全文获取类型
收费全文 | 2552篇 |
免费 | 74篇 |
国内免费 | 24篇 |
专业分类
安全科学 | 182篇 |
废物处理 | 151篇 |
环保管理 | 542篇 |
综合类 | 298篇 |
基础理论 | 586篇 |
环境理论 | 3篇 |
污染及防治 | 582篇 |
评价与监测 | 179篇 |
社会与环境 | 92篇 |
灾害及防治 | 35篇 |
出版年
2023年 | 13篇 |
2022年 | 19篇 |
2021年 | 27篇 |
2020年 | 26篇 |
2019年 | 26篇 |
2018年 | 61篇 |
2017年 | 58篇 |
2016年 | 76篇 |
2015年 | 72篇 |
2014年 | 70篇 |
2013年 | 231篇 |
2012年 | 108篇 |
2011年 | 148篇 |
2010年 | 114篇 |
2009年 | 131篇 |
2008年 | 127篇 |
2007年 | 143篇 |
2006年 | 133篇 |
2005年 | 97篇 |
2004年 | 85篇 |
2003年 | 107篇 |
2002年 | 72篇 |
2001年 | 54篇 |
2000年 | 53篇 |
1999年 | 41篇 |
1998年 | 39篇 |
1997年 | 35篇 |
1996年 | 33篇 |
1995年 | 26篇 |
1994年 | 34篇 |
1993年 | 31篇 |
1992年 | 21篇 |
1991年 | 24篇 |
1990年 | 13篇 |
1989年 | 11篇 |
1988年 | 16篇 |
1987年 | 19篇 |
1986年 | 13篇 |
1985年 | 19篇 |
1984年 | 12篇 |
1983年 | 18篇 |
1982年 | 19篇 |
1981年 | 24篇 |
1980年 | 13篇 |
1979年 | 10篇 |
1978年 | 6篇 |
1977年 | 9篇 |
1971年 | 6篇 |
1957年 | 5篇 |
1955年 | 5篇 |
排序方式: 共有2650条查询结果,搜索用时 15 毫秒
241.
Donald S. Cherry John H. Van Hassel Paul H. Ribbe John Cairns 《Journal of the American Water Resources Association》1987,23(2):293-306
ABSTRACT: The potentially toxic components in coal ash (ash particles, heavy metals) were evaluated in laboratory static, acute (96 hr) bioassays, both separately and in various combinations with extreme pH (5.0 and 8.5), using rainbow trout (Salmo gairdneri) and bluegifi sunfish (Lepomis macrochirus). Ash particle morphology and metal distribution anlaysis, using electron microscopy and surface-subsurface analysis by ion microscopy, showed that metals could be either clumped or evenly distributed on the surface of fly ash. Surface enrichment on fly ash particles from electrostatic precipitators, as measured by ion microscopy, was found for cadmium, copper, chromium, nickel, lead, mercury, titanium, arsenic, and selenium. Bottom (heavy) ash was not acutely toxic to either fish species at concentrations of up to 1500 mg/l total suspended solids (TSS) at pH 5.0, 7.5, or 8.5. Fly ash particles were not acutely toxic to blue-gill at levels up to 1360 mg/l TSS. Rainbow trout were highly sensitive to fly ash (25 to 60 percent mortality) at concentrations of 4.3 to 20.5 mg/I TSS when dissolved metal availability was high but were not sensitive at higher particulate concentrations (58 to 638 mg/I TSS) when dissolved metals were low. When metals were acid-leached from fly ash prior to testing, no rainbow trout mortality occurred at TSS concentrations of up to 2,350 mg/l TSS. When the percent of dissolved metal was high (e.g., 50–90 percent of the total), fish mortality was increased. Rainbow trout were nearly two orders of magnitude more sensitive than bluegill when subjected to a blend of cadmium, chromium, copper, nickel, lead, and zinc. The two species were similar in their acute sensitivity to acidic pH at levels at or below 4.0 and alkaline pH of 9.1. If the pH of coal ash effluent is contained within the range 6.0 to 9.0, acute toxicity to fish can be attributed to trace element availability from fly ash but not heavy ash. Control of holding pond and effluent pH and maximizing pond residence time are important strategies for minimizing effects of ash pond discharges on fish. 相似文献
242.
