全文获取类型
收费全文 | 739篇 |
免费 | 16篇 |
国内免费 | 7篇 |
专业分类
安全科学 | 27篇 |
废物处理 | 30篇 |
环保管理 | 173篇 |
综合类 | 85篇 |
基础理论 | 171篇 |
污染及防治 | 168篇 |
评价与监测 | 51篇 |
社会与环境 | 51篇 |
灾害及防治 | 6篇 |
出版年
2022年 | 7篇 |
2021年 | 14篇 |
2020年 | 11篇 |
2019年 | 11篇 |
2018年 | 19篇 |
2017年 | 20篇 |
2016年 | 18篇 |
2015年 | 20篇 |
2014年 | 16篇 |
2013年 | 82篇 |
2012年 | 30篇 |
2011年 | 42篇 |
2010年 | 24篇 |
2009年 | 24篇 |
2008年 | 41篇 |
2007年 | 48篇 |
2006年 | 35篇 |
2005年 | 18篇 |
2004年 | 19篇 |
2003年 | 38篇 |
2002年 | 24篇 |
2001年 | 10篇 |
2000年 | 13篇 |
1999年 | 5篇 |
1998年 | 10篇 |
1997年 | 9篇 |
1996年 | 9篇 |
1995年 | 8篇 |
1994年 | 18篇 |
1993年 | 11篇 |
1992年 | 4篇 |
1991年 | 6篇 |
1990年 | 10篇 |
1989年 | 4篇 |
1988年 | 5篇 |
1986年 | 6篇 |
1985年 | 9篇 |
1984年 | 6篇 |
1983年 | 12篇 |
1982年 | 10篇 |
1981年 | 7篇 |
1980年 | 7篇 |
1979年 | 6篇 |
1978年 | 5篇 |
1977年 | 4篇 |
1976年 | 1篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1971年 | 2篇 |
排序方式: 共有762条查询结果,搜索用时 125 毫秒
581.
In this paper, we develop a model of international trade and climate change in which emission discharges arising from production have a feedback effect on national production sectors by impacting upon effective factor endowments. With this context, the objectives are, first, to provide a general characterization of Pareto-efficient climate and trade policies and, second, to examine the possibility – starting from non-Pareto-efficient equilibria – for Pareto-improving environmental policies. We provide conditions under which several particular reforms of carbon taxes are welfare improving. 相似文献
582.
Climate policy analysis has come to rely heavily on large‐scale numerical simulation models of increasing complexity, posing a challenge to policy‐makers and other non‐specialists who must interpret and apply the models. This paper provides a “user's guide” to economic models used in climate analysis. We review basic features, underlying design issues, and basic research questions bearing on the models' foundations. We also provide an overview of five such global or world models currently in use. 相似文献
583.
This study evaluated the effectiveness of two application rates of a coral-derived surfacing material for both traffic and
nontraffic road conditions using simulated rainfall (110–120 mm h−1 for 30–90 min) on 0.75-m (wide) × 5.0-m (long) plots of similar slope (roughly 0.1 m m−1). The coral is a locally available material that has been applied to unpaved roads surfaces on Schoffield Barracks, Oahu,
Hawaii (USA), where this experiment was conducted. The simulations show that compared with a bare control plot, the coral-based
surface application rates of 80 and 160 kg m−2 (equivalent to only 10- and 20-mm thicknesses) reduced road sediment production by 75% and 95%, respectively, for nontraffic
conditions. However, after two passes of the research vehicle during wet conditions, sediment production rates for the two
coral treatments were not significantly different from those on the bare road plots. The overall effectiveness of the coral-derived
surfacing material is unsatisfactory, primarily because the on-road surface thickness associated with the application rates
tested was too small. These rates were selected to bracket those applied to training roads in the study area. Furthermore,
the composition of the coral-based material does not facilitate the development of a sealed, erosion-resistant surface. When
applied at the low rates tested, the coral material breaks down under normal traffic conditions, thereby losing its ability
to counter shearing forces exerted by overland flow on long hillslopes where erosion measures are most needed. These simulations,
combined with observations on roads in the study area, indicate that this material is not an appropriate road surfacing material
for the site—at least for the low application rates examined. These results are preliminary; extended testing of higher applications
rates at the hillslope scale under natural climate and traffic conditions is needed to better judge the effectiveness of this
material over time. 相似文献
584.
