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841.
Quantification of ventilation on distribution of gaseous pollutants emitted from stored swine manure
Chung‐Min Liao Dwaine S. Bundy 《Journal of environmental science and health. Part. B》2013,48(6):859-893
Abstract This paper describes the quantification of the effects of ventilation on distribution of gaseous pollutants as a result of mass transfer from stored manure to ventilation air in a swine confinement building. A multiple airflow regions model is developed and used to simulate the dynamics of gaseous pollutants in any airspace within a ventilated slotted‐inlet enclosure. The model predictions compared favorably with the measured results adapted from a literature research at ventilation rates between 443 and 932 m3/hr (deviations of 5.1 ‐ 14.68%) for carbon dioxide and ammonia concentrations. A comparison between predictions and measured carbon dioxide concentrations derived from an environmental chamber test found deviations ranged from 3.1 ‐ 5.6% at ventilation rates between 281 and 995 m3/hr. The results suggest that the model can be experimentally applied between ventilation rates of 443 and 995 m3/hr. The model also capable of predicting air exchange rate required to maintain acceptable levels of gaseous pollutants in swine confinement buildings based on gas emission rates. 相似文献
842.
M. Humayoun Akhtar Khaled Abo ElSooud Atef M. Shehata Anwar ‐ul‐Haq 《Journal of environmental science and health. Part. B》2013,48(5):1061-1084
Abstract Studies were conducted to determine the metabolic fate of chloramphenicol (CAP) in White Leghorn using the l4C‐labelled compound. In one experiment birds were administered orally via intra‐crop, a single dose of 100 mg (equivalent to 66 mg kg‐1 body weight) of CAP containing 14 μCi 14C‐CAP, and its absorption, elimination and distribution in plasma were recorded. Orally dosed 14C‐compound was rapidly absorbed, efficiently distributed in plasma and eliminated in excreta (>70% in 5 hr). After 5 h, CAP equivalent residues in tissues were lower than 15 μg g‐1 for this treatment. In a second experiment birds were given intra‐crop dose of either 0.5 or 5 mg of CAP (each dose contained 2.5 μCi 14C‐CAP) daily for five consecutive days followed by a seven day withdrawal period and elimination of 14C in excreta and eggs was monitored. More than 95% of the administered 14C was eliminated within the first 24 h after dosing. Radiocarbon (14C) was deposited preferentially in yolks compared to albumen or other tissues. Residues declined when feeding was stopped. Various metabolites were isolated and identified by a combination of TLC, LC, and LC‐MS. The main metabolic route of CAP in laying hens appears to be the glucuronidation. Cleavage of the dichloroacetate moiety was only a minor route. 相似文献
843.
M.D. Ferrando E. Sancho E. Andreu‐Moliner 《Journal of environmental science and health. Part. B》2013,48(5-6):491-498
Abstract The acute toxicities (24, 48, 72 and 96 hr) of eight pesticides to Anguilla anguilla were determined. The organochlorine pesticide, endosulfan was the most toxic, with LC50 values in the range of 0.042 to 0.041 mg/L Endosulfan was followed in order of decreasing toxicity by diazinon, fenitrothion, chlorpyrifos, lmdane, methidathion, trichlorfon and methylparathion. When fishes were exposed to the pesticides tested they exhibited signs of restlessness, erratic swimming, convulsions and difficulty in respiration. This response was more persistent in fishes exposed to organophosphorus pesticides. 相似文献
844.
Baig MN Leeke GA Hammond PJ Santos RC 《Environmental pollution (Barking, Essex : 1987)》2011,159(7):1802-1809
Extractions of volatile organic compounds (VOC’s) in contaminated soil from petroleum site were performed with supercritical carbon dioxide at different temperatures, pressures, extraction times, solvent flow rates, soil moisture contents and soil acidity. Three soil systems were investigated in order to compare the best parameters for extraction. A central composite rotatable design has been used to evaluate the influence of operation conditions on the extraction efficiency to generate model equations representing the types of soil. The results indicate that at least 70-80% of the initial amount of VOC’s can be removed at moderate temperatures even at very high moisture content. Supercritical extraction is best suited to silt type soils which have a low adsorption capacity. VOC’s recoveries from the artificial contaminated soil samples were higher in comparison with real contaminated soils. At moderate temperatures, the extraction efficiency for real soils is low because pollutants bind strongly to the soil. 相似文献
845.
Thakur Ravindra Singh Kumar Aditya Lugun Onila Ansari Nasreen Ghazi Prasad Satgur Das Triparna Gupta Neha Patel Devendra Kumar 《Environmental science and pollution research international》2023,30(10):25181-25192
Environmental Science and Pollution Research - In recent years, special attention has been given to emission research that led to the deposition of toxicants from road traffic. Thus, it is... 相似文献
846.
847.
This study examined the mediating influence of protege‐initiated mentoring relationships on the relationship between personality and situational characteristics and mentoring received. Data were obtained from Hong Kong Chinese graduate employees (N=184) in their early career stage. Results of the regression analysis showed that protege‐initiated mentoring relationships mediated the relationship between the personality (extraversion) but not the situational (individual development culture and opportunities for interactions on the job) characteristics and mentoring received. In other words, extraversion was indirectly related to mentoring received through protege‐initiated mentoring relationships but individual development culture and opportunities for interactions on the job were directly related to mentoring received. Additionally, opportunities for interactions on the job indirectly influenced mentoring received through protege‐initiated mentoring relationships. Limitations of the study, implications of the findings and directions for future research are discussed. Copyright © 1999 John Wiley & Sons, Ltd. 相似文献
848.
