全文获取类型
收费全文 | 18936篇 |
免费 | 970篇 |
国内免费 | 6662篇 |
专业分类
安全科学 | 1466篇 |
废物处理 | 1174篇 |
环保管理 | 1466篇 |
综合类 | 10756篇 |
基础理论 | 3045篇 |
环境理论 | 8篇 |
污染及防治 | 6273篇 |
评价与监测 | 802篇 |
社会与环境 | 715篇 |
灾害及防治 | 863篇 |
出版年
2024年 | 28篇 |
2023年 | 315篇 |
2022年 | 907篇 |
2021年 | 830篇 |
2020年 | 692篇 |
2019年 | 621篇 |
2018年 | 759篇 |
2017年 | 918篇 |
2016年 | 863篇 |
2015年 | 1073篇 |
2014年 | 1470篇 |
2013年 | 1938篇 |
2012年 | 1612篇 |
2011年 | 1752篇 |
2010年 | 1290篇 |
2009年 | 1258篇 |
2008年 | 1342篇 |
2007年 | 1114篇 |
2006年 | 988篇 |
2005年 | 704篇 |
2004年 | 536篇 |
2003年 | 641篇 |
2002年 | 551篇 |
2001年 | 464篇 |
2000年 | 505篇 |
1999年 | 570篇 |
1998年 | 488篇 |
1997年 | 460篇 |
1996年 | 427篇 |
1995年 | 344篇 |
1994年 | 275篇 |
1993年 | 223篇 |
1992年 | 157篇 |
1991年 | 128篇 |
1990年 | 80篇 |
1989年 | 70篇 |
1988年 | 53篇 |
1987年 | 25篇 |
1986年 | 26篇 |
1985年 | 12篇 |
1984年 | 17篇 |
1983年 | 15篇 |
1982年 | 13篇 |
1981年 | 8篇 |
1980年 | 1篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
961.
Potential particulate pollution derived from UV-induced degradation of
odorous dimethyl sulfide 总被引:1,自引:0,他引:1
UV-induced degradation of odorous dimethyl sulfide (DMS) was carried out in a static White cell chamber with UV irradiation. The
combination of in situ Fourier transform infrared (FT-IR) spectrometer, gas chromatograph-mass spectrometer (GC-MS), wide-range
particle spectrometer (WPS) technique, filter sampling and ion chromatographic (IC) analysis was used to monitor the gaseous and
potential particulate products. During 240 min of UV irradiation, the degradation e ciency of DMS attained 20.9%, and partially
oxidized sulfur-containing gaseous products, such as sulfur dioxide (SO2), carbonyl sulfide (OCS), dimethyl sulfoxide (DMSO),
dimethyl sulfone (DMSO2) and dimethyl disulfide (DMDS) were identified by in situ FT-IR and GC-MS analysis, respectively.
Accompanying with the oxidation of DMS, suspended particles were directly detected to be formed by WPS techniques. These
particles were measured mainly in the size range of accumulation mode, and increased their count median diameter throughout
the whole removal process. IC analysis of the filter samples revealed that methanesulfonic acid (MSA), sulfuric acid (H2SO4) and
other unidentified chemicals accounted for the major non-refractory compositions of these particles. Based on products analysis and
possible intermediates formed, the degradation pathways of DMS were proposed as the combination of the O(1D)- and the OH- initiated
oxidation mechanisms. A plausible formation mechanism of the suspended particles was also analyzed. It is concluded that UV-induced
degradation of odorous DMS is potentially a source of particulate pollutants in the atmosphere. 相似文献
962.
The competition between submersed plants has been recognized as an important factor influencing the structure of plant communities
in shallow lakes. The ability of different species to take up and store nutrients from the surrounding ambience varies, and hence plant
community structure might be expected to affect the cycling of nutrients in lake ecosystems. In this study, the uptake of phosphorus
by Hydrilla verticillata and Vallisneria natans was studied and compared in monoculture and competitive mixed-culture plantings.
