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71.
Aziz Azri Galal Elmanfe René Olier Mireille Privat 《Atmospheric environment (Oxford, England : 1994)》2010,44(39):5211-5217
From a literature-based assessment of the current knowledge about both the toxic or salutary properties of copper, this study focused on the determination, at 25 °C, of the interfacial properties of CuCl2, either alone or in mixture with carbofuran used, here, as a model of organics and/or pesticide. The interfaces under study were: i) the air/solution interface and ii) the silica/solution interface. The former is considered as a path for volatilization, whereas the latter permits a modelling of physical adsorption upon solids, which is the first and unavoidable step in any adsorption process. One should note that it can also mimic adsorption on some sandy soils. Coadsorption was clearly identified as implicated in an enhancement of the surface content of both solutes at both interfaces. However, at the two interfaces under study, the way the surface became structured led to opposite adsorption mechanisms for the organic compounds and the salt. A rough theory about ionic adsorption is also proposed. 相似文献
72.
Kärrman Anna Domingo José L. Llebaria Xavier Nadal Martí Bigas Esther van Bavel Bert Lindström Gunilla 《Environmental science and pollution research international》2010,17(3):750-758
Background, aim and scope
Perfluorinated compounds (PFCs) are global environmental pollutants that bioaccumulate in wildlife and humans. Laboratory experiments have revealed toxic effects such as delayed development, humoral suppression, and hepatotoxicity. Although numerous human blood levels have been reported, little is known about distribution in the human body. Knowledge about PFC distribution and accumulation in the human body is crucial to understanding uptake and subsequent effects as well as to conduct risk assessments. The present study reports PFC levels in human liver and breast milk from a general population living in Catalonia, Spain. Liver and milk levels are compared to previously reported levels in blood from the same geographic area as well as to other existing reports on human liver and milk levels in other countries. 相似文献73.
Alexandre Joly Audrey Smargiassi Tom Kosatsky Michel Fournier Ewa Dabek-Zlotorzynska Valbona Celo David Mathieu René Servranckx Réal D'amours Alain Malo Jeffrey Brook 《Atmospheric environment (Oxford, England : 1994)》2010,44(34):4325-4329
Little is known about the level and content of exposure to fine particles (PM2.5) among persons who attend fireworks displays and those who live nearby. An evaluation of the levels of PM2.5 and their elemental content was carried out during the nine launches of the 2007 Montréal International Fireworks Competition. For each event, a prediction of the location of the firework plume was obtained from the Canadian Meteorological Centre (CMC) of the Meteorological Service of Canada. PM2.5 was measured continuously with a photometer (Sidepak?, TSI) within the predicted plume location (“predicted sites”), and integrated samples were collected using portable personal samplers. An additional sampler was located on a nearby roof (“fixed site”). The elemental composition of the collected PM2.5 samples from the “predicted sites” was determined using both a non-destructive energy dispersive ED-XRF method and an ICP-MS method with a near-total microwave-assisted acid digestion. The elemental composition of the “fixed site” samples was determined by the ICP-MS with the near-total digestion method. The highest PM2.5 levels reached nearly 10 000 μg m?3, roughly 1000 times background levels. Elements such as K, Cl, Al, Mg and Ti were markedly higher in plume-exposed filters. This study shows that 1) persons in the plume and in close proximity to the launch site may be exposed to extremely high levels of PM2.5 for the duration of the display and, 2) that the plume contains specific elements for which little is known of their acute cardio-respiratory toxicity. 相似文献
74.
José Mario Aquino Romeu C. Rocha-Filho Cristina Sáez Pablo Cañizares Manuel A. Rodrigo 《Environmental science and pollution research international》2014,21(14):8442-8450
Oxidation of anthraquinonic dye Acid Blue 62 by electrolysis with conductive-diamond electrodes is studied in this work. COD, TOC, and color have been selected to monitor the degradation of the molecule as a function of several operating inputs (current density, pH, temperature, and NaCl concentration). Results show that the electrochemical oxidation of this model of large molecules follows a first order kinetics in all the conditions assessed, and it does not depend on the pH and temperature. The occurrence of chloride ions in wastewaters increases the rate of color and COD removal as a consequence of the mediated oxidation promoted by the chlorinated oxidizing species. However, chloride occurrence does not have an influence on the mineralization rate. First-order kinetic-constants for color depletion (attack to chromophores groups), oxidation (COD removal), and mineralization (TOC removal) were found to depend on the current density and to increase significantly with its value. A single model was proposed to explain these changes in terms of the mediated oxidation processes. Rate of mineralization remained very close to that expected for a purely mass transfer-controlled process. This was explained assuming that mediated oxidation does not have a significant influence on the mineralization in spite it has some effect on intermediate oxidation stages. The efficiency of the oxidation was found to depend mainly on the concentration of COD being negligible the effect of the other inputs assessed except for the occurrence of chloride ions. Opposite, the efficiency of mineralization depends on concentration of TOC and current density and it did not depend on the chloride occurrence. This observation was found to have an important influence on the power required to remove a given percentage of the initial TOC or COD. To decrease COD efficiently, the occurrence of chloride in the solution is very important, while to remove TOC efficiently, it is more important to work at low current densities and chloride effect is negligible. Energy consumption could be decreased by folds using the proper conditions. 相似文献
75.
