Baseflow nitrate in relation to stream order and agricultural land use

Management of agricultural nonpoint-source pollution continues to be a challenge because of spatial and temporal variability. Using stream order as an index, we explored the distribution of nitrate concentration and load along the stream network of a large agricultural watershed in Pennsylvania-the East Mahantango Creek Watershed and two of its sub-watersheds. To understand nitrate concentration variation in the stream water contributed from ground water, this study focused on baseflow. Impacts of agricultural land use area on baseflow nitrate in the stream network were investigated. Nitrate concentration showed a general decreasing trend with increasing stream order based on stream order averaged values; however, considerable spatial and temporal variability existed within each snapshot sampling. Nitrate loads increased with stream order in a power function because of the dominant effect of stream flow rate over the nitrate concentration. Within delineated sub-watersheds based on stream orders, positive linear functions were found between agricultural land use area percentage and the baseflow nitrate concentration and between agricultural drainage area and the nitrate load. The slope of the positive linear regression between the baseflow nitrate concentration and percent agricultural land area seems to be a valuable indicator of a watershed's water quality as influenced by agricultural practices, watershed size, and specific physiographic setting. Stream order seems to integrate, to a certain degree, the source and transport aspects of nonpoint-source pollution on a yearly averaged basis and thus might provide a quick estimate of the overall trend in baseflow nitrate concentration and load distribution along complex stream networks in agricultural watersheds.     

Integrating contributing areas and indexing phosphorus loss from agricultural watersheds

Most states in the USA have adopted P Indexing to guide P-based management of agricultural fields by identifying the relative risk of P loss at farm and watershed scales. To a large extent, this risk is based on hydrologic principles that frequently occurring storms can initiate surface runoff from fields. Once initiated, this hydrological pathway has a high potential to transport P to the stream. In regions where hydrologically active areas of watersheds vary in time and space, surface runoff generation by "saturation excess" has been linked to distance from stream, with larger events resulting in larger contributing distances. Thus, storm-return period and P loss from a 39.5-ha mixed-land-use watershed in Pennsylvania was evaluated to relate return-period thresholds and distances contributing P to streams. Of 248 storm flows between 1997 and 2006, 93% had a return period of 1 yr, contributing 47% of total P (TP) export, while the largest two storms (10-yr return period) accounted for 23% of TP export. Contributing distance thresholds for the watershed were determined (50-150 m) for a range of storm-return periods (1-10 yr) from hydrograph analysis. By modifying storm-return period thresholds in the P Index and thereby contributing distance, it is possible to account for greater risk of P loss during large storms. For instance, increasing return period threshold from 1 (current P indices) to 5 yr, which accounted for 67% of TP export, increased the P-management restricted area from 20 to 58% of the watershed. An increase in impacted area relative to a decreased risk of P loss creates a management-policy dilemma that cannot be ignored.     

Investigating habitat value to inform contaminant remediation options: case study

Habitat valuation methods were implemented to support remedial decisions for aquatic and terrestrial contaminated sites at the East Tennessee Technology Park (ETTP) on the US Department of Energy (DOE) Oak Ridge Reservation in Oak Ridge, TN, USA. The habitat valuation was undertaken for six contaminated sites: Contractor's Spoil Area, K-901-N Disposal Area, K-770 Scrapyard, K-1007-P1 pond, K-901 pond, and the Mitchell Branch stream. Four of these sites are within the industrial use area of ETTP and two are in the Black Oak Ridge Conservation Easement. These sites represent terrestrial and aquatic habitat for vertebrates, terrestrial habitat for plants, and aquatic habitat for benthic invertebrates. Current and potential future, no-action (no remediation) scenarios were evaluated primarily using existing information. Valuation metrics and scoring criteria were developed in a companion paper, this volume. The habitat valuation consists of extensive narratives, as well as scores for aspects of site use value, site rarity, and use value added from spatial context. Metrics for habitat value were expressed with respect to different spatial scales, depending on data availability. There was significant variation in habitat value among the six sites, among measures for different taxa at a single site, between measures of use and rarity at a single site, and among measures for particular taxa at a single site with respect to different spatial scales. Most sites had aspects of low, medium, and high habitat value. Few high scores for current use value were given. These include: wetland plant communities at all aquatic sites, Lepomid sunfish and waterbirds at 1007-P1 pond, and Lepomid sunfish and amphibians at K-901 pond. Aquatic sites create a high-value ecological corridor for waterbirds, and the Contractor's Spoil Area and possibly the K-901-N Disposal Site have areas that are part of a strong terrestrial ecological corridor. The only example of recent observations of rare species at these sites is the gray bat observed at the K-1007-P1 pond. Some aspects of habitat value are expected to improve under no-action scenarios at a few of the sites. Methods are applicable to other contaminated sites where sufficient ecological data are available for the site and region.     