Results showed that for both studied species the phosphorus concentrations of different tissues and of whole plants was unaffected by
competition. However, the quantity of phosphorus accumulated by whole plants of H. verticillata was significantly higher in mixture
culture than in monoculture, while that of V. natans was lower in the mixed culture. The results indicated that H. verticillata has a
competitive advantage over V. natans, when the two species are grown in competition, and is able to accumulate a greater quantity of
phosphorus. 相似文献
963.
The aim of the present work was to produce a polyaluminium ferric silicate chloride (PAFSiC) coagulant from acidic and alkaline
wastewater of purifying graphite by roasting, and subsequently to evaluate coagulation efficiency of the reagent by treating surface
water from the Yellow River as well as municipal wastewater in comparison with the conventional coagulant polyaluminium chloride
(PAC). The PAFSiC coagulant was prepared by co-polymerization. The effects of (Al+Fe)/Si molar ratio, OH/(Al+Fe) molar ratio (i.e.,
value), coagulant dosage and pH value of test suspension on the coagulation behavior of FAFSiC and the stability of the PAFSiC were
also examined. Results showed that PAFSiC performed more efficiently than PAC in removing turbidity, chemical oxygen demand
(COD), and total phosphate (TP). The PAFSiC with a
value of 2.0 and (Al+Fe)/Si ratio of 5 (PAFSiC 2.0/5) showed excellent
coagulation effect for both turbidity and COD, while PAFSiC 1.0/5 was the best for TP. The optimum coagulation pH range of PAFSiC
2.0/5 was 5.0–9.0, slightly wider than that of PAC (6.0–8.0). The process can be easily incorporated into high-purity graphite production
plants, thereby reducing wastewater pollution and producing a valuable coagulant. 相似文献
964.
Cleaning of hollow-fibre polyvinyl chloride (PVC) membrane with di erent chemical reagents after ultrafiltration of algal-rich
water was investigated. Among the tested cleaning reagents (NaOH, HCl, EDTA, and NaClO), 100 mg/L NaClO exhibited the best
performance (88.4% 1.1%) in removing the irreversible fouling resistance. This might be attributed to the fact that NaClO could
eliminate almost all the major foulants such as carbohydrate-like and protein-like materials on the membrane surface, as confirmed by
Fourier transform infrared spectroscopy analysis. However, negligible irreversible resistance (1.5% 1.0%) was obtained when the
membrane was cleaning by 500 mg/L NaOH for 1.0 hr, although the NaOH solution could also desorb a portion of the major foulants
from the fouled PVC membrane. Scanning electronic microscopy and atomic force microscopy analyses demonstrated that 500 mg/L
NaOH could change the structure of the residual foulants on the membrane, making them more tightly attached to the membrane
surface. This phenomenon might be responsible for the negligible membrane permeability restoration after NaOH cleaning. On the
other hand, the microscopic analyses reflected that NaClO could e ectively remove the foulants accumulated on the membrane surface. 相似文献
965.
Tao Zhang Qiucheng Li Lili Ding Hongqiang Ren Ke Xu Yonggang Wu Dong Sheng 《环境科学学报(英文版)》2011,23(6):881-890
Chemical precipitation to form magnesium ammonium phosphate (MAP) is an effective technology for recovering ammonium
nitrogen (NH4
+-N). In the present research, we investigated the thermodynamic modeling of the PHREEQC program for NH4
+-N
recovery to evaluate the effect of reaction factors on MAP precipitation. The case study of NH4
+-N recovery from coking wastewater
was conducted to provide a comparison. Response surface methodology (RSM) was applied to assist in understanding the relative
significance of reaction factors and the interactive effects of solution conditions. Thermodynamic modeling indicated that the saturation
index (SI) of MAP followed a polynomial function of pH. The SI of MAP increased logarithmically with the Mg2+/NH4
+ molar ratio
(Mg/N) and the initial NH4
+-N concentration (CN), respectively, while it decreased with an increase in Ca2+/NH4
+ and CO3
2??/NH4
+
molar ratios (Ca/N and CO3
2??/N), respectively. The trends for NH4
+-N removal at different pH and Mg/N levels were similar to the
thermodynamic modeling predictions. The RSM analysis indicated that the factors including pH, Mg/N, CN, Ca/N, (Mg/N) (CO3
2??/N),
(pH)2, (Mg/N)2, and (CN)2 were significant. Response surface plots were useful for understanding the interaction effects on NH4
+-N
recovery. 相似文献
966.