We examined the effect that value orientation to forests and wildland fire management has on an individual’s decision to create
defensible space around his or her residence in the wildland–urban interface. Using data from a mail-back questionnaire, respondents
in north central Minnesota were clustered by basic value–laden beliefs toward forest and wildland fire management and compared
across a number of perceptions and behaviors related to creating defensible space around residences. Value orientation groups
differed in attitudes, subjective norms, and perceived behavior control toward creating defensible space. In addition, relative
effects of these perceptions on intention to create defensible space differed across groups. Implications lie in (a) understanding
differences in motivations and reasons for support of strategies for managing fires near the wildland–urban interface, (b)
developing information designed to address the perspectives of different groups related to creating defensible space, and
(c) contributing to an improved integration of land management and public concerns and interests. 相似文献
585.
Felipe Montes Sasha D. Hafner C. Alan Rotz Frank M. Mitloehner 《Atmospheric environment (Oxford, England : 1994)》2010,44(16):1987-1995
Volatile organic compounds (VOCs) from agricultural sources are believed to be an important contributor to tropospheric ozone in some locations. Recent research suggests that silage is a major source of VOCs emitted from agriculture, but only limited data exist on silage emissions. Ethanol is the most abundant VOC emitted from corn silage; therefore, ethanol was used as a representative compound to characterize the pattern of emission over time and to quantify the effect of air velocity and temperature on emission rate. Ethanol emission was measured from corn silage samples removed intact from a bunker silo. Emission rate was monitored over 12 h for a range in air velocity (0.05, 0.5, and 5 m s?1) and temperature (5, 20, and 35 °C) using a wind tunnel system. Ethanol flux ranged from 0.47 to 210 g m?2 h?1 and 12 h cumulative emission ranged from 8.5 to 260 g m?2. Ethanol flux was highly dependent on exposure time, declining rapidly over the first hour and then continuing to decline more slowly over the duration of the 12 h trials. The 12 h cumulative emission increased by a factor of three with a 30 °C increase in temperature and by a factor of nine with a 100-fold increase in air velocity. Effects of air velocity, temperature, and air-filled porosity were generally consistent with a conceptual model of VOC emission from silage. Exposure duration, temperature, and air velocity should be taken into consideration when measuring emission rates of VOCs from silage, so emission rate data obtained from studies that utilize low air flow methods are not likely representative of field conditions. 相似文献
586.
