The use of silver as a selective precipitant for I in radioactive waste management

¹²⁹I is one of the more hazardous nuclides occurring in radioactive waste. In the form of I⁻, its most likely speciation, it is poorly sorbed on most geologic media. Several workers have suggested the use of silver to precipitate I⁻ as the insoluble AgI, in a cemented waste form, or as a “getter”. The efficacy of this procedure is examined by experiment, in conjunction with thermodynamic predictions.The addition of AgNO₃ to Portland cement leads to coprecipitation with C-S-H, with low Ag solubilities ( 10 μmg/L); 2–;3 orders of magnitude lower than predicted (from Ag₂O). AgI is stable in these matrices, with low aqueous I concentrations (<2 mg/L). In 85% BFS-15% OPC pastes, AgI is unstable due to redox and complexation reactions, with much I⁻ passing into solution; concentrations up to 900 mg/L were observed. It is shown that repository conditions, on closure, are also likely to induce solubilisation of I⁻ from AgI. It is concluded that the use of Ag is unlikely to significantly improve the immobilisation properties of the near field for radioiodine.     

Proactive environmental management is the key to full compliance

There are two key elements to achieving full and complete regulatory compliance: cost-efficient management of current regulatory requirements under existing environmental law and the capability to anticipate and analyze the impact of future regulations on the facility. The author provides step-by-step advice on how to develop a program to accomplish a corporate goal of zero violations.     

Productive utilization of pig farm wastes: a case study for developing countries

This paper presents a case study on pig farm waste management in which pig manure is stabilized in two-stage anaerobic reactors (to produce methane), while pig farm wastewater is treated in water hyacinth ponds from which the harvested water hyacinth plants are used in the production of silage (animal feed) or compost fertilizer. The results suggest the technical feasibility of applying these technologies to treat and recycle pig farm wastes. Cost/benefit analysis reveals the option to produce methane gas and silage to be financially viable after 15 years of operation. A management concept of waste recycling programs is presented, including relationships among objectives, constraints and implementation plan. Decision on a waste recycling program should not be based only on cost/benefit analysis, but also on the pollution control and public health improvement to be gained.     

VARIABILITY IN MEASURED BEDLO AD-TRANSPORT RATES1

ABSTRACT: Variability in bedload-transport rates during constant water discharge is an inherent part of the bedload-transport process. Although this variability has been measured extensively in the laboratory, similar information generally is not available from field measurements. During a four-day period of nearly constant water discharge, four sets of consecutively collected bedload samples, ranging from 43 to 120 samples, were obtained at the same cross channel location using a standard 65-pound Helley-Smith bedload sampler. When the measured transport rates are converted to dimensionless rates and plotted as cumulative frequency distributions, they show good agreement with a theoretical probability distribution function of rates derived for the case of ripples on dunes. The distributions show that during constant water discharge individual measured rates at a fixed point vary from near zero to four times the mean rate, and 60 percent of the sampled rates will be less than the mean. Because of the large variation in transport rates that occurs at every location in the cross section, many observations are required to establish an accurate estimate of the mean rate at any given location.     

An approach for analysing the potential for material efficiency improvement

Material efficiency improvement saves energy and reduces the consumption of primary resources and reduces the volume of waste. In this article an approach for analysing the potential for material efficiency improvement is proposed and discussed. In this approach the product functions performed by the materials and various improvement measures are taken into account. The potential for material saving and associated energy saving is assessed and evaluated economically. In this paper the approach is tested in an analysis of the potential for material efficiency improvement with respect to plastic packaging in the Netherlands. The technical reduction potential is found to be 34 ± 7% (157 ± 30 ktonne virgin plastics). Realization of this potential would improve the energy efficiency of the lifecycle of plastic packaging by 31% (10 PJ in 1988). From our study we conclude that our approach can indeed be used to investigate the potential for material efficiency improvement. However, a reliable technical and particularly an economical assessment of reduction measures cannot be made until more detailed data become available.     

A FIELD TECHNIQUE FOR WEIGHING BEDLOAD SAMPLES1

ABSTRACT: A technique for weighing bedload samples that was developed for laboratory use has been modified for field application. The technique involves determining the submerged weight of bedload samples as they are collected. The submerged weights are converted to dry weights from a knowledge of the specific gravity of the bedload material. The technique makes bedload transport data available immediately and eliminates costly and time-consuming steps involved with saving samples for laboratory analysis. Only samples designated for particle-size or other lab analyses need to be saved.     

Insect habitat management in pasture systems

Two important habitat management strategies in pasture systems involve controlled burning and effective grazing manipulation schemes to maintain native climax grassland vegetation These climax grasslands have historically suffered less insect pest pressure than imported systems However, these types of grasslands are difficult to reestablish after relatively severe disruption by man Also, the proper diversity and stability is difficult to capture in developing imported systems. Imported pastures can exhibit substantial yields per land unit but are often composed of vegetation that rapidly mines nutrients stored by the native vegetation, and often need considerable inputs of fossil fuel, manufactured fertilizers and pesticides, because they are or become very susceptible to pestiferous insects. Habitat manipulation efforts can be effective in regulating forage pest populations below economic levels in imported pasture systems Such efforts include: 1) land use (coupled with plant diversity, grazing, and harvest manipulations), 2) sanitation (including controlled burning), 3) planting dates and harvest times (including grazing manipulations), 4) tillage methods, 5) fertilization, 6) trap crops, 7) water management, and 8) fire management for insect pest suppression and augmentation of natural enemies.     

From the Editors

Editorial Introduction

From the Editors