基于MCR模型的大别山核心区生态安全格局异质性及优化

以大别山核心区精准扶贫对象岳西县为研究单元,选择10个生态阻力因子建立生态安全评价指标体系,利用ArcGIS构建生态阻力面,应用空间数据探索分析方法（Exploratory Spatial Data Analysis,ESDA）、最小累积阻力模型（Minimum Cumulative Resistance,MCR）和重力模型对生态安全进行诊断和潜在生态廊道识别提取。研究表明：（1）岳西县生态安全较高及高等级区域占县域总面积37.79%,而较低及低等级区域占51.89%,整体呈现北低南高的空间特征,生态安全水平总体偏低。（2）ESDA分析显示,生态安全空间分布全局Moran's I指数为0.6374,LISA图显示岳西县生态安全等级主要以高高（HH）、低低（LL）两种聚集类型为主,在空间上呈明显的片状集聚分布特征。在此基础上,选择生境良好的自然保护区及大型风景区斑块为生态源,生成累积耗费阻力面,基于MCR最小累积阻力模型构建生态源之间的最小累积耗费路径,提取潜在生态廊道90条,生态节点103个,利用重力模型识别出21条重要潜在生态廊道,其中,一级和二级潜在生态廊道分别为13条和8条。（3）结合岳西县旅游产业空间发展规划,提出了“一环三带”生态网络框架空间布局模式及优化对策,该模式可作为岳西县生态经济产业发展格局的有效补充。     

安徽某硫铁尾矿区农田土壤重金属污染特征

对安徽省某硫铁矿尾矿区农田土壤、农作物进行重金属污染分析和风险评价,为硫矿区农田重金属污染风险管理与土地利用提供理论依据。布设30个采样点采集土壤及其毛豆样品,ICP-MS法测定Cu、Zn、As、Cd、Pb重金属全量,运用单因子指数、综合污染指数、潜在生态风险指数法和生物富集系数法对重金属污染程度进行评价。结果表明,研究区土壤p H值在3. 37～4. 60,均值为4. 03,土壤呈强酸性、酸性。比对安徽省土壤重金属背景值,研究区土壤已明显遭受外源重金属污染;比对GB 15618—2018《土壤环境质量农用地土壤污染风险管控标准》风险筛选值,受到Cd、Cu重金属污染,其中60%采样点Cu超标,76. 67%采样点Cd超标,但都远低于标准风险管制值;单因子污染指数评价结果显示该研究区农田以Cu、Cd污染为主;内梅罗综合污染指数评价结果表明研究区农田土壤总体已遭受重金属污染;潜在生态危害指数评价结果显示研究区土壤总体为轻微综合潜在生态危害,Cd在67%以上检测点为中等风险水平、10%为强风险水平。研究区农田农作物毛豆籽粒中Pb、Cd、As质量比均值未超过GB 2762—2017《食品安全国家标准食品中污染物限量》规定的限量值,其对重金属的富集系数(EF)从大到小依次为Cd、Zn、Cu、As、Pb。     

Graphitic carbon nitride-based photocatalysts in the applications of environmental catalysis

Semiconductor photocatalytic technology has shown great prospects in converting solar energy into chemical energy to mitigate energy crisis and solve environmental pollution problems. The key issue is the development of high-efficiency photocatalysts. Various strategies in the state-of-the-art advancements, such as heterostructure construction, heteroatom doping, metal/single atom loading, and defect engineering, have been presented for the graphitic carbon nitride (g-C₃N₄)-based nanocomposite catalysts to design their surface chemical environments and internal electronic structures to make them more suitable for different photocatalytic applications. In this review, nanoarchitecture design, synthesis methods, photochemical properties, potential photocatalytic applications, and related reaction mechanisms of the modified high-efficiency carbon nitride-based photocatalysts were briefly summarized. The superior photocatalytic performance was identified to be associated with the enhanced visible-light response, fast photoinduced electron-hole separation, efficient charge migration, and increased unsaturated active sites. Moreover, the further advance of the visible-light harvesting and solar-to-energy conversions are proposed.     

强化生物除磷过程中污泥胞内糖原的红外光谱分析

采用傅里叶中红外光谱对强化生物除磷过程中污泥胞内糖原物质进行了表征,并将污泥样品与糖原标样的红外光谱进行对比,确认糖原物质在1020 cm-1峰附近有较明显的特征吸收贡献.因此,采用红外光谱945~1150 cm-1区域内的吸收光谱数据,结合测得胞内糖原的含量,应用偏最小二乘法和BP神经网络算法分别建立了污泥红外光谱与糖原含量的定量分析模型.结果显示,偏最小二乘法得到的测量值与预测值具有较小的平均绝对误差(MAE),其相关系数达到0.921.     

