Analysis of air pollution at Shuaiba industrial area in Kuwait

A study has been conducted over a period of one year on measurements of air pollution in the Shuaiba Industrial Area (SIA) of Kuwait. The study included analysis of pollutant behaviour relative to the wind speed and direction. SIA comprises several large scale industries including three petroleum refineries, two power plants, two fertilizer plants, a cement plant, a chlorine and soda plant, a commercial harbour and two large oil loading terminals. Measurements of 15 parameters have been carried out every 5 minutes using a mobile laboratory fitted with an automatic calibrator and a data storage system. The pollutants studied include methane, non‐methane hydrocarbons (NMHC), carbon monoxide, carbon dioxide, nitrogen oxides (NO, NO₂, and NO _x ), sulphur dioxide, ozone and suspended dust. Meteorological parameters monitored simultaneously include wind speed and direction, air temperature, relative humidity, solar radiation, and barometric pressure. The air quality data collected using the mobile laboratory have been used to calculate the diurnal and monthly variations in the major primary and secondary pollutants. Distribution levels of these pollutants relative to wind direction and speed have also been used in the analysis. The results show large diurnal variations in some pollutant concentrations. Generally, two types of concentration variations have been found, depending on whether the species is a primary or a secondary pollutant. Diurnal variations with two maxima were observed in the concentrations of primary pollutants including NO, SO₂, NMHC, CO and suspended dust, whereas a single maximum was observed for secondary pollutants such as O₃and NO₂. The monthly variations of SO₂and NO _x showed maximum values during the warm months. However, ozone showed a quite marked seasonal variation with maxima during spring and late summer and a minimum during the early summer. The results also indicated a common source for NO _x , SO₂, NMHC, CO and suspended dust to the North‐West (NW) of the monitoring station. Moreover for NO _x and SO₂, another less significant source is to the South‐South‐West (SSW) and South‐West (SW) of the monitoring station.     

Effect of some preparates on soil microflora on the basis of soil bioassay

Abstract

Trials for control of soil‐borne plant pathogen fungi with biological and chemical fungicide preparates have been carried out in our Biological Control Laboratory for more than 10 years. During all these experiments soil bioassay was always carried out in order to observe the soil microflora. Here we mention one trial which confirms the general opinion that chemical treatments significantly change the soil microflora. The tested biological fungicide did not cause such changes.     

Use of Stress‐Hormone Levels and Habitat Selection to Assess Functional Connectivity of a Landscape for an Amphibian

Abstract: The influence of landscape matrix on functional connectivity has been clearly established. Now methods to assess the effects of different land uses on species’ movements are needed because current methods are often biased. The use of physiological parameters as indicators of the level of resistance to animal movement associated with different land uses (i.e., matrix resistance) could provide estimates of energetic costs and risks to animals migrating through the matrix. To assess whether corticosterone levels indicate matrix resistance, we conducted experiments on substrate choice and measured levels of corticosterone before and after exposure of toads (Bufo bufo) to 3 common substrates (ploughed soil, meadow, and forest litter). We expected matrix resistance and hormone levels to increase from forest litter (habitat of the toad) to meadows to ploughed soil. Adult toads had higher corticosterone levels on ploughed soil than on forest litter or meadow substrates. Hormone levels did not differ between forest litter and meadow. Toads avoided moving onto ploughed soil. Corticosterone levels in juvenile toads were not related to substrate type; however, hormone levels decreased as humidity increased. Juveniles, unlike adults, did not avoid moving over ploughed soil. The difference in responses between adult and juvenile toads may have been due to differences in experimental design (for juveniles, entire body used to measure corticosterone concentration; for adults, saliva alone); differences in the scale of sensory perception of the substrate (juveniles are much smaller than adults); or differences in cognitive processes between adult and juvenile toads. Adults probably had experience with different substrate types, whereas juveniles first emerging from the water probably did not. As a consequence, arable lands could act as ecological traps for juvenile toads.     

PREDICTION OF LOCAL SCOUR AROUND BRIDGE PIERS USING ARTIFICIAL NEURAL NETWORKS1

This paper describes a method for predicting local scour around bridge piers using an artificial neural network (ANN). Methods for selecting input variables, calibrations of network control parameters, learning process, and verifications are also discussed. The ANN model trained by laboratory data is applied to both laboratory and field measurements. The results illustrate that the ANN model can be used to predict local scour in the laboratories and in the field better than other empirical relationships that are currently in use. A parameter study is also carried out to investigate the importance of each input variable as reflected in data.     

DECISION SUPPORT FOR ALLOCATION OF WATERSHED POLLUTION LOAD USING GREY FUZZY MULTIOBJECTIVE PROGRAMMING1

ABSTRACT: This paper uses the grey fuzzy multiobjective programming to aid in decision making for the allocation of waste load in a river system under versatile uncertainties and risks. It differs from previous studies by considering a multicriteria objective function with combined grey and fuzzy messages under a cost benefit analysis framework. Such analysis technically integrates the prior information of water quality models, water quality standards, wastewater treatment costs, and potential benefits gained via in‐stream water quality improvement. While fuzzy sets are characterized based on semantic and cognitive vagueness in decision making, grey numbers can delineate measurement errors in data collection. By employing three distinct set theoretic fuzzy operators, the synergy of grey and fuzzy implications may smoothly characterize the prescribed management complexity. With the aid of genetic algorithm in the solution procedure, the modeling outputs contribute to the development of an effective waste load allocation and reduction scheme for tributaries in this subwatershed located in the lower Tseng‐Wen River Basin, South Taiwan. Research findings indicate that the inclusion of three fuzzy set theoretic operators in decision analysis may delineate different tradeoffs in decision making due to varying changes, transformations, and movements of waste load in association with land use pattern within the watershed.     

