三维有机LDH的制备及其对有机物的普适性吸附

以表面活性剂十二烷基硫酸钠(SDS)为软模板剂,制得有机三维花状层状双金属氢氧化物(3D-SLDH).采用X射线衍射(XRD)、扫描电子显微镜(SEM)、X射线能谱仪(EDS)和N2吸附-脱附等表征手段对3D-SLDH的结构进行表征,确定最佳合成尿素浓度,并通过静态吸附实验考察了3D-SLDH对金橙Ⅱ(AO7)、罗丹明...     

矿井井筒提升设备绕流的数值模拟

基于经典的流体力学理论,建立罐笼绕流的二维RNGκ-ε湍流模型,分析其初始边界条件,并结合工程实际应用FLUENT计算流体动力学软件模拟罐笼运行时井筒内流场及压力场,得出井筒内流场及压力场的变化规律。研究结果表明:在罐笼运行期间,由于空间受限而引发活塞效应,井筒内压力发生瞬态变化,造成通风系统的压力波动,导致气流运动的动态改变,对通风系统稳定性有一定的影响。     

福建省近10年生态足迹与生态承载力研究

利用生态足迹分析法分析了福建省1995年、2000年和2004年的生态足迹及生态承载力.将福建省资源利用的动态特征纳入生态足迹模型中,在此基础上进行横向和纵向比较.结果显示,福建省人均生态赤字从1995年的0.340 3 hm2、2000年的0.443 6 hm2上升到2004年的0.720 2 hm2.这说明福建省在近10年的发展中,生产、生活强度大幅度增加,超过了自然生态系统的承载力,维持现状将难以保证可持续发展.因此,应提高科技与农林业结合水平,大力提倡节约型生活及消费方式,减少生态赤字,遏制生态环境的恶化.     

活塞风影响下地铁火灾烟气运动规律的数值模拟研究

地铁车站及地铁列车为人流密集的公众聚集场所,一旦发生火灾事故伤亡损失往往非常惨重,因此深入开展地铁火灾安全的研究有助于地铁安全管理工作。在合理分析地铁站台和列车火灾荷载的基础上,采用数值模拟方法对活塞风情况下地铁区间隧道火灾问题进行了模拟计算和分析,研究了在活塞风影响下的烟气蔓延规律和温度分布情况,其结果有助于提高地铁车站的运营的安全管理和发生火灾后的疏散指挥能力。     

Organochlorine pesticides in soil profiles from Tianjin, China

Soil cores were collected from soils at five sites in Tianjin area for the determination of hexachlorocyclohexane isomers (HCHs, including alpha-HCH, beta-HCH, gamma-HCH and delta-HCH), dichlorodiphenyltrichloroethane and metabolites (DDXs, including p,p'-DDT, p,p'-DDE and p,p'-DDD) and total organic carbon (TOC). The levels and vertical distributions of HCHs and DDXs are studied. Results show that the application of pesticides in the past years was the major contributor of HCHs and DDXs accumulation in the sampling areas. Significant positive correlations were seen between the residual and application amounts of HCHs and DDXs. Wastewater irrigation did not bring a significant contribution of HCHs or DDXs into the soils. HCHs and DDXs concentrations peak at the surface and decline in soil profile with depth, while fluctuations were observed in the plow layers of some cultivated soils caused by frequent cultivation activities and batch irrigation. Positive correlations were observed between the contents of TOC and HCHs and DDTs. Although the amounts of HCHs application in all sampling sites are larger than DDXs, at surface and near surface layers of most sampling sites, the concentrations of summation operatorHCHs are lower than summation operatorDDXs. The composition of DDXs in the applied pesticides and sampled soils indicates that there is no recent DDT input at the sample areas.     