Paul Lawless 《Journal of Environmental Planning and Management》1988,31(1):13-18
There has been a marked proliferation of local economic development initiatives in recent years. Enterprise Boards have proved one of the most successful of these innovations. In the early 1980s five were established. Two, the Greater London and the West Midlands Enterprise Boards, were initially designed to intervene radically within their local economies, although subsequent events moderated their activities. The remaining three in Lancashire, West Yorkshire and Merseyside, have successfully widened their operations to embrace collaborate projects with the private sector, training, boosting co‐operatives, and research. By many economic evaluations, for example, jobs supported, leverage ratios and investment per job, Enterprise Boards have performed better than other instruments of urban and regional development. Wider socio‐political objectives have proved more difficult to achieve. 相似文献
243.
Paul N. Wilson Teddy J. Goldammer James C. Wade 《Journal of the American Water Resources Association》1988,24(1):1-9
ABSTRACT: Urban wastewater can be a valuable source of water and plant nutrients for agricultural producers, particularly in arid regions. The scientific literature reveals cautious optimism concerning the biological, institutional, and economic viability of irrigating crops with secondary-treated effluent. A derived effluent demand function for agricultural producers near Tucson, Arizona, reveals a potential annual demand of 11,000 acre-feet under present price and proposed delivery system conditions. In this case, wastewater could be exchanged for ground water and both the urban and rural areas would gain. 相似文献
244.
245.
The natural degradation of monophenylheptamethylcyclotetrasiloxane and 2,6-cis-diphenylhexamethylcyclotetrasiloxane in soil was evaluated under laboratory conditions. Both monophenyl and 2,6-cis underwent rapid degradation in dry soil generating the same products in varying proportions. During the first 24 hr, approximately 99% of the two materials underwent significant chemical transformations forming silanols of various structures, dimethyl cyclic siloxanes of the structure (Me2SiO)x, and rearrangement products (geometrical isomers) of diphenylhexamethylcyclotetrasiloxane. Among the silanols, the following were identified as trimethylsilyl derivatives: HOSiMe2OH, HOSiMePhOH, HOSiMe2OSiMe2OH, HOSiMePhOSiMe2OH, HOSiMePhOSiMePhOH, HOSiMe2OSiMe2OSiMe2OH, HOSiMePhOSiMe2OSiMe2OH, HOSiMe2OSiMePhOSiMe2OH, HOSiMePhSiMe2OSiMePhOH, HOSiMePhOSiMePhOSiMe2OH, HOSiMePhOSiMe2OSiMe2OSiMe2OH, HOSiMe2OSiMePhOSiMe2OSiMe2OH, HOSiMePhOSiMe2OSiMePhOSiMe2OH, HOSiMePhOSiMePhOSiMe2OSiMe2OH, HOSiMePhOSiMe2OSiMe2OSiMePhOH, HOSiMe2OSiMePh-OSiMePhOSiMe2OH. Derivatization was carried out using bis(trimethylsilyl)trifluoroacetamide. Gas chromatography-mass spectrometry and liquid chromatography-mass spectrometry (atmospheric pressure chemical ionization) analyses were used to derive structures. Structures were confirmed by gas chromatography-mass spectrometry comparisons of synthetic standards. Degradation was slower in wet soil. Nevertheless, in 14 days, the chemical transformation was essentially found to be complete as soil was allowed to dry. Detection of phenol as one of the degradation products revealed the occurrence of carbon–silicon bond cleavage promoted by soil. 相似文献
246.
Vaughan Shilton Paul Giess David Mitchell Craig Williams 《Water, Air, & Soil Pollution: Focus》2002,2(5-6):237-246
Settled dust has been collected inside the main foyers ofthree University buildings in Wolverhampton City Centre,U.K. Two of the three buildings are located in a streetcanyon used almost exclusively by heavy duty dieselvehicles. The dust was collected on adhesive carbonspectro-tabs to be in a form suitable for analysis byscanning electron microscope and energy dispersive X-rayanalysis. Using these analytical techniques, individualparticle analysis was undertaken for morphology andchemistry. Seasonal variations and variations due tolocation were observed in both the morphologicalmeasurements and chemical analysis. Many of the differencesappear attributable to the influence of road traffic, inparticular, the heavy duty diesel vehicles, travellingalong the street canyon. 相似文献
247.