APPLICATION OF PARAMETER OPTIMIZATION METHOD FOR CALIBRATING TANK MODEL1

ABSTRACT: Many automatic calibration processes have been proposed to efficiently calibrate the 16 parameters involved in the four‐layered tank model. The Multistart Powell and Stuffed Complex Evolution (SCE) methods are considered the best two procedures. Two rainfall events were designed to compare the performance and efficiency of these two methods. The first rainfall event is short term and the second designed for long term rainfall data collection. Both rainfall events include a lengthy no‐rainfall period. Two sets of upper and lower values for the search range were selected for the numerical tests. The results show that the Multistart Powell and SCE methods are able to obtain the true values for the 16 parameters with a sufficiently long no‐rainfall period after a rainfall event. In addition, by using two selected objective functions, one based on root mean square error and one based on root mean square relative error criteria, it is found that the no‐rainfall period lengths necessary to obtain the converged true values for the 16 parameters are roughly the same. The SCE method provides a more efficient search based on an appropriate preliminary search range. The Multistart Powell method, on the other hand, leads to more accurate search results when there is no suitable search range selected based on the parameter calibration experience.     

Tracking remediation and redevelopment trends of brownfield clean‐up programmes: the Cook County experience

This study provides evidence on the clean‐up and development of properties in Cook County that have completed the two Illinois brownfield voluntary clean‐up programmes (VCPs) since 1989. Real estate and environmental databases are merged to allow analysis of development trends for a sample of several hundred entering sites, which are followed through the programme and into the marketplace. Results show that over half of the sites entering the programme received a closure letter, and that a quarter used a residential standard when remediating property. One‐third used caps or other engineering controls, and about 20% have received financing since obtaining the closure letter. These promising outcomes demonstrate the return of these properties to productive use.     

SOLIDS DISTRIBUTION IN LAKE CHAPALA,MEXICO1

ABSTRACT: Lake Chapala is the largest natural water body in Mexico and also one of the most important shallow lakes in Latin America. For the past several years it has suffered various environmental problems such as the upstream overuse of water, contamination, and sedimentation. For the past 10 years the lake has had less than 50 percent of its historical water level over the past century. No criteria are reported in the literature that establish a water storage volume that will guarantee water quality conditions necessary for the survival of the lake. After determining the behavior of total solids concentrations in relation to the variations in the lake's depth, we proposed a minimum water column height of 5.0 m, representing a storage volume of about 5,000 Mm³. This volume would result in the recommended water quality standards for total dissolved solids. Calculated distribution maps show that the total solids concentration in the lake has increased since the end of the 1970s. The solids are primarily concentrated in the eastern part of the lake, as a consequence of the high solids discharged from the Lerma River, its main tributary.     

IMPLEMENTATION OF BIORETENTION SYSTEMS: A WISCONSIN CASE STUDY1

ABSTRACT: The implementation of various bioretention systems was analyzed, including rain gardens, vegetated swales, trenches, and infiltration basins in the St. Francis subdivision, Cross Plains, Wisconsin. Through the examination of archival data and interviews with key participants, it was found that although regulatory and political pressures encouraged the inclusion of bioretention, current standards for storm water management prevailed. The developers had to meet both existing requirements and anticipated rules requiring infiltration. As a result, bioretention systems simply supplemented, rather than replaced, traditional storm water practices. The confusion surrounding dual standards contributed to substantial delays in the negotiations among relevant stakeholders in the watershed. It is concluded that the St. Francis subdivision serves as both a cautionary tale and a bioretention success story. As a caution, this situation demonstrates the need for careful review and refinement of existing storm water ordinances to incorporate water quality improvement technologies, such as bioretention. The demonstrated success of the St. Francis development, however, is that it became a positive prototype for best management storm water practices elsewhere in the region. In addition, the water quality monitoring data from the site has contributed to development of a new county ordinance, the first in Wisconsin to address both quantity and quality of storm water runoff.     

MULTIVARIATE ANALYSIS OF WATER QUALITY IN THE RICHIBUCTO DRAINAGE BASIN (NEW BRUNSWICK,CANADA)1

ABSTRACT: Specific conductivity, pH, dissolved oxygen, carbon, phosphorous, and nitrogen species were measured at 36 stations in the Richibucto River drainage basin, including the estuary, in New Brunswick, Canada, over the six‐year period 1996 through 2001. Each station was sampled between 1 and 26 times (mean = 7.5, standard deviation = 6.0) during the ice free seasons without regard to tide. There was significant variance among stations in most parameters. Principal component analysis (PCA) was used to identify the processes explaining the observed variance in water quality. Because of the high variability in specific conductance, stations were first grouped in a freshwater subset and an estuarine (brackish water) subset. For freshwater stations, most of the variance in water quality was explained by pH and total organic carbon, as well as high nutrient concentrations. These high nutrient concentrations, along with water salinity, which varies with flow and tides, are also important in determining water quality variability in brackish water. It is recommended that water quality parameters that were found to explain most of the variance by PCA be monitored more closely, as they are key elements in understanding the variability in water quality in the Richibucto drainage basin. Cluster analyses showed that high phosphorous and nitrate concentrations were mostly found in areas of peat runoff, tributaries receiving treated municipal effluent, and lentic zones upstream of culverts. Peat runoff was also shown to be acidic, whether it is runoff from a harvested area or a natural bog.