Zinc,lead, and cadmium tolerance and accumulation in Cistus libanotis,Cistus albidus,and Cistus salviifolius: Perspectives on phytoremediation

Heavy metal contamination is of particular concern for human health and the environment. Phytoremediation is an emerging cost‐effective strategy to remediate heavy metal contaminated soil. However, this technique is limited by the small number of plants that are tolerant to heavy metals and are also accumulators. This study assayed zinc, lead, and cadmium tolerance and accumulation in Cistus libanotis, Cistus albidus, and Cistus salviifolius. The plants were cultivated in hydroponic conditions and exposed to different concentrations of Pb(NO₃)₂ (100 and 200 µM), ZnSO₄ (100 and 200 µM), or CdCl₂ (10 and 20 µM) for 3 weeks. Plant biomass and metal accumulation in roots and aboveground parts varied greatly among the species. All three species appeared to be sensitive to Zn. However, C. albidus displayed strong tolerance to Pb and accumulated large quantities of Pb and Cd in its roots. C. libanotis accumulated large quantities of Pb and Cd in its aboveground parts. C. libanotis can thus be classified as a Pb and Cd accumulator species. The study results show that C. albidus is suitable for phytostabilization of Pb‐contaminated soils, while C. libanotis can be used for phytoextraction of both Pb and Cd.     

Does homesickness undermine the potential of job resources? A perspective from the work–home resources model

Rapid economic development in recent decades has resulted in a considerable increase in the number of people working far away from their home locations. Homesickness is a common reaction to the separation from home. Our research uses the work–home resources model to explain how the experience of homesickness can undermine the positive effect of job resources on job performance (i.e., task performance and safety behavior). In addition, we hypothesize that emotional stability and openness are key resources that can buffer the negative interference of homesickness with the job resources–performance relationship. We conducted two studies to test our hypotheses. Study 1 was a two‐wave longitudinal study using a migrant manufacturing worker sample. In this study, homesickness was measured at the between‐person level, and performance was measured three months later. Study 2 was a daily diary study conducted in a military trainee sample. In this study, homesickness was measured at the within‐person level to capture its fluctuations over 20 days, and daily job performance was assessed using supervisor ratings. Both studies showed evidence of the hypothesized moderating effect of homesickness and three‐way interaction effects of job resources, homesickness, and key resources (i.e., emotional stability and openness) on task performance and safety behavior.     

Electrochemical oxidation of PFOA and PFOS in concentrated waste streams

The electrochemical oxidation (EO) of environmentally persistent perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) with a Magnéli phase Ti₄O₇ electrode was investigated in this study. After 3 hours (hr) of electrolysis, 96.0 percent of PFOA (10 milligrams per liter [mg/L] in 100 milliliters [mL] 100 millimolar [mM] Na₂SO₄ solution) was removed following pseudo first‐order kinetics (k = 0.0226 per minute [min]) with the degradation half‐life of 30.7 min. Under the same treatment conditions, PFOS (10 mg/L in 100 mL 100 mM Na₂SO₄ solution) removal reached 98.9 percent with a pseudo first‐order degradation rate constant of 0.0491/min and the half‐life of 14.1 min. Although, the degradation of PFOA was slower than PFOS, when subjected to EO treatment in separate solutions, PFOA appeared to degrade faster than PFOS when both are present in the same solution, indicating possible competition between PFOA and PFOS during Ti₄O₇ anode‐based EO treatment with PFOA having the competitive advantage. Moreover, the EO treatment was applied to degrade highly concentrated PFOA (100.5 mg/L) and PFOS (68.6 mg/L) in ion‐exchange resin regenerant (still bottom) with high organic carbon content (15,800 mg/L). After 17‐hr electrolysis, the total removal of PFOA and PFOS was 77.2 and 96.5 percent, respectively, and the fluoride concentration increased from 0.84 mg/L to 836 mg/L. Also, the dark brown color of the original solution gradually faded during EO treatment. In another test using still bottom samples with lower total organic carbon (9,880 mg/L), the PFOA (15.5 mg/L) and PFOS (25.5 mg/L) concentrations were reduced to levels below the limits of quantification after 16‐hr treatment. In addition, the performance of EO treatment using different batch reactor setups was compared in this study, including one‐sided (one anode:one cathode) and two‐sided (one anode:two cathodes) setups. The two‐sided reactor configuration significantly enhanced the degradation efficiency, likely due to the larger anode area available for reactions.     

