Separation and chemical characterisation of specific compounds responsible for soil water repellency has not previously been achieved. Here we describe the extraction, separation and analysis by gas chromatography-mass spectrometry of organic compounds found in wettable and water repellent sandy soils from the Netherlands and United Kingdom. Fatty acids (C16–C24), amides (C14–C24), alkanes (C25–C33), aldehydes/ketones (C23–C31) and complex ring-containing structures were detected in all samples. We found a greater abundance of high molecular mass polar compounds in the water repellent samples. 相似文献
The extent to which aggrieved applicants appeal against planning refusals varies between types of development, between regions and over time. So, too, though in lesser degree, does the extent to which appeals are successful. The paper seeks to explain these variations. It does so by arguing that the appeal rate varies with the support that central government ministers and their inspectors (the Central Planning Authority, CPA) give to the local planning authorities (LPAs), with appeal costs and with applicant and LPA willingness to renegotiate over refused applications. The appeal success rate is seen to be largely independent of the appeal rate and varies with potential appellants’ awareness of CPA policy and with their rationality.
It is concluded that appeal rate differences are best explained in terms of the CPA's support for the LPAs whether consideration is given to applications submitted nationally for different development types, to applications submitted in the eight English regions or to applications submitted in England and Wales over the period since 1974. Thus, CPA support for the LPAs is high in relation to change of use and householder developments but low in relation to development of the other major type; the CPA is less supportive of LPA policy in Yorkshire and Humberside and in East Anglia than in the other English regions, at least in the mid 1980s; and the CPA markedly reduced its support for the LPAs in England and Wales in the early 1980s.
It is also concluded that the low appeal success rate for minor residential development is the result of low appellant rationality, potential appellants being particularly determined to press their proposals against the odds. Appellant awareness of CPA policy and rationality may be comparable for the remaining development types since the appeal success rate shows little variation. Similarly, appellant awareness and rationality may be comparable in the eight English regions. In contrast, the appeal success rate in England and Wales as a whole has increased since 1974 perhaps because potential appellants are now more aware of CPA policy. 相似文献
Chondrus crispus (Stackhouse) is a perennial red seaweed, common in intertidal and shallow sublittoral communities throughout the North Atlantic Ocean. In the intertidal zone, C. crispus may experience rapid temperature changes of 10 to 20C° during a single immerison-emerision cycle, and may be exposed to temperatures that exceed the thermal limits for long-term survival. C. crispus collected year-round at Long Cove Point, Chamberlain, Maine, USA, during 1989 and 1990, underwent phenotypic acclimation to growth temperature in the laboratory. This phenotypic acclimation enhanced its ability to withstand brief exposure to extreme temperature. Plants grown at summer seawater temperature (20°C) were able to maintain constant rates of lightsaturated photosynthesis at 30°C for 9 h. In contrast, light-saturated photosynthetic rates of plants grown at winter seawater temperature (5°C) declined rapidly following exposure to 30°C, reached 20 to 25% of initial values within 10 min, and then remained constant at this level for 9 h. The degree of inhibition of photosynthesis at 30°C was also dependent upon light intensity. Inhibition was greatest in plants exposed to 30°C in darkness or high light (600 mol photons m-2s-1) than in plants maintained under moderate light levels (70 to 100 mol photons m-2s-1). Photosynthesis of 20°C-acclimated plants was inhibited by exposure to 30°C in darkness or high light, but the degree of inhibition was less than that exhibited by 5°C-grown plants. Not only was light-saturated photosynthesis of 20°C plants less severely inhibited by exposure to 30°C than that of 5°C plants, but the former also recovered faster when they were returned to growth conditions. The mechanistic basis of this acclimation to growth temperature is not clear. Our results indicate that there were no differences between 5 and 20°C-grown plants in the thermal stability of respiration, electron transport associated with Photosystems I or II, Rubisco or energy transfer between the phycobilisomes and Photosystem II. Overall, our results suggest that phenotypic acclimation to seawater temperature allows plants to tolerate higher temperatures, and may play an important role in the success of C. crispus in the intertidal environment. 相似文献
ABSTRACT: Precipitation, throughfall, and stream pH were measured weekly over a 27-week period in 1982 on the Little Millseat watershed in eastern Kentucky. The average pH values over the study period were 4.3, 4.9, and 6.4, respectively, indicating significant buffering as water moved from the atmosphere, through the deciduous canopy, and through or over the soil to the stream. Regression analysis demonstrated that the timing and amount of precipitation were important factors influencing the pH of the throughfall. Weekly precipitation and the three-week average precipitation were statistically significant variables, explaining 53 percent of the variance in the observed through- fall pH. Precipitation pH was not a statistically significant variable for this watershed and sampling period. 相似文献
The country estate has a particular place in the English countryside and its contribution to the landscape scene is distinct and valuable. The paper describes an approach to planning a large country estate of parkland, woodland and estate villages in Cheshire. A Reconnaissance Survey led to the Outline Strategy for six ‘landscape types’ discovered on the estate. The Landscape Conservation Plan is described and the crucial importance of conservation measures is emphasised. 相似文献
To accommodate possible parameter changes in time series at times which are not specified in advance, we propose an adaptive procedure for estimating parameters and for forecasting. The mechanism for activating the adaptive procedure is a successively updated change-detection statistic. The statistic has small expected value when no change is present and has large value when change takes place - the larger the change, the larger the statistic. The statistic defines discounting factors which determine how much of the past will be used both for estimating parameters and for forecasting. The change-detection statistic is designed to effect major changes to parameter estimates and to forecasts in a discrete fashion only, as opposed to certain other adaptive procedures that react continuously to perceived fluctuations in data, and so indicate change even when parameters remain fixed. The procedure is illustrated using exponential smoothing and Holt's linear exponential smoothing and is applied to a hydrological series. 相似文献
Against a background of inward investment into the region, the paper examines crucial issues relating to labour. It examines approaches to recruitment and the selection process. Skill shortages and strategies for overcoming the problem are analysed together with a consideration about management and managers. The paper concludes with a detailed assessment of policies relating to training. 相似文献
ABSTRACT: Soil water potentials, slope throughflow, runoff chemistry, and isotopic composition were monitored in a 97 m2 zero-order basin within the Maimai 8 watershed on the South Island of New Zealand, for a natural rain storm and two artificial water applications. Contrary to results previously reported for other portions of the Maimai catchment, much of the runoff occurred as a shallow subsurface organic layer flow. For the 47 mm natural rain event, pre-storm soil matric potential ranged from ?60 to ?150 cm H2O. No saturation was produced within the profile, and the majority of storm runoff emanated from flow within the organic horizon perched on the mineral soil surface. Hillslope applications corroborated this interpretation by showing >90 percent new water flushing with negligible mineral soil moisture response. Although the mechanisms cited in the text are not representative of the entire catchment, the study demonstrates: (1) the value of a combined physical-chemical-isotopic approach in quantifying slope processes, and (2) the heterogeneous nature and diversity of slope runoff pathways in a relatively homogeneous catchment. 相似文献