Groundwater flow, multicomponent transport and biogeochemistry: development and application of a coupled process model

A research tool for modeling the reactive flow and transport of groundwater contaminants in multiple dimensions is presented. Arbitrarily complex coupled kinetic–equilibrium heterogeneous reaction networks, automatic code generation, transfer-function based solutions, parameter estimation, high-resolution methods for advection, and robust solvers for the mixed kinetic–equilibrium chemistry are some of the features of reactive flow and transport (RAFT) that make it a versatile research tool in the modeling of a wide variety of laboratory and field experiments. The treatment of reactions is quite general so that RAFT can be used to model biological, adsorption/desorption, complexation, and mineral dissolution/precipitation reactions among others. The integrated framework involving automated code generation and parameter estimation allows for the development, characterization, and evaluation of mechanistic process models. The model is described and used to solve a problem in competitive adsorption that illustrates some of these features. The model is also used to study the development of an in situ Fe(II)-zone by encouraging the growth of an iron-reducing bacterium with lactate as the electron donor. Such redox barriers are effective in sequestering groundwater contaminants such as chromate and TCE.     

Participative governance and integrated coastal management. An experiment of dialogue in an insular community at isle-aux-coudres (Quebec, Canada)

This paper is about an Integrated Coastal Management Project on an island, Isle-aux-Coudres, located in the St-Lawrence Estuary (Québec, Canada). It is based on data collected from 2003 to 2007 on the participatory aspects of the project such as: types of stakeholders, relationships between stakeholders, time dedicated to dialogue, consensus versus negotiation, and outcomes. We analyze the way concerns evolved into actions and the relationship between dialogue and actions during the project. We conclude that the difficulty is to join together the differences around various stakes, without forcing the consensus, or negating problems and conflicts.     

Low-level sedimentation modifies behaviour in juvenile Haliotis iris and may affect their vulnerability to predation

Sedimentation is an important stressor of coastal ecosystems; yet, there is little research into specific mechanisms by which populations are affected by additional sediment loads resulting from anthropogenic-driven processes. This study explored the potential impact of the proposed disposal of over 7 million m³ of dredge spoil on a nearby fishery for the blackfoot abalone Haliotis iris. The range of sediment deposition predicted by models to occur on reefs inhabited by H. iris as a result of the dispersal of sediment from the disposal site was used to design controlled experiments between July and September 2011 to test the likely effects of sedimentation on: (a) behaviour and mortality of juvenile H. iris and (b) photosynthetic vitality of crustose coralline algae (CCA) that form nursery habitats for H. iris obtained from Brinns Point (45, 40.3′S, 170, 39.4′E). We observed no direct effects on the health or mortality of H. iris juveniles or the photosynthetic vitality of habitat forming CCA. H. iris did, however, avoid sediments by moving from predation refugia beneath cobbles to vertical surfaces on cobble edges significantly more often in sediment treatments compared to sediment-free controls. Deposited sediments were also found to inhibit righting response, key behaviour in allowing H. iris to reattach to the substratum following dislodgement. Results of this study suggest that indirect mortality from reductions in available refugia from predation and inability to recover from dislodgement could be significant. These results highlight the importance of understanding indirect impacts of stressors on key ecological processes in order to predict ecological responses.     

Method for reporting in-use vehicle fuel consumption and carbon dioxide emissions from a fast-pass transient inspection

A method has been developed that allows reporting of the fuel consumption and carbon dioxide (CO2) emissions for in-use vehicles from a fast-pass transient (IM240) inspection. The major technical obstacle to reporting CO2 emission rate and fuel consumption is that inspection and maintenance tests do not all use a standardized test duration or test method. The method is able to project full-duration fuel consumption from IM240 tests that actually fast-passed as early as just 30 sec from starting the test. It is based on basic considerations of the work done in driving the inspection cycle, with additional empirical adjustments. The initial application examined the differences between passing and failing inspections, and this did confirm that there are significant differences.     

