Cadmium (Cd) in coal, fly ash, slag, atmospheric deposition, soils and sediments collected from Tianjin, northern China, were measured to provide baseline information and determine possible Cd sources and potential risk. The concentrations of Cd in coal, fly ash and atmospheric deposition were much higher than the soil background values. Fallout from coal-fired thermal power plants, heating boilers and industrial furnaces has increased the Cd concentration in soils and sediments in Tianjin. The concentrations of Cd in soils of suburban areas were significantly higher than in rural areas, suggesting that coal burning in Tianjin may have an important impact on the local physical environment. Cd from coal combustion is readily mobilized in soils. It is soluble and can form aqueous complexes and permeate river sediments. The high proportion of mobile Cd affects the migration of Cd in soils and sediments, which may pose an environmental threat in Tianjin due to the exposure to Cd and Cd compounds via the food chain. This study may provide a window for understanding and tracing sources of Cd in the local environment and the risk associated with Cd bioaccessibility. 相似文献
This study investigated the potential use of chelator-induced bioextraction of heavy metals from soil by Coprinus comatus in a pot experiment. Two production waves of the mushroom were obtained to determine biomass and metal concentration. The application of ethylenediaminetetraacetic acid (EDTA) or nitrilotriacetate (NTA) slightly inhibited the growth of C. comatus, but significantly enhanced the accumulation of heavy metals in fruiting bodies compared with the control. The highest concentrations of Pb, Cu and Cd reached 900.60, 783.61 and 23.64 mg·kg?1 in a single pot, respectively. However, application of citric acid (CA) had no effect on metal uptake. Moreover, chelators applied to soil after fructification increased the dry biomass and metal concentration in fruiting bodies compared with those applied before sowing mycelia. EDTA was more efficient for inducing metal uptake by C. comatus than NTA or CA, and split applications of EDTA after fructification resulted in the highest total metal uptake by mushroom, i.e. 19.08±2.84, 17.57±0.69 and 0.55±0.06 mg for Pb, Cu and Cd, respectively, which were 130, 12 and 5 times values obtained with the control. Interestingly, many mushrooms turned blue after soil had been treated with chelator, indicating that these mushrooms are rich in Cu. 相似文献
Some species have disproportionate influence on assemblage structure, given their numbers or biomass. Most examples of such "strong interactors" come from small-scale experiments or from observations of the effects of invasive species. There is evidence that entire avian assemblages in open woodlands can be influenced strongly by individual species over very large areas in eastern Australia, with small-bodied species (< 50 g) being adversely affected. We used data from repeated surveys in 371 sites in seven districts across a region from Victoria to Queensland (> 2000 km). A series of linked Bayesian models was used to identify large-bodied (> or = 50 g) bird species that were associated with changes in occurrence and abundance of small-bodied species. One native species, the Noisy Miner (Manorina melanocephala; family Meliphagidae), was objectively identified as the sole large-bodied species having similar detrimental effects in all districts, depressing occurrence of 57 of 71 small-bodied species. Adverse effects on abundances of small-bodied species were profound when the Noisy Miner occurred with mean site abundances > or = 1.6 birds/2 ha. The Noisy Miner may be the first species to have been shown to influence whole-of-avifauna assemblage structure through despotic aggressiveness over subcontinental scales. These substantial shifts in occurrence rates and abundances of small-bodied species flow on to alter species abundance distributions of entire assemblages over much of eastern Australia. 相似文献
Current taxonomy indicates a single global species of the Great Barracuda (Sphyraena barracuda) despite differences in color and behavior between Atlantic and Pacific forms. To investigate these differences and qualify
the dispersal characteristics of this unique coastal–pelagic teleost (bony fish), we conducted a global phylogeographic survey
of 246 specimens from thirteen sampling locations using a 629-base pair fragment of mtDNA cytochrome b. Data indicate high overall gene flow in the Indo-Pacific over large distances (>16,500 km) bridging several biogeographic
barriers. The West Atlantic population contains an mtDNA lineage that is divergent from the Indo-Pacific (d = 1.9%), while the East Atlantic (N = 23) has two mutations (d = 0.6%) apart from the Indo-Pacific. While we cannot rule out distinct evolutionary partitions among ocean basins based on
behavior, coloration, and near-monophyly between Atlantic and Indo-Pacific subpopulations, more investigation is required
before taxonomic status is revised. Overall, the pattern of high global dispersal and connectivity in S. barracuda more closely resembles those reported for large oceanic predators than reef-associated teleosts. 相似文献
The best-fit equations of linear and non-linear forms of the two widely used kinetic models, namely pseudo-first-order and pseudo-second-order equations, were compared in this study. The experimental kinetics of methylene blue adsorption on activated carbon was used for this research. Both the correlation coefficient (R2) and the normalized standard deviation Δq(%) were employed as error analysis methods to determine the best-fitting equations. The results show that the non-linear forms of pseudo-first-order and pseudo-second-order models were more suitable than the linear forms for fitting the experimental data. The experimental kinetics may have been distorted by linearization of the linear kinetic equations, and thus, the non-linear forms of kinetic equations should be primarily used to obtain the adsorption parameters. In addition, the Δq(%) method for error analysis may be better to determine the best-fitting model in this case. 相似文献
Selective withdrawal is commonly implemented in nonlinearly stratified ambient, which typically has stratified ambient conditions, for purposes of controlling quality. A floating intake is applied as an effective facility of selective withdrawal. However, the outflow dynamics of a floating intake in a nonlinearly stratified ambient have been disregarded, which has a significant effect on the outflow water quality of a reservoir. Experiments were conducted to investigate the effect of thermal stratification on the flow characteristics using particle image velocimetry at three temperature distributions (no stratification, weak stratification and strong stratification). The flow fields upstream of the floating intake showed that the withdrawal layer was formed inhibited by the thermal stratification. And strong stratification produced the thinner withdrawal layer thickness, leading to a larger nonuniform coefficient of the velocity profile. To quantitatively describe the velocity profiles, formulas of dimensionless velocity profiles were proposed. The flow developments were analysed, and the virtual control points located 0.56d above the floating intake (where d is the straight pipe diameter of the floating intake) were obtained. The positions of virtual control points mainly depended on the withdrawal discharge. The decay rate of the velocity along the horizontal line passing through the virtual control point was inversely proportional to the stratification intensity.