Effects of Water Withdrawal From Ice‐Covered Lakes on Oxygen,Temperature, and Fish1

Abstract: In northern regions, large volumes of water are needed for activities such as winter road construction. Such withdrawals, particularly from small lakes, can reduce oxygen concentrations and water levels, potentially affecting aquatic organisms. Withdrawal limits have been developed by regulatory agencies, but are largely theoretical. Water withdrawal thresholds were tested in two small lakes by removing 10% and 20% of their respective under‐ice volumes and comparing oxygen parameters, temperature, over‐wintering habitat, and northern pike (Esox lucius) abundance to reference conditions. Because of a milder winter, oxygen parameters were elevated in reference lakes in the period following withdrawal compared to the prewithdrawal period. The 10% withdrawal resulted in a ?0.2 m shift in the oxygen concentration profile at 4 mg/l in that lake, but had no effect on total volume‐weighted oxygen, or volume of over‐wintering habitat. In contrast, the 20% withdrawal caused 0.7 m reduction in the oxygen concentration profile at 4 mg/l compared to the previous year, a 26% decline in the volume‐weighted oxygen concentration, and a 23% reduction in the volume of over‐wintering habitat compared to prewithdrawal conditions. Water temperatures were slightly (≤ 10%) colder in the upper strata in the year following the withdrawal in both withdrawal and reference lakes. Northern pike abundance was not impacted by water withdrawals in either of the lakes. The results of this study show that the effects of water withdrawal on the parameters investigated reflected the characteristics of the lakes, and would therefore be expected to vary from lake to lake. Policy development to mitigate impacts must therefore reflect the site‐specific nature of water withdrawal.     

The value of coastal wetlands for hurricane protection

Coastal wetlands reduce the damaging effects of hurricanes on coastal communities. A regression model using 34 major US hurricanes since 1980 with the natural log of damage per unit gross domestic product in the hurricane swath as the dependent variable and the natural logs of wind speed and wetland area in the swath as the independent variables was highly significant and explained 60% of the variation in relative damages. A loss of 1 ha of wetland in the model corresponded to an average USD 33,000 (median = USD 5000) increase in storm damage from specific storms. Using this relationship, and taking into account the annual probability of hits by hurricanes of varying intensities, we mapped the annual value of coastal wetlands by 1 km x 1 km pixel and by state. The annual value ranged from USD 250 to USD 51,000 ha(-1) yr(-1), with a mean of USD 8240 ha(-1) yr(-1) (median = USD 3230 ha(-1) yr(-1)) significantly larger than previous estimates. Coastal wetlands in the US were estimated to currently provide USD 23.2 billion yr(-1) in storm protection services. Coastal wetlands function as valuable, selfmaintaining "horizontal levees" for storm protection, and also provide a host of other ecosystem services that vertical levees do not. Their restoration and preservation is an extremely cost-effective strategy for society.     

High-impact conservation: invasive mammal eradications from the islands of western México