Quality assured measurements of animal building emissions: gas concentrations

Comprehensive field studies were initiated in 2002 to measure emissions of ammonia (NH3), hydrogen sulfide (H2S), carbon dioxide (CO2), methane (CH4), nonmethane hydrocarbons (NMHC), particulate matter <10 microm in diameter, and total suspended particulate from swine and poultry production buildings in the United States. This paper focuses on the quasicontinuous gas concentration measurement at multiple locations among paired barns in seven states. Documented principles, used in air pollution monitoring at industrial sources, were applied in developing quality assurance (QA) project plans for these studies. Air was sampled from multiple locations with each gas analyzed with one high quality commercial gas analyzer that was located in an environmentally controlled on-farm instrument shelter. A nominal 4 L/min gas sampling system was designed and constructed with Teflon wetted surfaces, bypass pumping, and sample line flow and pressure sensors. Three-way solenoids were used to automatically switch between multiple gas sampling lines with > or =10 min sampling intervals. Inside and outside gas sampling probes were between 10 and 115 m away from the analyzers. Analyzers used chemiluminescence, fluorescence, photoacoustic infrared, and photoionization detectors for NH3, H2S, CO2, CH4, and NMHC, respectively. Data were collected using personal computer-based data acquisition hardware and software. This paper discusses the methodology of gas concentration measurements and the unique challenges that livestock barns pose for achieving desired accuracy and precision, data representativeness, comparability and completeness, and instrument calibration and maintenance.     

超声去除垃圾渗滤液中的氨氮

采用超声辐照技术去除垃圾渗滤液中的氨氮.研究结果表明,超声辐照对垃圾渗滤液中的氨氮有很好的去除效果.渗滤液中氨氮超声去除的机理主要是氨氮以游离氨的形式在空化泡内发生高温热解反应,生成氮气和氢气而排出.     

Effect of arsenic on chloroplast ultrastructure and calcium distribution in arsenic hyperaccumulator Pteris vittata L

This study investigated the impacts of arsenic (As) on the chloroplast ultrastructure and calcium (Ca) distribution in Chinese brake (Pteris vittata L.) mainly by histochemical methods, with an emphasis on the possible function of Ca in As detoxification and accumulation in P. vittata. P. vittata was grown in an artificially contaminated soil added with different concentrations of Na(2)HAsO(4) (0, 100, 300 and 800 mg kg(-1) As dry soil) for 24 weeks in a greenhouse. The addition of As did not affect the chloroplast ultrastructure of young pinna, meanwhile most of the membrane systems of chloroplasts in mature pinna were severely damaged under high As condition. Calcium concentration in the fronds of P. vittata was not significantly affected by the addition of As, but Ca concentration in the mature pinna significantly increased by As addition, consistent with the position appearing As toxicity. When no As was added, most of calcium precipitates distributed around the inner membrane of vacuole. But when the pinna appeared plasmolysis, more calcium precipitates resided outside the cell membrane and bigger particles evenly distributed in the cytoplasm. All the results indicated that Ca had a close relation with As toxicity in P. vittata.     

新型沸石填料间歇硝化反应器的研究

介绍一种新型沸石填料 ,用于提高生物脱氮系统中硝化反应器的硝化性能。试验结果表明 ,应用了沸石填料的硝化反应器的硝化性能得到了显著提高 ,在脱氮效率和速率上 ,与普通生物载体硝化反应器相比具有明显的优势。硝化反应器连续运行 17d ,出水氨氮基本在 1mg/L以下 ,氨氮去除率在 97%以上。该系统停止运行 5 0d后再次启动 ,一周内硝化性能得以恢复     

Changes of copper speciation in maize rhizosphere soil

Chemical forms of copper in the rhizosphere and bulk soil of maize were investigated using rhizobox cultivation and sequential extraction techniques. The copper accumulations were also determined. The results demonstrated that there were continuous changes in copper fractionation within the maize rhizosphere. Initially, the amount of exchangeable copper increased before dropping below the initial level after 40 days or so. Carbonate associated copper followed a similar trend of change, but with a slower pace than the exchangeable copper. The increase in carbonate associated copper only become evident after 30 days, with the net loss occurring after 60 days. There were also initial increases in oxide bound copper as well as decreases in the organic matter associated copper, both followed by a turnover after 40-50 days. The accumulation of copper in the maize plant was found to be biomass dependent. The amount of accumulated copper absorbed in the plant material exceeded the initial quantity of the exchangeable copper in the soil, revealing a transformation from less bioavailable to more bioavailable fractions. During cultivation, decreases in redox potential and increases in pH, dissolved organic carbon (DOC), and microbial activity in the maize rhizosphere were observed. The change in copper speciation may result from root-induced changes in DOC, redox potential, and microbial activity in the rhizosphere.