Distribution and mode of occurrence of selenium in US coals

Selenium excess and deficiency have been established as the cause of various health problems in man and animals. Combustion of fossil fuels, especially coal, may be a major source of the anthropogenic introduction of selenium in the environment. Coal is enriched in selenium relative to selenium's concentration in most other rocks and relative to selenium in the Earth's crust.Data from almost 9,000 coal samples have been used to determine the concentration and distribution of selenium in US coals. The geometric mean concentration of selenium in US coal is 1.7 ppm. The highest mean selenium value (geometric mean 4.7 ppm) is in the Texas Region. Atlantic Coast (Virginia and North Carolina) and Alaska coals have the lowest geometric means (0.2 and 0.42 ppm, respectively). All western coal regions have mean selenium concentrations of less than 2.0 ppm. In contrast, all coal basins east of the Rocky Mountains (except for several small basins in Rhode Island, Virginia, and North Carolina) have mean selenium values of 1.9 or greater.Generally, variations in selenium concentration do not correlate with variations in ash yield, pyritic sulphur, or organic sulphur concentrations. This may be the result of multiple sources of selenium; however, in some non-marine basins with restricted sources of selenium, selenium has positive correlations with other coal quality parameters.Selenium occurs in several forms in coal but appears to be chiefly associated with the organic fraction, probably substituting for organic sulphur. Other important forms of selenium in coal are selenium-bearing pyrite, selenium-bearing galena, and lead selenide (clausthalite). Water-soluble and ion-exchangeable selenium also have been reported.     

Factors controlling sorption of prosulfuron by variable-charge soils and model sorbents

Prosulfuron [1-(4-methoxy-6-methyltriazin-2-yl)-3-[2-(3,3,3-trifluoropropyl) phenylsulfonyl]-urea), a relatively new sulfonylurea herbicide, is a weak acid (pK(a) 3.76), and therefore, will undergo pH-dependent speciation and sorption. Understanding prosulfuron sorption in soils is important for predicting its environmental fate. Soil and solution factors controlling sorption were investigated by measuring prosulfuron sorption on five model sorbents (amorphous silica, alpha-alumina, CaSWy1 montmorillonite, commercial humic acid, and anion exchange resin) and 10 variable-charge soils from CaCl(2) and Ca(H(2)PO(4))(2) solutions as a function of pH and ionic strength. Anion exchange of prosulfuron accounted for up to 82% of overall sorption in the pH range from 3 to 7. The relative importance of anion exchange to prosulfuron sorption was positively correlated to the ratio of anion and cation exchange capacities. Comparison between organic carbon (OC)-normalized sorption (K(oc)) versus pH for humic acid and variable-charge soils show similar trends with sorption decreasing with increasing pH. However, K(oc) values estimated from variable-charge soils in the lower pH range where anion exchange has the greatest contribution to sorption was almost one log unit greater than that estimated from humic acid clearly exemplifying the impact of anion exchange. Similarity in K(oc)-pH curves for humic acid and variable-charge soils may result from the fact that (i) cation exchange capacity increases with increasing OC content, thus effective anion exchange capacity is reduced; and (ii) the relative contribution of hydrophobic and hydrophilic sorption mechanisms was fairly constant. Given that both hydrophilic and hydrophobic sorption of prosulfuron decrease with increasing pH, addition of fertilizer and lime amendments may enhance the potential for off-site leaching of recently applied acidic pesticides.     

Social organization and space-use in Gunnison's prairie dog

Summary Social organization of the Gunnison's prairie dog, Cynomys gunnisoni, was studied in two populations in south-central Colorado. Gunnison's prairie dogs live in complex, interactive societies fitting current definitions of highly social ground squirrels. Members of harems (coteries) cooperatively use and defend a common territory. Spatial overlap is extensive between the adult male(s) and adult females, and among adult females within the harem through the active season. Amicable behavioral interactions are frequent within the harem, whereas interactions between members of different harems are primarily agonistic and spatial overlap is minimal. Although their behavioral repertoire is more limited, social organization of the Gunnison's prairie dog most closely resembles that of the black-tailed prairie dog, C. ludovicianus. Although body size, age of first reproduction, and age of emigration differed between the two study populations (Rayor 1985a), a comparison of social traits did not reveal substantial differences.     