Status of nanoremediation and its potential for future deployment: Risk‐benefit and benchmarking appraisals

NanoRem (Taking Nanotechnological Remediation Processes from Lab Scale to End User Applications for the Restoration of a Clean Environment) was a research project, funded through the European Commission's Seventh Framework Programme, which focuses on facilitating practical, safe, economic, and exploitable nanotechnology for in situ remediation of polluted soil and groundwater, which closed in January 2017. This article describes the status of the nanoremediation implementation and future opportunities for deployment based on risk‐benefit appraisal and benchmarking undertaken in the NanoRem Project. As of November 2016, NanoRem identified 100 deployments of nanoremediation in the field. While the majority of these are pilot‐scale deployments, there are a number of large scale deployments over the last five to 10 years. Most applications have been for plume control (i.e., pathway management in groundwater), but a number of source control measures appear to have taken place. Nanoremediation has been most frequently applied to problems of chlorinated solvents and metals (such as chromium VI). The perception of risk‐benefit balance for nanoremediation has shifted as the NanoRem Project has proceeded. Niche benefits are now more strongly recognized, and some (if not most) of the concerns, for example, relating to environmental risks of nanoremediation deployment, prevalent when the project was proposed and initiated, have been addressed. Indeed, these now appear overstated. However, it appears to remain the case that in some jurisdictions the use of nanoparticles remains less attractive owing to regulatory concerns and/or a lack of awareness, meaning that regulators may demand additional verification measures compared to technologies with which they have a greater level of comfort.     

How does it feel and how does it look? The role of employee motivation in organizational learning type

Employees' work outcomes vary as a function of their focus on exploring new possibilities versus exploiting current opportunities. But what determines how employees divide their attention between these contrasting work behaviors? Drawing on studies on work motivation and employees' impression management concerns, we examine how intrinsic work motivation and self‐enhancement motivation relate to the exploration–exploitation balance and how environmental dynamism moderates these relationships. Based on the analyses of a sample of 638 employees in 34 organizations in Finland, we find that intrinsic work motivation is positively associated with employees' focus on exploration relative to exploitation. By contrast, self‐enhancement motivation negatively associates with exploration relative to exploitation, but this relationship is nonlinear, such that as self‐enhancement motivation increases, its positive association with exploitation diminishes. The findings also show that the hypothesized nonlinear relationship between self‐enhancement motivation and exploration is particularly pronounced in stable business environments. Our findings contribute to organizational learning research and provide a new theoretical perspective on pursuing exploration and exploitation in organizations.     

Modes of Variability of Annual and Seasonal Rainfall in Mexico

The aim of this study is to identify temporal and spatial variability patterns of annual and seasonal rainfall in Mexico. A set of 769 weather stations located in Mexico was examined. The country was divided into 12 homogeneous rainfall regions via principal component analysis. A Pettitt test was conducted to perform a homogeneity analysis for detecting abrupt changes in mean rainfall levels, and a Mann‐Kendall test was conducted to examine the presence of monotonically increasing/decreasing patterns in the data. In total, 14.4% of the annual series was deemed nonstationary. Fourteen percent of the samples were nonstationary in the winter and summer, and 9% were nonstationary in the spring and autumn. According to the results, the nonstationarity of some seasonal rainfall series may be associated with the presence of atmospheric phenomena (e.g., El Niño/Southern Oscillation, Pacific Decadal Oscillation, Atlantic Multidecadal Oscillation, and North Atlantic Oscillation). A rainfall frequency analysis was performed for the nonstationary annual series, and significant differences in the return levels can be expected for the scenarios analyzed. The identification of areas that are more susceptible to changes in rainfall levels will improve water resource management plans in the country, and it is expected that these plans will take into account nonstationary theory.     

