soils were experimentally treated with a final concentration of 1000 ppm of trace metals (Cu2+, Zn2+, Al3+, Fe2+, Pb2+, Ni2+, Mn2+, Cr3+ and Cd2+). Soils were stored in 571 plastic containers for one year, and watered with 1001 during this period. Leachate was recovered through a bottom tap. Samples of the three depths were studied. Soil microbial communities showed different effects to other studies presented in the literature, but carried out on non-Mediterranean soils. Dramatic differences were found between treated soils and untreated ones, but not between soils or horizons. the treated soil displayed a decrease in CFUs, SIR N-mineralization and EPI together with a dominance of r-growing strategists. the relative moles percent of several PLFAs, especially 15:0, 16: 1ω7, cy17: 0, br18:0 and 18: 1ω7 decreased because of the pollution of soils, whereas 10Me16, 18:2ω6, cy19:0, i16:0 and br17:0 showed higher values than in untreated soils. 相似文献
106.
Copper, iron, lead, manganese, and zinc contents were determined in various phyla of macroalgae typical of the rocky mesolittoral zone of Cuba and widely distributed in the Caribbean Region. the samples were collected in different zones along the shores of Havana City which are more or less influenced by anthropogenic activities. Differences in metal contents were observed due to seasonal variations and differences between sampling sites. of the analyzed species, only one brown alga, Padina vickersiae is considered as a suitable candidate for the monitoring of metal contamination. 相似文献
107.
María Oliveira Rosa M. Crujeiras Alberto Rodríguez-Casal 《Environmental and Ecological Statistics》2013,20(1):1-17
The goal of this work is to introduce nonparametric kernel methods for density and regression estimation for circular data, and illustrate their use by a brief simulation study and real data application. Apart from supplying practitioners with a license free and easy to run code for the use of these methods, our aim is also to provide solutions to practical problems that may be encountered in their application. The real data examples belong to the International Polar Year project, concerned with the environmental change in the polar regions. 相似文献
108.
Manuela Bartel Stefanie Hartmann Karola Lehmann Kai Postel Humberto Quesada Eva E. R. Philipp Katja Heilmann Burkhard Micheel Heiko Stuckas 《Marine Biology》2012,159(10):2195-2207
Sperm proteins of the marine sessile mussels of the Mytilus edulis species complex are models to investigate reproductive isolation and speciation. This study aimed at identifying sperm proteins and their corresponding genes. This was aided by the use of monoclonal antibodies that preferentially bind to yet unknown sperm molecules. By identifying their target molecules, this approach identified proteins with relevance to Mytilus sperm function. This procedure identified 16 proteins, for example, enkurin, laminin, porin and heat shock proteins. The potential use of these proteins as genetic markers to study reproductive isolation is exemplified by analysing the enkurin locus. Enkurin evolution is driven by purifying selection, the locus displays high levels of intraspecific variation and species-specific alleles group in distinct phylogenetic clusters. These findings characterize enkurin as informative candidate biomarker for analyses of clinal variation and differential introgression in hybrid zones, for example, to understand determinants of reproductive isolation in Baltic Mytilus populations. 相似文献
109.
Aldas Miguel Pavon Cristina De La Rosa-Ramírez Harrison Ferri José Miguel Bertomeu David Samper María Dolores López-Martínez Juan 《Journal of Polymers and the Environment》2021,29(8):2686-2700
Journal of Polymers and the Environment - Since biodegradable materials are unwittingly mixed with synthetic materials, this work aimed to study the feasibility of reliably identifying some... 相似文献
110.
Gómara B González MJ Baos R Hiraldo F Abad E Rivera J Jiménez B 《Environment international》2008,34(1):73-78
This study provides information on the current status of contamination by organochlorines (DDTs, PCBs, PCDDs and PCDFs) in the declining red kite (Milvus milvus L.) population breeding in the Do?ana National Park (DNP), south-western Spain. Analyses were performed in addled eggs collected between 1999 and 2001. DDE concentrations ranged from 0.1 to 33.5 microg/g ww, representing more than 86% of the total DDTs. Of the samples studied, 50% showed DDE levels above those associated with reproductive impairment in other raptor species. Concentrations of ortho PCBs (average 36.8 microg/g ww+/-37.7) in 50% of the eggs were much higher than levels reported to cause reduced hatching success, embryo mortality, and deformities in birds (>20 microg/g ww). It is remarkable that average ortho PCB and DDE concentrations showed an increase of one order of magnitude compared to previous data for the species during the 80s. Total PCDD/Fs showed levels in the low pg/g range (7.2-42 pg/g ww), having PCDDs and PCDFs similar contributions in most samples. Total mean TEQs were 238 pg/g (ww), being the range 7.02-667 pg/g (ww). Spatial variation within DNP was observed for PCBs, DDTs, as well as for TEQs. Since some eggs exceeded the NOEL (67%) and LOEL (33%) reported for other raptor species, we would expect the red kite to experience detrimental effects to dioxin-like toxicity. Our results suggest that organochlorine contaminants should be regarded as an element of concern in the population under study, in addition to other conservation problems already reported. Further investigations should be undertaken to identify potential sources of these chemicals in DNP, and to find out if organochlorine contamination is present in other predator species in the area, as well as their potential health effects on individuals and/or populations. 相似文献