Does homesickness undermine the potential of job resources? A perspective from the work–home resources model
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Rapid economic development in recent decades has resulted in a considerable increase in the number of people working far away from their home locations. Homesickness is a common reaction to the separation from home. Our research uses the work–home resources model to explain how the experience of homesickness can undermine the positive effect of job resources on job performance (i.e., task performance and safety behavior). In addition, we hypothesize that emotional stability and openness are key resources that can buffer the negative interference of homesickness with the job resources–performance relationship. We conducted two studies to test our hypotheses. Study 1 was a two‐wave longitudinal study using a migrant manufacturing worker sample. In this study, homesickness was measured at the between‐person level, and performance was measured three months later. Study 2 was a daily diary study conducted in a military trainee sample. In this study, homesickness was measured at the within‐person level to capture its fluctuations over 20 days, and daily job performance was assessed using supervisor ratings. Both studies showed evidence of the hypothesized moderating effect of homesickness and three‐way interaction effects of job resources, homesickness, and key resources (i.e., emotional stability and openness) on task performance and safety behavior. 相似文献
849.
Shangtao Liang Randall "David" Pierce Jr. Hui Lin Sheau‐Yun Chiang Qingguo "Jack" Huang 《补救:环境净化治理成本、技术与工艺杂志》2018,28(2):127-134
The electrochemical oxidation (EO) of environmentally persistent perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) with a Magnéli phase Ti4O7 electrode was investigated in this study. After 3 hours (hr) of electrolysis, 96.0 percent of PFOA (10 milligrams per liter [mg/L] in 100 milliliters [mL] 100 millimolar [mM] Na2SO4 solution) was removed following pseudo first‐order kinetics (k = 0.0226 per minute [min]) with the degradation half‐life of 30.7 min. Under the same treatment conditions, PFOS (10 mg/L in 100 mL 100 mM Na2SO4 solution) removal reached 98.9 percent with a pseudo first‐order degradation rate constant of 0.0491/min and the half‐life of 14.1 min. Although, the degradation of PFOA was slower than PFOS, when subjected to EO treatment in separate solutions, PFOA appeared to degrade faster than PFOS when both are present in the same solution, indicating possible competition between PFOA and PFOS during Ti4O7 anode‐based EO treatment with PFOA having the competitive advantage. Moreover, the EO treatment was applied to degrade highly concentrated PFOA (100.5 mg/L) and PFOS (68.6 mg/L) in ion‐exchange resin regenerant (still bottom) with high organic carbon content (15,800 mg/L). After 17‐hr electrolysis, the total removal of PFOA and PFOS was 77.2 and 96.5 percent, respectively, and the fluoride concentration increased from 0.84 mg/L to 836 mg/L. Also, the dark brown color of the original solution gradually faded during EO treatment. In another test using still bottom samples with lower total organic carbon (9,880 mg/L), the PFOA (15.5 mg/L) and PFOS (25.5 mg/L) concentrations were reduced to levels below the limits of quantification after 16‐hr treatment. In addition, the performance of EO treatment using different batch reactor setups was compared in this study, including one‐sided (one anode:one cathode) and two‐sided (one anode:two cathodes) setups. The two‐sided reactor configuration significantly enhanced the degradation efficiency, likely due to the larger anode area available for reactions. 相似文献
850.
Status of nanoremediation and its potential for future deployment: Risk‐benefit and benchmarking appraisals
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NanoRem (Taking Nanotechnological Remediation Processes from Lab Scale to End User Applications for the Restoration of a Clean Environment) was a research project, funded through the European Commission's Seventh Framework Programme, which focuses on facilitating practical, safe, economic, and exploitable nanotechnology for in situ remediation of polluted soil and groundwater, which closed in January 2017. This article describes the status of the nanoremediation implementation and future opportunities for deployment based on risk‐benefit appraisal and benchmarking undertaken in the NanoRem Project. As of November 2016, NanoRem identified 100 deployments of nanoremediation in the field. While the majority of these are pilot‐scale deployments, there are a number of large scale deployments over the last five to 10 years. Most applications have been for plume control (i.e., pathway management in groundwater), but a number of source control measures appear to have taken place. Nanoremediation has been most frequently applied to problems of chlorinated solvents and metals (such as chromium VI). The perception of risk‐benefit balance for nanoremediation has shifted as the NanoRem Project has proceeded. Niche benefits are now more strongly recognized, and some (if not most) of the concerns, for example, relating to environmental risks of nanoremediation deployment, prevalent when the project was proposed and initiated, have been addressed. Indeed, these now appear overstated. However, it appears to remain the case that in some jurisdictions the use of nanoparticles remains less attractive owing to regulatory concerns and/or a lack of awareness, meaning that regulators may demand additional verification measures compared to technologies with which they have a greater level of comfort. 相似文献