Carolina Fernández-Ramos Oscar Ballesteros Alberto Zafra-Gómez Francisco Javier Camino-Sánchez Rosario Blanc Alberto Navalón José Luís Vílchez 《Environmental science and pollution research international》2014,21(6):4286-4296
The study describes the environmental monitoring of anionic surfactants―alcohol sulfates (AS) and alcohol ethoxysulfates (AES)—in marine sediments. Concentration values were obtained after pressurised liquid extraction (PLE) and liquid chromatography–tandem mass spectrometry analysis (LC–MS/MS). Samples were collected from a range of wastewater discharge points along the coast of the provinces of Huelva, Málaga, Granada and Almería. Urban, agricultural and industrial wastewaters are discharged at the selected 38 sampling sites. Principal component analysis was carried out in order to evaluate the distribution and behaviour of these compounds in these coastal environments. Evaluation of the data revealed that the behaviour and sources of AS and AES in marine sediments are different, and that the distribution of AES depends on the length of the alkyl chain, while the number of ethoxylated units is not relevant. Additionally, the 38 sampling sites can be grouped into only two types of outfalls according to their AS distribution. The concentration of compounds in sediment samples ranged from 7.52 to 13.50 mg kg?1 for AS, from 3.04 to 10.68 mg kg?1 for AES–C12Ex and from 3.83 to 11.56 mg kg?1 for AES–C14Ex. 相似文献
76.
Nicola Cortesi José Carlos Gonzalez-Hidalgo Michele Brunetti Martín de Luis 《Regional Environmental Change》2014,14(5):1743-1749
The spatial variability of annual and seasonal precipitation in the conterminous land of Spain has been evaluated by using correlation decay distance analysis (CDD). The CDD analysis essentially explores how the correlation between neighbouring stations varies according to distance. We analysed CDD independently for the decades 1956–1965, 1966–1975, 1976–1985, 1986–1995, and 1996–2005 using only those stations with no missing values for each decade. To this end, 972, 1,174, 1,242, 773 and 695 complete series were used for each decade, respectively. In particular, for each station and decade, we calculated the threshold distance at which the common variance between target (i) and neighbour series is higher than 50 % (r 2 = 0.5) to evaluate whether current density of the climate data set captures the spatial variability of precipitation within the study area. Results indicate that, at an annual scale, neighbouring stations with 50 % of common variance are restricted on average to about 105 km, but this distance can vary from 28 to 251 km within the study area. The lowest variability is located to the SW and in winter, while the higher spatial variability is found to the north, in the Cantabrian area, and to the east, in the Mediterranean and Pyrenees, during summer. Our results suggest that current density of climate stations (those operating in 2005) is good enough to study precipitation variability at an annual scale for winter, spring and autumn, but not enough for summer. 相似文献
77.
Elisa Oteros-Rozas Berta Martín-López José A. González Tobias Plieninger César A. López Carlos Montes 《Regional Environmental Change》2014,14(4):1269-1289
The ecosystem services framework is receiving increasing attention in the fields of policy and research. The assessment of human attitudes and perceptions regarding ecosystem services has been proposed as a promising tool for addressing complex problems associated with environmental change, particularly in the context of cultural landscapes. Transhumance is not only a farming practice responsible for shaping cultural landscapes but also an adaptive strategy based on mobility that may represent a useful approach to overcoming the growing challenges posed by accelerated environmental change. A socio-cultural valuation of ecosystem services associated with the Conquense Drove Road, one of the major transhumant networks still in use in Mediterranean Spain, was conducted via the distribution of questionnaires to 416 local residents and visitors to capture their perceptions regarding the importance of 34 ecosystem services (10 provisioning, 12 regulating, and 12 cultural) for both social and personal well-being. Overall, the ecosystem services considered to be the most important for social well-being were fire prevention, air purification and livestock. Most of the ecosystem services in question were perceived as declining, with the exception of those associated with recreation, scientific knowledge and environmental education. This study revealed that perceptions regarding the value of ecosystem services differed among respondents, depending on their age, place of origin and gender. Several methodological issues, as well as the implications of socio-cultural valuation for policy making, are also discussed here. 相似文献
78.
