Leaching of copper,chromium and arsenic in a soil of south west Victoria,Australia

The movement of copper, chromium and arsenic originating from samples of the wood preservative Tanalith® through mildly acidic, sandy loam soil was investigated. Small, undisturbed soil cores (of dimensions 15 × 15 × 15 cm) were removed from the topsoil of a paddock adjacent to the Glenelg River in the Western District of Victoria, Australia. The paddock soils were thin (<30cm) greyish brown, mildly acidic, sandy loams with a moderate organic carbon content (2–5%) overlying a limestone cap. Tanalith® was applied to the surface of the cores which were then irrigated with deionised water at approximately 30 mm day^‐1. Copper concentrations in all leachate remained at background levels throughout the experiment, and this element was found to be immobilised in the top 4 cm of the soil. Up to 29% of the applied dose of chromium was detected in the leachate, with breakthrough occurring within 20 days of Tanalith® application. Up to 13% ofthe applied dose ofarsenic was detected in the leachate, although in this case breakthrough was not observed until 25 days after Tanalith® application and leachate concentrations were still rising when the experiment came to a close. Significant concentrations of arsenic and chromium were found in the top 6 cm of the soil profile.     

The extraction and utilization of local and scientific geospatial knowledge within the Bluff oyster fishery, New Zealand

This paper assesses the Bluff oyster fishery in New Zealand as a case study in common pool resource management. It discusses ways in which modern information technology, augmented by low-tech data gathering strategies and community ethnography, can be used to produce an integrated scientific and local knowledge-inspired fishery database that lends itself to fostering collaboration in resource management and planning. The specific context and state of the oyster fishery in Bluff are described. Issues regarding undocumented and ephemeral intergenerational knowledge, much of which is geospatial in nature, on the fishery, the current crisis that many see in the future of the fishery, and a lack of cohesion or common sense of purpose between the stakeholder groups are discussed. It is argued that the digital resource that results from the integration of local and scientific knowledge and the potential community building processes that can ensue from collaboration and dialogue around this centrepiece are of central importance in developing an oyster fishery management plan that is holistic in concept and sustainable in purpose.     

Lessons for sustainability from the world’s most sustainable culture

Environmentally sustainable development is one of the key challenges faced by societies today. Yet it is not a new challenge; throughout history, societies have faced the need to live within environmental constraints. Some have done so well, and some poorly. One society which did well for tens of thousands of years is that of Aboriginal Australia. This paper explores some lessons from Aboriginal Australia which have resonance in the modern world and shows that countries which have learned those lessons are in fact more sustainable than those which have not. It thus suggests that there is much that the pantheon of human experience can teach the modern world as it endeavours to create a sustainable future.     

Subregional differences in Australian climate risk perceptions: coastal versus agricultural areas of the Hunter Valley,NSW

‘Environmental cognitive stress’ a hybrid model combining environmental stress and cognitive determinants of pro-environmental behavior is explored among Australians living in contrasting ‘micro’ climates in the same river catchment system. Peoples’ climate risk perceptions are mediated by their connections to local environment, observations of environmental change and personal weather experiences. A longitudinal study randomly sampled 1,162 Hunter Valley coastal and rural residents in New South Wales. Telephone interviewers (2008) recruited lakeside homeowners ‘at risk’ of sea level rise, nearby ‘control’ residents and a comparable farming area group. Follow-up interviews (2011) located 81.5 % of the original sample. Fifty-six items based on the model asked about climate change observations, concerns, impacts and actions. Statistically significant rural–suburban and time differences were found. The rural sample was attuned to conditions affecting agricultural productivity: They worried about drought and heat, saw trees dying and changes to seasons and natural rhythms. They anticipate the impact of water scarcity, conserve water and value protecting plants and animals. Compared to higher elevation residents, lake dwellers observed marine life loss, worry about sea level rise and predict the decline of property values. Across time, all groups’ perceptions of warming indicators declined. Concerns and impacts were high and generally stayed high, as did actions related to energy use. No differences emerged in beliefs about climate warming. Climate change observations, along with concerns and actions, have important implications for the environmental cognitive stress model. Overall, dynamic changes in residents’ understandings are related to a changing policy environment, the vicissitudes of climate debates and weather experiences, including extreme swings from inundation to drought.     