Effects of oxide coating and selected cations on nitrate reduction by iron metal

Under anoxic conditions, zerovalent iron (Fe(0)) reduces nitrate to ammonium and magnetite (Fe3O4) is produced at near-neutral pH. Nitrate removal was most rapid at low pH (2-4); however, the formation of a black oxide film at pH 5 to 8 temporarily halted or slowed the reaction unless the system was augmented with Fe(2+), Cu(2+), or Al(3+). Bathing the corroding Fe(0) in a Fe(2+) solution greatly enhanced nitrate reduction at near-neutral pH and coincided with the formation of a black precipitate. X-ray diffractometry and scanning electron microscopy confirmed that both the black precipitate and black oxide coating on the iron surface were magnetite. In this system, ferrous iron was determined to be a partial contributor to nitrate removal, but nitrate reduction was not observed in the absence of Fe(0). Nitrate removal was also enhanced by augmenting the Fe(0)-H2O system with Fe(3+), Cu(2+), or Al(3+) but not Ca(2+), Mg(2+), or Zn(2+). Our research indicates that a magnetite coating is not a hindrance to nitrate reduction by Fe(0), provided sufficient aqueous Fe(2+) is present in the system.     

An evaluation of grid rod failure in a mobile bed scrubber

The body of information presented in this paper is directed to those engineers and maintenance personnel involved in the operation of mobile-bed scrubbers. Materials tests were performed on three specimens of austenitic stainless steel to determine the possible causes of grid rod failure in a mobile-bed scrubber controlling particulate emissions from a pulverized-coal-fired, steam-electric generating station. These three specimens were successively placed in an Instrom universal testing machine and loaded in tension until rupture occurred. The results of these tests, in addition to other supporting data, were used in an attempt to determine the cause of the grid rod failure during scrubber operation. It was determined that the grade of stainless steel used, the scrubber water quality, and certain operational problems could be causes of premature failure.     

An economic modelling approach to the design and delivery of sustainable waste minimisation clubs: Prospects in the new policy framework

Since the early 1990s, waste minimisation clubs have been important sources of information for industry in the UK on clean technology and sustainable waste management practice. Despite this contribution, concern has grown about the declining number of clubs, their performance and the likelihood that they will continue to play a key role in national policy.This paper examines the evidence available and provides estimates of how the numbers varied in England since the first clubs were formed. The results presented indicate that, after initial expansion, numbers went into decline. The paper then explores, using economic theory, why this pattern should have developed and suggests it to be a function of how clubs were designed and managed. The results of the analysis are used to propose alterations in how future clubs could be designed so that they continue to contribute effectively to the development of sustainable waste management in UK industry. These lessons are of value to policy in both the UK and other countries considering the development of this important tool of waste strategy. The paper concludes with a number of suggestions for future research.     

THERMAL DISCHARGES AND PUBLIC POLICY DEVELOPMENT1

ABSTRACT The generation of electric energy in steam-electric power plants is accompanied by the discharge of large quantities of waste heat into the environment. In most cases, this heat is released into natural bodies of water at temperatures relatively close to ambient. In certain locations, such as the Chesapeake Bay, discharges of waste heat may triple in the next decade. It is expected that past practices of thermal discharge, if continued into the future, will result in significant damages to other legitimate users of the water resource, both present and future. This paper reviews the economic causes of these potential damages, and describes the role of public policy as one of removing such causes through regulation incentive or intervention. Possible public policies are reviewed, including prohibition, standards, various types of dollar incentives such as taxes and subsidies, marketable effluent permits, and direct government investment. The innovative power plant siting program recently adopted in Maryland is also discussed. It is concluded that no statements can be made regarding the comparative efficiency or effectiveness of the various policies at the present state of knowledge. It is recommended that policy-makers adopt mixed strategies, preserving as many options as possible for dealing with similar problems in the future.