Markey M. Johnson Ron Williams Zhihua Fan Lin Lin Edward Hudgens Jane Gallagher Alan Vette Lucas Neas Halûk Özkaynak 《Atmospheric environment (Oxford, England : 1994)》2010,44(38):4927-4936
The Mechanistic Indicators of Childhood Asthma (MICA) study in Detroit, Michigan introduced a participant-based approach to reduce the resource burden associated with collection of indoor and outdoor residential air sampling data. A subset of participants designated as MICA-Air conducted indoor and outdoor residential sampling of nitrogen dioxide (NO2), volatile organic compounds (VOCs), and polycyclic aromatic hydrocarbons (PAHs). This participant-based methodology was subsequently adapted for use in the Vanguard phase of the U.S. National Children’s Study. The current paper examines residential indoor and outdoor concentrations of these pollutant species among health study participants in Detroit, Michigan.Pollutants measured under MICA-Air agreed well with other studies and continuous monitoring data collected in Detroit. For example, NO2 and BTEX concentrations reported for other Detroit area monitoring were generally within 10–15% of indoor and outdoor concentrations measured in MICA-Air households. Outdoor NO2 concentrations were typically higher than indoor NO2 concentration among MICA-Air homes, with a median indoor/outdoor (I/O) ratio of 0.6 in homes that were not impacted by environmental tobacco smoke (ETS) during air sampling. Indoor concentrations generally exceeded outdoor concentrations for VOC and PAH species measured among non-ETS homes in the study. I/O ratios for BTEX species (benzene, toluene, ethylbenzene, and m/p- and o-xylene) ranged from 1.2 for benzene to 3.1 for toluene. Outdoor NO2 concentrations were approximately 4.5 ppb higher on weekdays versus weekends. As expected, I/O ratios pollutants were generally higher for homes impacted by ETS.These findings suggest that participant-based air sampling can provide a cost-effective alternative to technician-based approaches for assessing indoor and outdoor residential air pollution in community health studies. We also introduced a technique for estimating daily concentrations at each home by weighting 2- and 7-day integrated concentrations using continuous measurements from regulatory monitoring sites. This approach may be applied to estimate short-term daily or hourly pollutant concentrations in future health studies. 相似文献
587.
Riddell N Becker R Chittim B Emmerling F Köppen R Lough A McAlees A McCrindle R 《Chemosphere》2011,84(7):900-907
Technical 1,2,5,6,9,10-hexabromocyclododecane (HBCD) consists largely of three diastereomers (α-, β-, and γ-HBCD) produced by the trans addition of bromine to cis,trans,trans-cyclododeca-1,5,9-triene (CDT). However, another seven diastereomers are theoretically possible and may be produced by trans addition of bromine across the double bonds of the other three isomers of 1,5,9-CDT. There are indications that small amounts of the minor HBCD isomers may be present in commercial HBCD mixtures or in products containing this brominated flame retardant (BFR). Such minor components may indeed derive from traces of other 1,5,9-CDTs in the cis, trans, trans starting material, however their formation may also be possible through isomerizations during the processing of this BFR or by bioisomerization subsequent to its release into the environment. Two of the seven additional diastereomers (δ- and ε-HBCD) were synthesized previously from trans,trans,trans-CDT. We now report the preparation of the remaining five diastereomers, ζ-, η-, and θ-HBCD from cis,cis,trans-CDT and ι- and κ-HBCD from cis,cis,cis-CDT, and their characterization by 1H NMR spectroscopy and X-ray crystallography. The availability of these further diastereomers of HBCD should aid in determining if the minor isomers are present in commercial samples of this BFR, in products containing HBCDs, or in environmental samples. We have also carried out an X-ray crystal structure determination on ε-HBCD, so that crystal structures are now available for all 10 HBCD diastereomers. 相似文献
588.
Rowlands JC Budinsky R Gollapudi B Novak R Abdelmegeed M Cukovic D Dombkowski A 《Chemosphere》2011,85(2):232-238
Toxicogenomics was used to examine mRNA expression profiles obtained from primary rat hepatocytes treated for 24 h with 0.01 or 1.0 nM 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD), 0.02 or 2.0 nM 2,3,4,7,8-pentachlorodibenzofuran (2,3,4,7,8-PeCDF) and 0.1 or 10 nM 2,3,7,8-tetrachlorodibenzofuran (2,3,7,8-TCDF). The concentrations of 2,3,4,7,8-PeCDF and 2,3,7,8-TCDF were chosen to be equivalent to 2,3,7,8-TCDD’s concentration based on the toxic equivalency factor/toxic equivalent (TEF/TEQ) method for estimating biological potency. 2,3,7,8-TCDD at 1.0 nM altered the expression of 533 genes; 2,3,4,7,8-PeCDF at 2.0 nM altered 182 genes, and 2,3,7,8-TCDF at 10 nM altered 154 genes. Of these, 57 genes were affected by all three congeners. Agglomerative hierarchical clustering revealed distinct congener-dependent gene subclusters. Principal components analyses of the microarray data revealed that these congeners cluster independently of one another. Data presented here demonstrate that equivalent TEQ concentrations of 2,3,7,8-TCDD, 2,3,4,7,8-PeCDF and 2,3,7,8-TCDF, while altering the expression of a small battery of genes in common, also produce substantial congener specific alterations in gene expression. 相似文献
589.
