TiO2/SiO2催化剂光催化降解罗丹明B的表观动力学

采用多孔硅胶为载体的TiO₂/SiO₂光催化剂,建立了三相内循环流化床光催化氧化体系,并以罗丹明B染料为典型污染物,研究其降解规律.通过对罗丹明B降解过程的表观动力学研究,发现在该体系中罗丹明B的降解并不符合Langmuir-Hinshelwood反应动力学模型.实验表明,其降解反应动力学符合双曲型模式,即降解率的倒数1/X和时间的倒数1/t成线性关系.反应速率常数与反应物初始浓度无关,与光源强度和相对体积能量吸收速率成正比.将不同实验条件下的罗丹明B的降解率实测值与模型计算值相比较,二者能很好吻合,平均相对偏差仅为3.25%.     

Nationwide monitoring of polychlorinated biphenyls and organochlorine pesticides in sediments from coastal environment of Korea

To assess the organochlorine contamination in the Korean marine environment, a nationwide monitoring study was conducted. A total of 138 surface sediments, covering the whole Korean coast, were collected and analyzed. Organochlorine compounds (OCs) were widely distributed in the Korean coastal environment, with PCB and DDT contamination being particularly prevalent. The overall concentrations of PCBs, DDTs, HCHs, CHLs, and HCB in surface sediments were in the range of 0.088-199ngg(-1) (median value: 1.56ngg(-1)), 0.006-135ngg(-1) (0.68ngg(-1)), not detected (ND)-5.46ngg(-1) (0.32ngg(-1)), ND-3.26ngg(-1) (0.14ngg(-1)), and ND-2.59ngg(-1) (0.05ngg(-1)), respectively. The southeastern coast was found to be highly contaminated. Overall contamination status of Korean coastal sediments with regard to OCs is lower than that of USA. With the exception of highly industrialized sites, Korean coastal areas in general showed similar OC concentrations to those of other Asian countries. There was a significant correlation between distributions of most organochlorine contaminants with each other. OC contamination is closely related to shipping and industrial activities. Of the 7 sites categorized as highly polluted, 4 are in a harbor zone. Adverse effects to benthic communities are expected at the levels of OC contamination observed from harbor and industrial areas.     

Emission factors of air toxics from semiconductor manufacturing in Korea

The development of local, accurate emission factors is very important for the estimation of reliable national emissions and air quality management. For that, this study is performed for pollutants released to the atmosphere with source-specific emission tests from the semiconductor manufacturing industry. The semiconductor manufacturing industry is one of the major sources of air toxics or hazardous air pollutants (HAPs); thus, understanding the emission characteristics of the emission source is a very important factor in the development of a control strategy. However, in Korea, there is a general lack of information available on air emissions from the semiconductor industry. The major emission sources of air toxics examined from the semiconductor manufacturing industry were wet chemical stations, coating applications, gaseous operations, photolithography, and miscellaneous devices in the wafer fabrication and semiconductor packaging processes. In this study, analyses of emission characteristics, and the estimations of emission data and factors for air toxics, such as acids, bases, heavy metals, and volatile organic compounds from the semiconductor manufacturing process have been performed. The concentration of hydrogen chloride from the packaging process was the highest among all of the processes. In addition, the emission factor of total volatile organic compounds (TVOCs) for the packaging process was higher than that of the wafer fabrication process. Emission factors estimated in this study were compared with those of Taiwan for evaluation, and they were found to be of similar level in the case of TVOCs and fluorine compounds.     

基于FLACS的LNG船舶泄漏爆炸过程数值模拟研究*

为研究大尺寸、全场景下LNG船舶卸货作业过程中的泄漏爆炸风险,构建某LNG接收站及其周边20.5 km2的区域场景模型,采用FLACS软件数值模拟LNG泄漏扩散、气云爆炸的演化过程。结果表明:LNG从卸料臂处以满输速率持续泄漏5 min,最大液池面积17 047 m2,最大汽化速率350 kg/m3,遇点火源发生气云爆炸,爆炸持续时间12 s,产生最高爆炸火球340 m和最大爆炸超压0.25 MPa,形成半径380 m轻伤区、150 m重伤区和60 m死亡区。     

