地下车库汽车尾气污染源强计算浅析

近年来，地下车库空气污染越来越严重。在建设项目环境影响评价文件中．因为所采用的源强计算公式不同而导致不同的评价结果；所以就三种源强计算经验公式进行对比分析．发现公式二更适合地下车库污染源强的计算。     

A metal-OH group modification strategy to prepare highly-hydrophobic MIL-53-Al for efficient acetone capture under humid conditions

A series of highly-hydrophobic MIL-53-Al (MIL = Materials of Institut Lavoisier) frameworks synthesized via decoration of the Al-OH groups by alkyl phosphonic acid were developed as adsorbents for removing acetone from humid gas streams. The newly prepared materials were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), N₂ adsorption-desorption and thermogravimetric analysis (TGA). Their adsorption behaviors toward acetone vapor under dry and wet conditions were studied subsequently. Results showed that alkyl phosphonic acid was successfully grafted into MIL-53-Al skeleton through coordinating interaction with Al³⁺ generating [email protected]_x (x = 12, 14, 18). The [email protected]_x exhibited similar crystal structure and thermal stability to parent MIL-53-Al. Furthermore, the modified materials showed significantly enhanced hydrophobicity. The water vapor uptake of [email protected]₁₄ decreased by 72.55% at 75% relative humidity (RH). Dynamic adsorption experiments demonstrated that water vapor had almost no effect on the acetone adsorption performance of [email protected]₁₄. Under the condition of 90% RH, the acetone adsorption capacity of [email protected]₁₄ was 102.98% higher than that of MIL-53-Al. Notably, [email protected]₁₄ presented excellent adsorption reversibility and regeneration performance in 10 adsorption-desorption cycles. Taken together, the strategy of metal-OH group modification is an attractive way to improve the acetone adsorption performance over metal-organic frameworks (MOFs) under humid conditions. Besides, [email protected]₁₄ would be deemed as a promising candidate for capturing acetone in high moisture environment.     

Quantitative structure - activity study on the reductivedehalogenation potency of the halogenated aromatics

Ｑｕａｎｔｉｔａｔｉｖｅｓｔｒｕｃｔｕｒｅ－ａｃｔｉｖｉｔｙｓｔｕｄｙｏｎｔｈｅｒｅｄｕｃｔｉｖｅｄｅｈａｌｏｇｅｎａｔｉｏｎｐｏｔｅｎｃｙｏｆｔｈｅｈａｌｏｇｅｎａｔｅｄａｒｏｍａｔｉｃｓＨｕａｎｇＱｉｎｇｇｕｏ；ＷａｎｇＬｉａｎｓｈｅｎｇ；Ｈａｎ...     

重金属对土壤—植物系统中氮的转化与NO3-淋失影响的研究

本项研究采用“微宇宙”方法,在实验室植物生长箱可控条件下,进行动态模拟实验。实验选择了七种重金属,按照土壤阳离子代换量计算出三种不同等级的土壤重金属剂量,研究它们对京津渤地区典型土壤(碳酸盐草甸土)中氮的转化与NO_3~-淋失影响。实验结果表明:七种重金属对该类土壤中氮的转化与NO_3~-淋失量有明显影响,但其表现的程度和特征有很大差异。其作用强度的次序为:Hg~(2 )>>Cd~(2 )>>Ni~(2 )>>Zn~(2 )>Pb~(2 )>Cu~(2 )>Cr~(3 )。各重金属作用的持续时间不同:Hg~(2 )、Cd~(2 )达7—11周以上,而其余重金属在4—7周。实验结论:本地区碳酸盐土壤虽然对重金属有较大的容量,但从土壤—植物系统污染生态学角度,仍可选择NO_3~-作为一项反映重金属对土壤生态毒性的早期诊断指标。     

长白山西坡风灾干扰区的恢复和保护

长白山西坡发生的灾害性风灾干扰,一方面给长白山自然保护区的森林资源造成巨大损失,同时也提出了如何加强保护和加速恢复的新课题。文中分析了风灾干扰区的更新格局和过程以及干扰后处理的有关问题,提出了从立地和景观水平促进更新恢复的保护措施     

旅游资源的环境保护对策

随着旅游和假日经济的日益升温，旅游资源的环境保护就显得更为迫切。本文基于旅游业的可持续发展要求，提出了有效保护旅游资源环境的几点对策     

水解酸化─厌氧─好氧─混凝─吸附工艺处理洁霉素生产丁提高浓度有机废水

采用水解酸化厌氧好氧混凝吸附工艺处理洁霉素生产丁提高浓度有机废水，工程实践表明，ＣＯＤＣｒ和ＢＯＤ５去除率在９９％以上，所排废水各项指标达到国家排放标准。     

绿色化学浅议

绿色化学是更高层次的化学，其产生是为了避免或减少化学过程对人类健康和环境造成的危害，由此出现的技术是环境友好的技术。绿色化学的发展能节省资源、减少环境污染，并将成为可持续发展战略的核心内容之一。     

Biogenic VOCs emission inventory development of temperate grassland vegetation in Xilin River basin, Inner Mongolia, China

Given the key role of biogenic volatile organic compounds(VOCs) to tropospheric chemistry and regional air quality, it is important to generate accurateVOCs emission inventories. However, only a less fraction of plant species, in temperate grassland of Inner Mongolia, has been characterized by quantitative measurements. A taxonomic methodology, which assigns VOCs measurements to unmeasured species, is an applicable and inexpensive alternation for extensive VOCs emission survey, although data are needed for additional plant families and genera to further validate the taxonomic approach in grassland vegetation. In this experiment, VOCs emission rates of 178 plant species were measured with a portable photoionization detector( PID). The results showed the most of genera and some families have consistent feature of their VOCs emission, especially for isoprene, and provide the basic premise of taxonomic methodology to develop VOCs emission inventories for temperate grassland. Then, the taxonomic methodology was introduced into assigning emission rate to other 96 species, which no measured emission rates available here. A systematical emission inventory of temperate grassland vegetation in Inner Mongolia was provided and further evidence that taxonomy relationship can serve as a useful guide for generalizing the emissions behavior of many, but not all, plant families and genera to grassland vegetation.     

土壤改良材料在非点源污染控制中的应用初探

研究表明,从源头上控制径流污染物是一种经济有效的方法.土壤改良材料不仅可以提高土壤的质地和入渗性能,而且可以减少径流中污染物的输出.文章从经济、环保和生态角度,分类论述了目前国内外几种常用的土壤改良材料,并对研究成果进行剖析,试图对土壤改良材料作为非点源污染源区促渗材料的应用前景进行探索,并为废弃物资源化利用提供一种新的思路.