Investigation of volatile methyl siloxanes in biogas and the ambient environment in a landfill

Landfill biogas is a potential alternative for fossil fuel,but the containing impurities,volatile methyl siloxanes(simplified as siloxanes),often cause serious problems in gas turbines when applied to generate electricity.In this research,a collecting and analyzing method based on solvent adsorption and purge and trap-gas chromatography-mass spectrometry was established to determine the siloxanes in biogas from a landfill in Jinan,China,and adjacent ambient samples,such as soil,air,and leachate of the landfill.The results showed that,octamethylcyclotetrasiloxane(D4) and decamethylcyclopentasiloxane(D5) accounted for 63% of total siloxanes;and without considering D4 and D5,the order of detected siloxanes in concentration was found relating to Gibbs free energies of molecules,namely that higher abundant siloxane(except for D4 and D5) usually had lower Gibbs free energy.Additionally,the mass ratio between D4 and octamethyltrisiloxane(L3) in the bio gas varied with different garbage age in landfills,possibly revealing the breaking-down of larger siloxane molecules with time.The samples,which were collected from environmental samples adjacent to the landfill,such as soil,water,and air,presented much higher siloxane level than urban or rural area away from landfills.The current H2 S scrubber of the landfill biogas could decrease the total siloxanes from 10.7 to 5.75 mg/m~3 due to Fe2 O3 and a refrigerant drier in a purification system and cyclic siloxanes were more easily removed than linear ones.     

欧盟废荧光灯管回收管理经验及对中国的启示

中国在废荧光灯管回收管理方面尚未建立有效的法规制度体系,导致废荧光灯管大部分混入生活垃圾进行了填埋或焚烧处置。欧盟在废荧光灯管回收管理方面建立了较为完善的收集体系和资金机制,取得了较好的效果。中国应借鉴欧盟经验,尽快建立健全社会源废荧光灯管生产者责任延伸制度,加快建设社会源尤其是家庭源废荧光灯管的多元化收集体系,积极探索实行由行业协会等第三方机构主导的资金机制运行方式,并坚持开展长期宣传教育活动。     

合成氨装置系统安全仪表系统安全完整性等级分析

论文在介绍安全仪表系统、安全完整性等级的基本原理基础上,综合分析了危险与可操作性分析(HAZOP)、保护层分析(LOPA)等系统风险分析理论的应用方法。并结合上述理论,确定了安全仪表系统的安全完整性等级(SIL)定级。以合成氨装置为例,应用HAZOP及保护层分析方法,得出了合成塔压力过高及废热锅炉液位过低2个场景下的安全完整性SIL等级。结果表明:合成塔装置仪表的SIL等级为1,废热锅炉仪表的SIL等级为2。     

Ventilation mode changes our safety in buses: Study on “air-rain” flow against chemical and arson attack in public transport vehicles

Objectives: Public transport vehicles (PTVs) play a decisive role in development of the urban economy. However, the safety of PTVs is threatened by the man-released chemical or arson attack. It was found that indoor air safety can be greatly improved by employing air-rain ventilation instead of the common ventilation in a PTV.

Methods: Numerical simulations and experiments have been done to prove the effectiveness of the air-rain flow against chemical attack or arson in PTVs.

Results: The research shows that, during a chemical attack, an air-rain flow of 0.1 m/s can constrain the spread of a chemical agent in a very limited zone near its source, which is far away from the passengers’ breathing area in the PTV. During an arson attack, at an air-rain flow of 0.3 m/s, most of the area in the PTV maintains a low temperature for at least 60?s during a fire, which is long enough for passenger evacuation.

Conclusion: Compared to common ventilation, the key characteristic of air-rain ventilation is its resistance to the blending effect of the air. Because of this, the spread of chemical agents, hot gas/combustion products during a fire, and fuel aerosol is constrained to a limited area in a PTV. Passengers are then protected from chemical attack, explosion of fuel aerosols, and high temperatures and smoke. Thus, we can say that this new ventilation mode increases passenger safety in buses.     