Paul Benneworth Leanne Conroy Peter Roberts 《Journal of Environmental Planning and Management》2002,45(2):199-217
This paper examines the institutional impacts of the new English regional sustainability framework and highlights the tension between the need for regional involvement and the central desire to control the debates and intentions of the regional actors. The paper argues that the regional sustainable development frameworks have been worth writing because they have had a strong demonstration effect: they have allowed regional chambers to become more proactive bodies independent of the regional development agencies (which chambers were created to scrutinize). They have also allowed pluralistic conceptions of sustainable regional development to develop in the English regions alongside the economistic perspectives of national policy makers. 相似文献
248.
Land Evaluation for Maize Based on Fuzzy Set and Interpolation 总被引:1,自引:0,他引:1
The objective of this article is to apply fuzzy set and interpolation techniques for land suitability evaluation for maize in Northern Ghana. Land suitability indices were computed at point observations using the Semantic Import (SI) model, whereas spatial interpolation was carried out by block kriging. Interpolated land suitability shows a high correlation (R2 = 0.87) with observed maize yield at the village level. This indicates that land suitability is closely related to maize yield in the study area. Membership functions were further used to assess the degree of limitation of land characteristics to maize. Sixty percent of the data has membership functions ranging from 0.23 for ECEC to 1.00 for drainage. ECEC, organic C, and clay are the major constraints to maize yield. The use of the fuzzy technique is helpful for land suitability evaluation, especially in applications in which subtle differences in soil quality are of a major interest. Furthermore, the use of kriging that exploits spatial variability of data is useful in producing continuous land suitability maps and in estimating uncertainties associated with predicted land suitability indices. 相似文献
249.
Munitions wastes such as TNT are widespread contaminants in soils and ground waters. We investigated a coupled abiotic-biotic treatment scheme for remediation of aqueous solutions of TNT. Mineralization of aqueous TNT (0.22 mM) was initially optimized with minimum reactant use (Fe3+ and H2O2) in light-assisted and dark, modified Fenton reactions at acidic and neutral pH. Complete TNT degradation occurred under all reaction conditions within 24 h. Using the optimum reactant concentrations, coupled abiotic-biotic reactions showed an increase in TNT mineralization, from 47 to 80%, after biomass addition to the acidic, dark Fenton-like reaction. Comparable increases of TNT mineralization were observed under neutral pH with similar reaction conditions. In light-assisted Fenton-like reactions at neutral pH, no increase in cumulative TNT mineralization (66%) was seen in coupled abiotic-biotic reactions. Abiotic photo-Fenton-like reactions alone, at acidic pH, produced complete TNT mineralization and required no biotic assistance. While light-enhanced Fenton reactions alone can provide high levels of TNT mineralization, the dark abiotic-biotic reaction scheme has perhaps a wider use due to a similar extent of TNT mineralization in the absence of light, leading to possible applications in soil slurry and in situ processes in the subsurface. 相似文献
250.
Few would now deny that the use of organobromine compounds to achieve fire retardancy in a diverse array of products and materials has led to contamination of the ecosphere on a widespread scale. This environmental prevalence and persistence of the brominated flame retardants, coupled with growing evidence of their potential for harm, present all too familiar parallels with the previous generation of persistent organic pollutants. Indeed, given the intrinsic properties of these brominated chemicals, the nature and extent of the current problem could well have been predicted in advance. The question is then whether we are prepared to let history repeat itself once more or to take precautionary action now to switch to more sustainable alternatives. The choice facing society is not between brominated flame retardants and unsafe products, but between fire safety leading to global contamination or fire safety achieved in less polluting ways. If we look beyond options for simple chemical-for-chemical substitution to alternative materials and designs, many of the solutions are already available. The remainder could undoubtedly be developed given the incentives to do so. However, a strong and clear policy approach, backed by legislative phase-outs within specified (and challenging) timeframes, will be necessary to break our current dependency on organobromine chemistry. This paper presents the justification for such an approach, reviews those initiatives already underway to replace brominated flame retardants and identifies pathways to the use of more sustainable products in the service of society. 相似文献