Portable X-ray fluorescence in the characterisation of arsenic contamination associated with industrial buildings at a heritage arsenic works site near Redruth,Cornwall, UK

An investigation using in situ analysis by portable X-ray fluorescence (PXRF) has shown that contamination present on industrial buildings at a heritage arsenic works site near Redruth, Cornwall, UK results from the absorption of arsenic by porous and semi-porous building materials that were in contact with arsenic-rich flue gases. Results from a preliminary survey indicate that arsenic remains locked in these materials and is being gradually leached out by weathering processes. This weathering causes general contamination of the adjacent building surfaces averaging 1845 microg g(-1) arsenic, presumably caused by evaporation of leach solutions in contact with air at the surface of the building materials. More extensive crystalline deposits were found under arches protected from dissolution and further dispersion by rain water. These deposits appeared to comprise calcium sulfate (gypsum), associated with on average between 1.2 and 6.8% m/m As. In situ PXRF proved to be highly effective in locating sources of contamination at the site and in providing data that allowed a hypotheses for the origin of this contamination to be formulated and tested in the field.     

A Comprehensive Approach to Identifying Monitoring Priorities of Small Landbirds on Military Installations

Military installations provide important native habitat for songbirds, including many species that have experienced population declines in recent decades. As part of the Land Condition Trend Analysis (LCTA) program to monitor animal populations on military lands, we surveyed small (<250 g) breeding landbirds on 60 permanent plots on the Fort Riley Military Installation in northeastern Kansas from 1991 to 2002. During this period, species richness averaged 39.0 species (SE 0.9)/year and mean species richness per plot ranged from 3.6 species (SE=0.2)/plot (1999) to 7.5 species (SE=0.3)/plot (1992). Turnover (the appearance and disappearance of species on all plots from one year to the next) ranged from 5 species (2000–2001) to 16 species (1992–1993) and was driven primarily by turnover of woodland species. We developed an index of relative difference (C) to evaluate relative trends of local populations and found that 25 species declined, 15 species increased, and 7 did not change. Based on migration assemblages, more resident species (6 of 10) and more short-distant migrants (9 of 12) decreased than long-distance migrants (10 vs. 11). Our analysis of major vegetation communities on plots showed few changes in the quantity of habitats (grassland vs. woodlands) during the study. Our results indicate that Fort Riley provides important habitats for many landbirds, particularly those that require grasslands for breeding. Several species exhibited local declines when compared to the regional Breeding Bird Survey routes. We offer an approach that evaluates population changes of small landbirds and provides objective inputs for conservation directives. These can be adopted easily for use on military installations (that use LCTA), parks, and wildlife refuges that have data from annual breeding bird surveys.     

Relationship between soil test phosphorus and phosphorus in runoff: effects of soil series variability

Phosphorus loss in runoff from agricultural fields has been identified as an important contributor to eutrophication. The objective of this research was to determine the relationship between phosphorus (P) in runoff from a benchmark soil (Cecil sandy loam; fine, kaolinitic, thermic Typic Kanhapludult) and Mehlich III-, deionized water-, and Fe(2)O(3)-extractable soil P, and degree of phosphorus saturation (DPS). Additionally, the value of including other soil properties in P loss prediction equations was evaluated. Simulated rainfall was applied (75 mm h(-1)) to 54 1-m(2) plots installed on six fields with different soil test phosphorus (STP) levels. Runoff was collected in its entirety for 30 min and analyzed for total P and dissolved reactive phosphorus (DRP). Soil samples were collected from 0- to 2-, 0- to 5-, and 0- to 10-cm depths. The strongest correlation for total P and DRP occurred with DPS (r(2) = 0.72). Normalizing DRP by runoff depth resulted in improved correlation with deionized water-extractable P for the 0- to 10-cm sampling depth (r(2) = 0.81). The STP levels were not different among sampling depths and analysis of the regression equations revealed that soil sampling depth had no effect on the relationship between STP and P in runoff. For all forms of P in runoff and STP measures, the relationship between STP and runoff P was much stronger when the data were split into groups based on the ratio of oxalate-extractable Fe to Al. For all forms of P in runoff and all STP methods, R(2) increased with the inclusion of oxalate-extractable Al and Fe in the regression equation. The results of this study indicate that inclusion of site-specific information about soil Al and Fe content can improve the relationship between STP and runoff P.     