Quirós-Alcalá L Bradman A Nishioka M Harnly ME Hubbard A McKone TE Eskenazi B 《Environment international》2011,37(3):592-596
California residents may experience the highest polybrominated diphenyl ether (PBDE) flame retardant exposures in the United States, the nation with the highest body burdens worldwide. It is hypothesized that Californians' high exposures are due to the state's strict furniture flammability standards. Ingestion of PBDE-contaminated dust, to which children may be particularly susceptible, is a dominant exposure pathway. Low-income populations may also face disparately high exposures due to the presence of older, deteriorated or poorly manufactured furniture treated with PBDEs. We collected up to two dust samples per home (54 samples total), several days apart, from low-income California households in the urban community of Oakland (n=13 homes) and the agricultural community of Salinas (n=15 homes). We measured BDE-47, BDE-99 and BDE-100, the major constituents of the penta-PBDE flame retardant formulation commonly used in furniture. All three PBDE congeners were detected in every sample with concentrations (loadings) ranging from 185 to 126,000ng/g (621-264,000ng/m(2)), 367-220,000ng/g (1550-457,000ng/m(2)), and 84-41,100ng/g (257-85,700ng/m(2)) for BDE-47, BDE-99 and BDE-100, respectively. Median concentrations (loadings) observed in Salinas homes for BDE-47, BDE-99 and BDE-100 were 3100ng/g (10,800ng/m(2)), 5480ng/g (19,500ng/m(2)), and 1060ng/g (3810ng/m(2)), respectively, and in Oakland homes 2780ng/g (10,700ng/m(2)), 4450ng/g (19,100ng/m(2)), and 1050ng/g (4000ng/m(2)), respectively. Maximum concentrations for BDE-47 and BDE-99 are the highest reported to date. Indoor concentrations and loadings did not significantly differ between communities; concentrations and loadings were strongly correlated between collections for all three congeners (Spearman rho=0.79-0.97, p<0.002). We estimated non-dietary ingestion of each congener for one child in each home (n=28 children) and found that estimated intake for BDE-47 and BDE-99 exceeded the U.S. Environmental Protection Agency's recommended chronic reference dose for three and five children, respectively. Children's estimated intake via dust ranged from 1.0 to 599ng/kg/day, 2.0-1065ng/kg/day and 0.5-196ng/kg/day for BDE-47, BDE-99 and BDE-100, respectively. In order to mitigate these exposures, future research must address the factors that contribute to PBDE exposures in low-income homes. 相似文献
590.
This paper reviews the state of knowledge on modelling air flow and concentration fields at road intersections. The first part covers the available literature from the past two decades on experimental (both field and wind tunnel) and modelling activities in order to provide insight into the physical basis of flow behaviour at a typical cross-street intersection. This is followed by a review of associated investigations of the impact of traffic-generated localised turbulence on the concentration fields due to emissions from vehicles. There is a discussion on the role of adequate characterisation of vehicle-induced turbulence in making predictions using hybrid models, combining the merits of conventional approaches with information obtained from more detailed modelling. This concludes that, despite advancements in computational techniques, there are crucial knowledge gaps affecting the parameterisations used in current models for individual exposure. This is specifically relevant to the growing impetus on walking and cycling activities on urban roads in the context of current drives for sustainable transport and healthy living. Due to inherently longer travel times involved during such trips, compared to automotive transport, pedestrians and cyclists are subjected to higher levels of exposure to emissions. Current modelling tools seem to under-predict this exposure because of limitations in their design and in the empirical parameters employed. 相似文献