Sedimentary record of polycyclic aromatic hydrocarbons in Lake Erhai,
Southwest China 总被引:1,自引:0,他引:1
Jianyang Guo Zhang Liang Haiqing Liao Zhi Tang Xiaoli Zhao Fengchang Wu 《环境科学学报(英文版)》2011,23(8):1308-1315
The temporal distribution of polycyclic aromatic hydrocarbons (PAHs) was investigated in a sediment core from Lake Erhal in Southwest China using gas-chromatography/mass spectrometry (GC/MS) method.The total organic carbon (TOC) normalized total PAHs concentrations (sum of US Environmental Protection Agency proposed 16 priority PAHs) ranged from 31.9 to 269 μg/g dry weight (dw),and were characterized by a slowly increasing stage in the deeper sediments and a sharp increasing stage in the upper sediments.The PAHs in the sediments were dominated by low molecular weight (LMW) PAHs,suggesting that the primary source of PAHs was low- and moderate temperature combustion processes.However,both the significant increase in high molecular weight (HMW) PAHs in the upper sediments and the vertical profile of diagnostic ratios pointed out a change in the sources of PAHs from low-temperature combustion to high-temperature combustion.The ecotoxicological assessment based on consensus-based sediment quality guidelines implied that potential adverse biological impacts were possible for benzo(ghi)perylenelene and most LMW PAHs.In addition,the total BaP equivalent quotient of seven carcinogenic polycyclic aromatic hydrocarbons (BaA,CHr,BbF,BkF,BaP,DBA and INP) was 106.1 ng/g,according to the toxic equivalency factors.Although there was no great biological impact associated with the HMW PAlls,great attention should be paid to these PAH components based on their rapid increase in the upper sediments. 相似文献
967.
Visible light responsive N-F-codoped TiO2 photocatalysts exhibit a higher catalytic activity than N-doped TiO2 for the degradation of 4-chlorophenol due to the synergistic effect of nonmetal elements. 相似文献
968.
The activities of CeO2 nanocubes calcined at different temperatures were tested for catalytic oxidation of o-xylene. Using CeO2 nanocubes as catalysts, complete catalytic oxidation of o-xylene was achieved below 210℃. The CeO2 nanomaterials were characterized by means of BET, X-ray diffraction (XRD), transmission electron microscopy (TEM), and high-resolution transmission electron microscopy (HRTEM). From the TEM images, all Ce02 nanocubes displayed cubic morphology irrespective of calcination temperature. The HRTEM images revealed that these nanocubes were enclosed by reactive {001}planes, which may contribute to the intrinsically catalytic property of o-xylene oxidation. The higher activity of Ce02 nanocubes calcined at 550℃ than those calcined at above 550℃ was attributed to their smaller crystallite size and larger surface area. The influences of reaction conditions were also studied, which found that a higher reaction temperature was necessary for complete catalytic oxidation of o-xylene at higher weight hourly space velocity (WHSV) and o-xylene concentration. 相似文献
969.
970.
Preliminary report on methane emissions from the Three Gorges Reservoir in the summer drainage period 总被引:3,自引:0,他引:3
Fei Lu Le Yang Xiaoke Wang Xiaonan Duan Yujing Mu Wenzhi Song Feixiang Zheng Junfeng Niu Lei Tong Hua Zheng Yongjuan Zhou Jiangxiao Qiu Zhiyun Ouyang 《环境科学学报(英文版)》2011,23(12):2029-2033
Considerable variations may exist in CH4 emissions from the Three Gorges Reservoir. 相似文献