不同类型清水剂处理油田含聚污水的效果对比

考察了阳离子型CWC-14、非离子型NQS-01和阴离子型AQS-08 3类清水剂对油田含聚污水的处理效果,对比了它们的作用特点和絮体性能。实验结果表明:在清水剂加入量350 mg/L、处理温度65℃、搅拌转速300 r/min、搅拌时间5 min的条件下,CWC-14、NQS-01和AQS-08对含聚污水的除油率分别为98.8%、98.0%和99.4%;NQS-01受处理温度、搅拌条件影响较大;CWC-14受污水中聚合物质量浓度影响最大。清水剂的絮体特点与其作用机理有关,CWC-14的絮凝速率最快,起效时间最短,絮体呈黏性大块状;NQS-01的絮凝速率最慢,起效时间最长,絮体呈浮油状;AQS-08的絮凝速率和起效时间适中,絮体呈松散状、流动性好。对比结果表明,非阳离子型清水剂可有效避免油田含聚污水处理过程中的黏性油泥问题。     

Plot-scale spatiotemporal variations of CO2 concentration and flux across water–air interfaces at aquaculture shrimp ponds in a subtropical estuary

Human activities have increased anthropogenic CO₂ emissions, which are believed to play important roles in global warming. The spatiotemporal variations of CO₂ concentration and flux at fine spatial scales in aquaculture ponds remain unclear, particularly in China, the country with the largest aquaculture. In this study, the plot-scale spatiotemporal variations of water CO₂ concentration and flux, both within and among ponds, were researched in shrimp ponds in Shanyutan Wetland, Min River Estuary, Southeast China. The average water CO₂ concentration and flux across the water–air interface in the shrimp ponds over the shrimp farming period varied from 22.79?±?0.54 to 186.66?±?8.71 μmol L^?1 and from ??0.50?±?0.04 to 2.87?±?0.78 mol m^?2 day^?1, respectively. There was no remarkable difference in CO₂ concentration and flux within the ponds, but significantly spatiotemporal differences in CO₂ flux were observed between shrimp ponds. Chlorophyll a, pH, salinity, air temperature, and morphometry were the important factors driving the spatiotemporal patterns of CO₂ flux in the shrimp ponds. Our findings highlighted the importance and spatiotemporal variations of CO₂ flux in the important coastal ecosystems.

     

Similarities and differences of metal distributions in the tissues of molluscs by using multivariate analyses

Multivariate analysis including correlation, multiple stepwise linear regression, and cluster analyses were applied to investigate the heavy metal concentrations (Cd, Cu, Fe, Ni, Pb, and Zn) in the different parts of bivalves and gastropods. It was also aimed to distinguish statistically the differences between the marine bivalves and the gastropods with regards to the accumulation of heavy metals in the different tissues. The different parts of four species of bivalves and four species of gastropods were obtained and analyzed for heavy metals. The multivariate analyses were then applied on the data. From the multivariate analyses conducted, there were correlations found between the soft tissues of bivalves and gastropods, but none was found between the shells and the soft tissues of most of the molluscs (except for Cerithidea obtusa and Puglina cochlidium). The significant correlations (P < 0.05) found between the soft tissues were further complemented by the multiple stepwise linear regressions where heavy metals in the total soft tissues were influenced by the accumulation in the different types of soft tissues. The present study found that the distributions of heavy metals in the different parts of molluscs were related to their feeding habits and living habitats. The statistical approaches proposed in this study are recommended for use in biomonitoring studies, since multivariate analyses can reduce the cost and time involved in identifying an effective tissue to monitor the heavy metal(s) bioavailability and contamination in tropical coastal waters.     

洪水作用下汽车的起动流速研究

针对洪水作用下汽车的起动条件开展了一系列的研究:首先分析部分淹没状态下汽车的受力情况,结合滑动平衡的临界起动条件建立相关方程,导出了洪水中汽车起动流速公式;然后在室内水槽中对三款模型车进行了一系列的起动试验。试验结果表明:对于同一款模型车,平行于水流方向放置时,起动流速与水深的相关性较好;并且水深越大,起动流速越小。接着运用试验资料率定了起动流速公式中的相关参数。最后采用模型相似率及率定后的计算公式估算了原型车辆在不同水深下的起动流速,两种方法所得的结果较为接近,故预测结果较为可靠。     

论可持续发展的物质体系

可持续发展的物质体系包括资源、环境和生态。可持续发展的终极基础是资源物质变换，可持续发展的生存依托是环境，可持续发展的动态载体是生态平衡网络。本文通过分析资源、环境和生态之间的关系与相互作用，提出了可持续发展的基础是物质体系的观点。