Beyond men and women: a critical perspective on gender and disaster

Consideration of gender in the disaster sphere has centred almost exclusively on the vulnerability and capacities of women. This trend stems from a polarised Western understanding of gender as a binary concept of man—woman. Such an approach also mirrors the dominant framing of disasters and disaster risk reduction (DRR), emphasising Western standards and practices to the detriment of local, non‐Western identities and experiences. This paper argues that the man—woman dichotomy is an insufficient construct with which to address the gendered dimensions of a disaster as it fails to capture the realities of diverse gender minorities in non‐Western contexts. The paper presents case studies from the Philippines, Indonesia, and Samoa, where gender minorities display specific patterns of vulnerability associated with their marginal positions in society, yet, importantly, also possess a wide array of endogenous capacities. Recognition of these differences, needs, skills, and unique resources is essential to moving towards inclusive and gender‐sensitive DRR.     

Using a Mass Balance Model to Evaluate Groundwater Budget of Seawater‐Intruded Island Aquifers1

Jang, Cheng‐Shin, Chen‐Wuing Liu, Shih‐Kai Chen, and Wen‐Sheng Lin, 2011. Using a Mass Balance Model to Evaluate Groundwater Budget of Seawater‐Intruded Island Aquifers. Journal of the American Water Resources Association (JAWRA) 48(1): 61‐73. DOI: 10.1111/j.1752‐1688.2011.00593.x Abstract: The study developed a mass balance model to evaluate the groundwater budget of seawater‐intruded island aquifers using limited available data. The Penghu islands were selected as a study area. As sparse observed data were available in the islands, methods of combining water and chloride balances were used to determine the amounts of groundwater pumping, seawater intrusion, aquifer storages, and safe yields in the shallow and deep aquifers. The groundwater budget shows that seawater intrusion to freshwater aquifers was 1.38 × 10⁶ and 0.29 × 10⁶ m³/year in the shallow and deep aquifers, respectively, indicating that the seawater intrusion is severe in the both aquifers. The safe yield of the shallow aquifer was 14.56 × 10⁶ m³/year in 2005 which was four times higher than that of the deep aquifer (3.70 × 10⁶ m³/year). However, the annual pumping amounts in the shallow and deep aquifers were 4.77 × 10⁶ and 3.63 × 10⁶ m³/year, respectively. Although the safe yield of the shallow aquifer is enough for all water resources demands, only 55% of exploitation amount was extracted from the shallow aquifer due to its poor water quality. Groundwater exploitation in the deep aquifer should be significantly reduced and regulated by a dynamic management of pumping scheme because the annual pumping amounts are close to the safe yield and seawater intrusion occurs continually. Additionally, to alleviate further aquifer salination, at least half of the current annual groundwater abstraction should be reduced.     

Crop biodiversity,productivity and production risk: Panel data micro‐evidence from Ethiopia

This paper uses data from the Central Highlands of Ethiopia to assess the productivity and production risk impacts of crop diversification. Using count index as a measure of crop biodiversity, results show that increasing crop biodiversity contributes positively to farm level productivity. In addition, the findings suggest that the level of production risk significantly responds to the level of diversity, with the effect highly conditional on the skewness. The major contribution of the paper is that, unlike previous similar studies that tended to focus on intra‐crop diversity, it incorporates the mutual interdependencies across crops within a farm by focusing on inter‐crop diversity. Hence the study adds to the growing empirical literature, particularly in Africa, that tests empirical relationships between productivity, risk and crop diversity. An important policy implication for a diversity rich country such as Ethiopia is that agro‐biodiversity can be used to improve agricultural productivity while promoting in situ conservation.     

A disaggregated emissions inventory for Taiwan with uses in hybrid input‐output life cycle analysis (IO‐LCA)

This paper reports on a life‐cycle analysis (LCA) of Taiwan's “agriculture and forestry”, “crude petroleum, coal and natural gas extraction” and “electricity generation” sectors, revealing for the first time Taiwan's CO₂ and CH₄ emissions inventories and matching Taiwan's input‐output sectors. Integrated hybrid input‐output life cycle analysis is used to disaggregate the electricity generation sector into nuclear, hydro, gas, oil and coal, and cogeneration. Results show that the fossil‐fuel‐related electricity sub‐sectors have higher CO₂ emissions intensity than the remaining sectors in the economy and that the “paddy rice” sector is Taiwan's most CH₄‐intensive sector, making rice cultivation an important source of CH₄ emissions. This work is vital to sound policy decisions concerning power generation, coal, and agriculture and forestry at the national level.