长江上游泥石流灾害的特征

长江上游地区地质条件复杂、新构造运动强烈、地震活跃、地形起伏巨大、降水丰沛而集中,对泥石流发育极为有利;而长期不合理的人类经济活动(如过度采伐森林、毁林开荒、陡坡耕作、建设和采矿不合理弃渣等)则对生态环境造成强烈破坏,加剧了泥石流灾害的发生,使长江上游成为我国泥石流活动最强烈及灾害最严重的地区。据统计,1753~2002年的200多年中,区内仅一场泥石流致死百人以上的特大灾害点就达17个,累计死亡近6 000人;致死百人以下的灾害点更多,致死十人以下的灾害点不计其数,死亡人数总和远远大于上列数字;有60余个市县政府驻地城镇受泥石流危害或威胁,乡镇则多达上百个。由泥石流造成的人员伤亡每年数十到数百人,经济损失10~15(亿元／a)。其灾害的严重性由此可见一斑。泥石流灾害已成为制约长江上游地区经济发展的重要因素之一。研究泥石流灾害,掌握其特征,是长江上游防灾减灾所必需,对促进长江上游地区社会经济发展和西部大开发具有重要意义。长江上游己查明的泥石流沟6 800余条。其特殊的地理位置和巨大的地形高差及岩性差异,使区内发育的泥石流不仅数量众多,而且类型石相当齐全,除无火山泥石流外,几乎 包含了世界上目前己发现的其他各种类型的泥石流。在青藏高原边缘等岭谷高差变化大的地貌过渡带,泥石流极为发育;沿深大断裂带和强烈地震带泥石流集中分布;泥石流主要出现在流域面积小于10 km\+2的小流域内,分布呈非地带性特征。泥石流活动频率高,每年都有成百上千处发生,导致了泥石流灾害频繁。如云南东川的蒋家沟,从1965~2001年的37年中,共发生泥石流459次,平均12．4次／a;甘肃武都柳弯沟平均每年暴发泥石流11次。此外,泥石流搬运泥沙石块的能力惊人,搬运物以粗粒物质为主,据干流和支流的69个泥石流堆积物样品分析,堆积物中粒径大于20 mm 的石块占43.%~64.8%,平均50．4％;由此,常常造成其汇入的主河被堵塞而形成淹没和溃决后水毁等次生灾害。泥石流冲刷与淤积能力极强,运动中可将基岩下切10余m,金沙江、雅砻江、大渡河、岷江及其支流被泥石流堵塞成湖,形成淹没灾害,溃决后对下游造成严重的水毁灾害,均屡见不鲜。     

浅议保险对企业安全监督管理之作用

通过开展适合于保险和安全监管工作的风险评估体系的研究,充分发挥保险于安全监管的作用,从而为降低职工、企业乃至全社会的风险水平,为经济的可持续发展和社会稳定提供必要的保证。     

中心商业区环境安全管理与控制

城市中心商业区环境安全的管理与控制是城市诸多问题中的热点.通过分析中心商业区的环境空气质量和环境噪声、防火防爆设施及应急装备、人流车流秩序、公共卫生系统,提出了在城市中心商业区环境安全的管理与控制中应执行的相关标准,设立了相关部门和管理措施.对中心商业区环境安全控制的规制化具有一定积极意义.     

城市土壤污染研究现状与趋势

城市土壤是城市生态环境系统的有机组成部分,对城市的可持续发展有着重要的意义.城市化和工业化进程的加快,造成城市土壤污染、侵蚀、酸化和硬化以及土壤生物和植被退化等一系列较为严重的城市环境问题,直接危及到城市居民的健康和安全;因此,城市土壤污染问题已经引起人们的高度重视.近10多年来,国内外有关城市土壤重金属污染,微有机物污染,生源要素污染和城市土壤污染的环境与健康风险评价等诸多研究取得了一系列的研究成果.本文主要就以上研究成果进行了较为系统地总结与阐述,并且在此基础上提出了今后有关城市土壤污染研究的发展重点与趋势,以期为改善城市生态环境质量提供重要的科学依据.     

个人因素事故致因模型的探讨

从个人因素事故致因模型出发．探讨了潜在危险存在的情况下．个人因素与事故发生之间的联系;分析了不同的个人因素对于潜在危险的感知认识的作用和影响以及由此而决定的工作行为的安全程度;讨论了以控制导致事故发生的个人因素为出发点．用以预防事故发生的对策措施;提出在现代安全科学领域中,不仅要解决职工安全生产技术方面的问题．更要强调职工个人的社会性,在工作之中的成就感,被尊重的程度．这样才能达到充分激励职工、加强安全生产的目的。     

Research on 10-year tendency of China coal mine accidents and the characteristics of human factors

The trend of China coal mine accidents in the latest 10 years was studied and the human factors in these accidents were analyzed by multi-dimensional statistic analysis. It shows that the number of major coal mine accidents and the death toll in the accidents were decreasing steadily, while sporadic death accidents still accounted for the largest percentage of deaths. Gas outburst accidents, gas explosion accidents and mine water accidents remained the major part of the whole story and subject to close attention. Among the causes of these accidents, human factors accounted for 94.09%, of which intentional violation, mismanagement and defective design accounted for 35.43%, 55.12%, 3.54% respectively. Improper operational and management practices in which the safety system, procedures and specifications were neglected or broken were still key roots of China coal mine accidents.