The evaluation of the association constant between R-SN and Hg2+

The effective determination of heavy metals from environmental media is among the most important issues for many industrialized countries. The interaction between RS-N, as novel heavy metal probe, and metal ions was studied. RS-N shows selective color change from colorless to pink in the presence of Hg²⁺ in methanol/water solvent and the UV–Vis study shows peak at 560 nm. Fluorescence data revealed that the fluorescence enhance of RS-N by Hg²⁺ dramatically was the result of the formation of [Hg²⁺]RS-N complex. The effective association constants (K _a ) were 3.97?×?10⁵ and 0.204?×?10⁵ M^?1 for Hg²⁺ and Cu²⁺ to RS-N, respectively. The thermodynamic parameters, enthalpy change (ΔH ⁰) and entropy change (ΔS ⁰), were calculated to be ?6.431?±?0.226 kJ/mol and ?0.129?±?0.008 J/K/mol, respectively, according to van’t Hoff equation on the basis of Gibbs free energy (ΔG ⁰) ranged from ?33.8326 to ?28.5389 kJ/mol.     

风景名胜区管理体制研究综述

风景名胜区管理体制问题是旅游学中最重要的组成部分之一,是学界研究的焦点,理论研究意义重大。在查阅大量文献的基础上,立足于国内外风景名胜区管理体制现状,运用比较分析法对中外风景名胜区管理体制进行分析研究,旨在为该领域以后的研究发展方向提供借鉴和参考。     

安徽省旅游业转型升级研究——以承接长三角产业转移为例

旅游业作为我国国民经济发展战略性支柱产业的提出,促使各地区进一步加快发展旅游业的步伐。产业转移作为调整产业结构、促进经济发展的重要方式,在旅游业转型升级过程中起到了一定的推动作用。安徽省旅游资源丰富,但总体发展水平不高。通过与长三角地区旅游业发展状况的比较,找出安徽省旅游业发展中的不足之处,分析安徽省旅游业承接产业转移的原因及挑战,并提出相应对策。     

Halogenated organic contaminants (HOCs) in sediment from a highly eutrophicated lake, China: Occurrence, distribution and mass inventories

Halogenated organic contaminants (HOCs) including 16 polybrominated diphenyl ethers (PBDEs) and 37 polychlorinated biphenyls (PCBs) were determined in 49 surfacial sediments from Chaohu Lake, a highly eutrophicated lake, China. PBDEs were detected in almost samples with the range of the total concentration (defined as Σ₁₆PBDEs) from 0.84 to 86.6 ng g⁻¹. Compared with the occurrence of PBDEs in Pearl River Delta and Yangtze River Delta in China, lower percentage of BDE-209 over the concentration of Σ₁₆PBDEs was inferred by the high-volume application of penta-BDE mixture product for local domestic furniture purpose. The total concentration of 37 PCBs (Σ₃₇PCBs) ranged from 0.05 to 3.36 ng g⁻¹ with the most detection of PCB-1, -4, -52 and -71. Both the concentrations of Σ₁₆PBDE and Σ₃₇PCB poorly correlated with total organic carbon (TOC), suggesting the significant contribution of phytoplankton organic carbons to sediment TOC. The contamination by PBDEs and PCBs in western region of the lake was significantly more serious than in eastern lake. Our findings about the higher residues of PBDEs and PCBs in sediments at the estuary of Nanfei River compared to the other estuaries also supported the conclusion that urban area (Hefei city) was the main source of PBDEs and PCBs. The comparison with the concentration of HOC in the present study with those in other lacustrine sediments around the world suggested the contamination by PBDEs in Chaohu Lake is at middle of the global concentration range, whereas PCBs is at low end of the global range which could be elucidated by local economic development and historical usage of PBDEs and PCBs. The mass inventories of HOCs in the lake were estimated at 561 and 38 kg, which corresponds to only 0.000006% and 0.0001% of these global historical produce volumes, respectively.     

Effects of fulvic acid on aggregation,sedimentation, and adsorption of Fe3O4 magnetic nanoparticles

Environmental Science and Pollution Research - Environmental behavior, bioavailability, and risks posed by Fe3O4, magnetic nanoparticles (Fe3O4 NPs) in surface waters are affected by complex...     

巢湖流域土地景观格局变化及生态风险驱动力研究

健康的流域生态系统是区域经济社会可持续发展的重要基础。探讨流域土地景观格局变化及生态风险驱动机制有助于生态系统状况诊断与风险来源认识,为有效制定生态风险管控措施提供决策依据。应用空间信息技术平台及计量分析方法,探讨了基于县域行政单元的快速城市化阶段巢湖流域土地景观格局变化及生态风险驱动力。研究表明:(1)2000~2013年,巢湖流域土地景观类型变化表现出农地、林地、水体景观面积下降,建设用地景观面积显著增加的趋势;流域景观水平上多样性和均匀度呈下降、优势度呈上升趋势,景观空间异质性下降;(2)近15 a来,巢湖流域9个行政单元内生态风险均呈上升趋势,生态风险整体恶化,需加强对流域生态风险上升的管控;(3)生态风险驱动力分析表明,快速城市化阶段巢湖流域生态风险的主要驱动因子为第二产业值、城市化率、人口密度和固定资产投资,而人均GDP的增加在一定程度上会降低生态风险水平。