The role of humic non-exchangeable binding in the promotion of metal ion transport in groundwaters in the environment

Metal ions form strong complexes with humic substances. When the metal ion is first complexed by humic material, it is bound in an 'exchangeable' mode. The metal ion in this fraction is strongly bound, however, if the metal-humic complex encounters a stronger binding site on a surface, then the metal ion may dissociate from the humic substance and be immobilised. However, over time, exchangeably-bound metal may transfer to a 'non-exchangeable' mode. Transfer into this mode and dissociation from it are slow, regardless of the strength of the competing sink, and so immobilisation may be hindered. A series of coupled chemical transport calculations has been performed to investigate the likely effects of non-exchangeable binding upon the transport of metal ions in the environment. The calculations show that metal in the non-exchangeable mode will have a significantly higher mobility than that in the exchangeable mode. The critical factor is the ratio of the non-exchangeable first-order dissociation rate constant and the residence time in the groundwater column, metal ion mobility increasing with decreasing rate constant. A second series of calculations has investigated the effect of the sorption to surfaces of humic/metal complexes on the transport of the non-exchangeably bound metal. It was found that such sorption may reduce mobility, depending upon the humic fraction to which the metal ion is bound. For the more weakly sorbing humic fractions, under ambient conditions (humic concentration etc.) the non-exchangeable fraction may still transport significantly. However, for the more strongly sorbed fractions, the non-exchangeable fraction has little effect upon mobility. In addition to direct retardation, sorption also increases the residence time of the non-exchangeable fraction, giving more time for dissociation and immobilisation. The non-exchangeable dissociation reaction, and the sorption reaction have been classified in terms of two Damkohler numbers, which can be used to determine the importance of chemical kinetics during transport calculations. These numbers have been used to develop a set of rules that determine when full chemical kinetic calculations are required for a reliable prediction, and when equilibrium may be assumed, or when the reactions are sufficiently slow that they may be ignored completely.     

Using Measurements of Nitrogen Oxides to Estimate the Emission Controls Required to Meet the UK Nitrogen Dioxide Standard

In this paper we introduce a new method of analysing the relationship between nitrogen dioxide (NO₂) and oxides of nitrogen (NO_x) concentrations using data from the UK National Air Quality Archive. The study includes analyses of measurements from two different types of site in London, a kerbside site: Cromwell Rd, and three background sites: Bridge Place, London Bloomsbury and West London, over several years (1991–7). The data in some years showed that hourly NO₂ concentrations exceeded the UK Standard of 150 ppb. Data were binned, averaged, and polynomials fitted at each site. Analysis of the resulting polynomials was used to estimate reductions in NO_x emission required to achieve the National Air Quality Strategy Objective. Examination of the empirical ratio NO₂:NO_x (the 'yield') gives an indication of the sensitivity of the NO₂ to NO_x controls and the amount of NO₂ that would arise from modelled values of total oxides of nitrogen. The response of NO₂ to emission changes is very non-linear, implying 30–45% controls on NO_x may be required.     

Contribution of Burning of Agricultural Wastes to Photochemical Air Pollution

Agricultural wastes from orchards, grain fields, and range lands are burned each year in California as the most practical means of ridding the land of these wastes. In order to determine the relative contribution of the burning of such material to photochemical air pollution, the effluent from 1 23 fires of known weights of range brush, both dry and green, barley and rice stubble, and prunings from various fruit and nut trees were monitored in a special tower which provided an open burning situation. Analyses were made for total hydrocarbon, expressed as C, by flame ionization detection, and for 24 individual hydrocarbons by gas chromatography, as well as for CO and CO₂ by infrared spectroscopy. A few analyses were made for oxides of nitrogen. These data, coupled with temperature and airflow measurements, allowed calculations to be made on pounds of effluent per ton of material burned and demonstrated that the emissions from agricultural burning are much less than those from the automobile, a principal source of such emissions.     

Carbon bed mercury emissions control for mixed waste treatment

Mercury has various uses in nuclear fuel reprocessing and other nuclear processes, and so it is often present in radioactive and mixed (radioactive and hazardous) wastes. Compliance with air emission regulations such as the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards can require off-gas mercury removal efficiencies up to 99.999% for thermally treating some mixed waste streams. Test programs have demonstrated this level of off-gas mercury control using fixed beds of granular sulfur-impregnated activated carbon. Other results of these tests include (1) the depth of the mercury control mass transfer zone was less than 15-30 cm for the operating conditions of these tests; (2) MERSORB carbon can sorb mercury up to 19 wt % of the carbon mass; and (3) the spent carbon retained almost all (98.3-99.99%) of the mercury during Toxicity Characteristic Leachability Procedure (TCLP) tests, but when even a small fraction of the total mercury dissolves, the spent carbon can fail the TCLP test when the spent carbon contains high mercury concentrations.