Islands harbor a disproportionate amount of the earth's biodiversity, but a significant portion has been lost due in large part to the impacts of invasive mammals. Fortunately, invasive mammals can be routinely removed from islands, providing a powerful tool to prevent extinctions and restore ecosystems. Given that invasive mammals are still present on more than 80% of the world's major islands groups and remain a premier threat to the earth's biodiversity, it is important to disseminate replicable, scaleable models to eradicate invasive mammals from islands. We report on a successful model from western México during the past decade. A collaborative effort between nongovernmental organizations, academic biologists, Mexican government agencies, and local individuals has resulted in major restoration efforts in three island archipelagos. Forty-two populations of invasive mammals have been eradicated from 26 islands. For a cost of USD 21,615 per colony and USD 49,370 per taxon, 201 seabird colonies and 88 endemic terrestrial taxa have been protected, respectively. These conservation successes are a result of an operational model with three main components: i) a tri-national collaboration that integrates research, prioritization, financing, public education, policy work, capacity building, conservation action, monitoring, and evaluation; ii) proactive and dedicated natural resource management agencies; and iii) effective partnerships with academic researchers in Mexico and the United States. What is now needed is a detailed plan to eradicate invasive mammals from the remaining islands in the region that integrates the needed additional financing, capacity, technical advances, and policy issues. Island conservation in western Mexico provides an effective approach that can be readily applied to other archipelagos where conservation efforts have been limited.     

Sorption of nonpolar neutral organic compounds to humic acid-coated sands: contributions of organic and mineral components

The contributions of organic matter and the mineral surface to the overall sorption of six nonpolar neutral organic compounds (1,2,4-trichlorobenzene, 1,4-dichlorobenzene, chlorobenzene, m-xylene, toluene, benzene) by five humic acid (HA)-coated sands with different fractions of organic carbon (f(oc)) ranging from 0.024% to 0.154% were evaluated on the basis of measured data and four different sorption models. Sorption of all six sorbates to both uncoated and heated sands was nearly linear due to the coverage of hydrophilic mineral surface with the ordered vicinal water region. Sorption of all six sorbates to the HA-coated sands was also essentially linear, and resulted from a combination of sorption to both organic matter and the mineral surface, with the dominance of either contribution depending on the properties of the sorbents (e.g., f(oc)) and the sorbates (e.g., K(ow)). A proposed two-component model for sorption including blocking effect was appropriate for quantifying the contributions of organic matter and the mineral surface to the overall sorption. However, conventional sorption models considering the contributions of both organic matter and the mineral surface provided essentially as good agreement between predicted and measured distribution coefficients as the more complicated, two-component model for sorption that takes into account mineral surface blocking by HA.     

Estimating the environmental impact of micro-pollutants in the low Ebro River (Spain): an approach based on screening toxicity with Vibrio fischeri

The aim of this study was to assess the likely impacts on the ecosystems due to agricultural, human, and industrial activities carried out in an ecologically important area of the Ebro River (Spain). For it, a screening site specific ecological risk assessment was conducted. Considering the presence of high levels of potentially toxic substances, such as metals and chlorinated organic compounds, aqueous and organic extracts were used to assess toxicity in sediments by using the photo-luminescent bacteria Vibrio fischeri (Microtox) as screening response variable. Sediment samples collected during 2005-2006 in the last course of the Ebro River and its Delta have been analyzed. Toxic responses have shown strong relationships to the levels of pollutants in the area. Moreover, various sites presented some toxicity level, probably because of other factors associated with reducing environments into the sediments. Results indicate that Microtox bioassay is an appropriate tool to perform risk assessment studies at screening level.     

Effects of long-term soil amendment with sewage sludges on soil humic acid thermal and molecular properties

Sewage sludges are frequently used as soil amendments due to their high contents of organic matter and nutrients, particularly N and P. However, their effects upon the chemistry of soil humic acids, one of the main components of the soil organic matter, need to be more deeply studied in order to understand the relation between organic matter structure and beneficial soil properties. Two sewage sludges subjected to different types of pre-treatment (composted and thermally dried) with very different chemical compositions were applied for three consecutive years to an agricultural soil under long-term field study. Thermal analysis (TG–DTG–DTA) and solid-state ¹³C NMR spectroscopy were used to compare molecular and structural properties of humic acids isolated from sewage sludges, and to determine changes in amended soils. Thermally dried sewage sludge humic acids showed an important presence of alkyl and O/N-alkyl compounds (70%) while composted sludge humic acids comprised 50% aromatic and carbonyl carbon. In spite of important differences in the initial chemical and thermal properties of the two types of sewage sludges, the chemical and thermal properties of the soil humic acids were quite similar to one another after 3 years of amendment. Long-term application of both sewage sludges resulted in 80–90% enrichment in alkyl carbon and organic nitrogen contents of the soil humic acid fraction.