Flavia Tromboni Lucia Bortolini José Antonio Morábito 《Environment, Development and Sustainability》2014,16(6):1317-1336
This study presents an integrated hydrologic–economic model as decision support system for groundwater use and incorporates uncertainties of climate change. The model was developed with the Vensim software (Ventana Systems) for system dynamic simulations. The software permitted the integration of economic variables along with hydrologic variables, in a unified format with the aim of evaluating the economic impacts of climate change on arid environments. To test the model, we applied it in one of the upper Tunuyán River sub-basin, located in the Mendoza Province (Argentina), where irrigation comes from groundwater. The model defines the best mix of crops and the total land use required to maximize the total river sub-basin monetary income, considering as a limit the amount of water that does not exceed the natural annual aquifer recharge. To estimate the impacts of climatic changes, four scenarios were compared: the business as usual (with the number of existing wells) in a dry year with a temperature increase of 4 °C; the business as usual in a wet year with an increase in temperature of 1.1 °C; an efficient use of wells in a dry year and a temperature increase of 4 °C and an efficient use of wells in a wet year with a temperature increase of 1.1 °C. Outputs calculated by the model were: land use per crop, total sub-basin net benefit, total sub-basin water extraction, water extraction limit depending on river discharge and total number of wells required to irrigate the entire area. Preliminary results showed that the number of existing wells exceeded the optimized number of wells required to sustainably irrigate the entire river sub-basin. Results indicated that in an average river discharge year, if wells were efficiently used, further rural development would be possible, until the limit of 350 million m3 of water extraction per year was reached (650 million m3 for a wet year and 180 million m3 for a dry year). The unified format and the low cost of the software license make the model a useful tool for Water Resources Management Institutions, particularly in developing countries. 相似文献
79.
Thalita Rangueri de Barros Sandro Donnini Mancini José Lázaro Ferraz 《Environment, Development and Sustainability》2014,16(2):415-429
A study was made of the composition of wastes collected from the pipes of the stormwater drainage system of Sorocaba, SP, Brazil (600 thousand inhabitants). A total of 10 samples weighing at least 100 kg each were sorted into 19 items to determine the fraction that can be considered natural (earth/sand, stones, organic matter, and water, the latter determined after oven-drying the samples) and the anthropogenic fraction (the remaining 15 items, especially construction and demolition wastes and packaging). Soil/sand was found to be the main item collected (52.5 % dry weight), followed by the water soaked into the waste (24.3 %), which meant that all the other wastes were saturated in mud, whose contents varied from 6.4 % (glass) to 87.2 % (metalized plastics packaging). In general, 83 % of the collected wastes can be classified as “natural,” but the remaining 17 % represent 2,000 kg of the most varied types of wastes discarded improperly every day on the streets of the city. This is an alarming amount of wastes that may clog parts of the drainage systems, causing troubles for all the population (like flooding) and must be strongly considered in municipal solid wastes management and in environmental education programs. 相似文献
80.
Juan José Cabello Dunia Garcia Alexis Sagastume Rosario Priego Luc Hens Carlo Vandecasteele 《Environment, Development and Sustainability》2012,14(4):573-591
This paper analyzes the Cuban model of sustainable development and explains the causes that made Cuba the only country that meets the conditions of sustainability according to the Worldwide Fund for Nature (WWF). The Human Development Index has three main components: quality of life (health indicator measured as life expectancy at birth), knowledge (education indicator measured as adult literacy) and the standard of life (economic indicator measured by the Gross Domestic Income). This paper analyses the aspects of the educational and health system of Cuba and also of its energy policies that explain the excellent scores of the Human Development Index. Cuba shows a Human Development Index of 0.8 with an Ecological Footprint of 1.8?gha. This is achieved with a Gross Domestic Income lower than other countries with similar Human Development Index. The Ecological Footprint of Cuba is mainly determined by the CO2 and the agricultural land footprint. The paper shows how the economic transition, after the economic crisis of the early 1990s, was realized without significantly increasing the Ecological Footprint. 相似文献