A horizontal merger in the iron ore industry: An event study approach

The purpose of this paper is to analyse the competitive and efficiency impacts of a large merger in the world iron ore industry, using an event study approach. This method builds on an analysis of stock market reactions of the merging firms as well as close rivals at the time of the merger announcement. The event study method allows for the possibility to assess both the motivations behind as well as the welfare effects of the merger. The event study results for the merger announcement of Rio Tinto and North Ltd. show that, according to the market reactions, the main motive behind the merger was either the market power or the efficiency hypothesis. When adjusting the analysis to include several information releases about the merger, the overall result indicates that efficiency improvements were the predominant motives behind the merger. Thus, the event study results suggest that there are positive welfare effects to expect and the European Commission's decision to allow the merger is supported.     

Flow experiences at work: for high need achievers alone?

Applying Csikszentmihalyi's ( 1990 ) flow theory of optimal experience to the workplace, two studies examined the relationships of employees' perceived skill and challenge at work and need for achievement with their positive mood, intrinsic task interest, and extra‐role performance. Among achievement‐oriented employees only, high skill and challenge was associated with greater positive mood, task interest, and performance than other skill/challenge combinations. Additionally, positive mood mediated the interactive relationship of skill/challenge and need for achievement with performance. Copyright © 2005 John Wiley & Sons, Ltd.     

Fatal occupational injuries in Jordan during the period 1980 through 1993

All fatal occupational injuries compensated by the Social Security Corporation (SSC) in Jordan during the period 1980–1993 were studied. Variables considered in the analysis included gender, age, nationality, occupation, salary, cause of injury, body part injured and cause of death. The overall fatality rate, of the 705 cases reviewed, was 25.5/100,000/year. The majority (98%) of fatalities were males. The risk of fatal injuries increased with age. Workers over 55 years, had the highest annual fatality rate (37.8). Immigrant workers had a higher fatality rate (32.26) than Jordanians (23.95). Unskilled workers constituted 58.3% of decedents and professionals had the highest fatality rate (52.9). Transportation sector had the highest fatality rate (122.4) followed by construction (50.6). Over the study period, fatality rates tended to decrease significantly in manufacturing, construction and trade economic sectors while no such trend was established by transportation, agriculture and services sectors. The leading causes of fatal injuries were motor-vehicle related accidents (63.0%) and fall of persons (11.1%). Head was the body part most injured and was involved in 46.6% of all deaths. Haemorrhage was the main reported cause of death (24.5%). It is concluded that intervention measures targeting specific occupations (transportation and construction) and causes of fatalities such as motor-vehicle incidents are needed.     

Contents Volume 7

Volume Contents

Contents Volume 7     

Resorbed co-twin as an explanation for discrepant chorionic villus results: Non-mosaic 47,XX, +16 in villi (direct and culture) with normal (46,XX) amniotic fluid and neonatal blood

Non-mosaic trisomy 16 was observed in chorionic villus cytotrophoblasts (direct) as well as cultured mesenchymal core cells derived from the pregnancy of a 38-year-old woman. Chromosome preparations from amniotic fluid and neonatal cultures (cord blood) were 46,XX. Normal fetal growth as determined by serial ultrasound examinations occurred throughout the pregnancy, which resulted in a healthy 2724 g female. Multiple biopsies taken from the umbilical cord, placental cotyledons, and fetal membranes were 46,XX. However, a placental nodule and three of six cultures initiated from membranes (amnion and chorion) showed 46,XX/47,XX, + 16 mosaicism. We propose that the trisomy 16 cells arose from residual villi derived from a trisomic cotwin that never developed. This case further demonstrates that normal fetal growth may presage normal outcome irrespective of cytogenetic findings in cytotrophoblasts (direct) and cultured mesenchymal core cells.