Dispersion of odour: a case study with a municipal solid waste landfill site in North London,United Kingdom

Municipal solid waste (MSW) landfills are a potential source of offensive odours that can create annoyance within communities. Dispersion modelling was used to quantify the potential odour strength causing an impact on the community around a particular MSW landfill site north of the London area in the United Kingdom. The case studies were completed with the short-term mode of COMPLEX-I, software developed by the US-EPA. The year 1998 was chosen as a source of baseline data. It was observed that by 2004, when the landfill will progress towards the west and a big band of the area towards the north would be partly/fully restored, the maximum contribution of the new sources giving higher odour concentrations would be in the southwesterly regions away from the landfill. Concentrations as high as 25.0 ou(E)/m(3) were observed with 3 min averaging time in the southwesterly areas as compared to concentrations of 20.0 ou(E)/m(3) at 10 min averaging times. However, the percentage frequency of such critical events occurring would be low. All other surrounding farms and small villages would be exposed to the concentration of 3.0 ou(E)/m(3) on certain occasions. In the year 2008, the majority of the filling fronts would be filled with wastes with no contributions from the active and operational cells. The maximum odour concentration around the landfill site for 1 h averaging time would be approximately 3 ou(E)/m(3) about 1.0 km north and 500 m west of the landfill site. For 3 min averaging time, the stretch of 5 ou(E)/m(3) band would be up to 2.5 km towards the north of the landfill site. It is argued that further analysis of the model calculations considering effects of wind direction, frequency of wind direction, stability of the atmosphere, selected odour threshold, integration time of the model, etc. would form a basis for calculating the separation distances of the landfill site from the surrounding community.     

Phosphorus and ammonium concentrations in surface runoff from grasslands fertilized with broiler litter

Application of broiler (Gallus gallus domesticus) litter to grasslands can increase ammonium (NH4-N) and dissolved reactive phosphorus (DRP) concentrations in surface runoff, but it is not known for how long after a broiler litter application that these concentrations remain elevated. This long-term study was conducted to measure NH4-N and DRP in surface runoff from grasslands fertilized with broiler litter. Six 0.75-ha, fescue (Festuca arundinacea Schreb.-)bermudagrass [Cynodon dactylon (L.) Pers.] paddocks received broiler litter applications in the spring and fall of 1995-1996 and only inorganic fertilizer N in the spring of 1997-1998. Surface runoff from each paddock was measured and analyzed for NH4-N and DRP. Broiler litter increased flow-weighted NH4-N and DRP concentrations from background values of 0.5 and 0.4 mg L(-1), respectively, to values > 18 mg L(-1) in a runoff event that took place immediately after the third application. Ammonium concentrations decreased rapidly after an application and were not strongly related to time after application or runoff volume. In contrast, DRP concentrations tended to decrease more slowly, reaching values near 1 mg L(-1) by 19 mo after the last application. Dissolved reactive P concentrations decreased linearly with the natural logarithm of days after application (p<0.03), and increased linearly with the natural logarithm of runoff volume (p<0.0001).     

An empirical analysis of a goal setting questionnaire

This research presents an analysis of a goal setting questionnaire developed by Locke and Latham (1984). The Locke and Latham measure attempts to assess the core goal attributes of ‘specificity’ and ‘difficulty’, as well as other attributes of the goal setting process (such as perceptions about ‘performance feedback’, ‘supervisor support’, ‘conflict’ and ‘stress’). The psychometric properties of the measure were examined using respondents from employees of a large, west-coast electronics organization. A principal components analysis extracted 10 meaningful factors and identified a need for additional items. Results generally supported the meaningfulness of the goal setting factors and provide important directions for future research.     

A WATER RESOURCE PLANNING PROCEDURE FOR RURAL TOWNS1

ABSTRACT: Six new techniques have been developed for lake watershed analysis and water resource management. The techniques are for determining: (1) watershed land use intensity with reference to water quality, (2) lake vulnerability, (3) water quality, (4) watershed carrying capacity, (5) the economic value of the lake, and (6) the potential of undeveloped lake-shore. These analyses are designed for use by rural planning commissions with guidance and assistance from state agencies and the state university. The comprehensive rural watershed land and water use plan developed by this procedure is inexpensive in time and money, understandable by the layman, and scientificially sound. It is based on presently available information. This water resource planning procedure has been demonstrated in several town planning projects. It is suggested that this method, or modification of it, could be adopted in all rural states by action by a few administrators and without any new enabling or appropriations legislation.