油指纹多元统计分析在鉴别地表水石油类污染来源中的应用研究

采用油指纹多元统计方法,对嘉兴市杭州塘和长山河水系沿岸加油站9个不同来源的轻质柴油进行了分类鉴别,并考察了风化的影响.结果表明:仅基于GC-MS谱图,很难对不同轻质柴油的来源进行鉴别;但基于GC-MS谱图,提取正构烷烃及多环芳烃特征比值,进一步采用多元统计方法,可以对不同来源的轻质柴油进行区分.考虑实际水环境中油污染物会风化,向河水中投入两种轻质柴油,考察了不同初始浓度和不同风化时间下的油指纹变化,发现油污染物初始浓度为0.5 mg·L~(-1)时,所有特征比值在风化过程中均极不稳定,无法用于分类鉴别;油污染物初始浓度达到1.0 mg·L~(-1)及以上时,特征比值C_(17)/Pr、C_(18)/Ph在风化5 d内可用作油指纹的鉴别指标,5 d后无法用于鉴别;特征比值Pr/Ph、(C_(19)+C_(20))/(C_(21)+C_(22))、CPI受风化时间影响小,始终可以作为油指纹鉴别的特征指标.     

桐乡市城市污水处理厂A~2/O工艺净化水质效果及影响因素研究

以采用A2/O工艺的桐乡城市污水处理厂净化城市污水为研究对象,介绍了该污水处理厂工艺设计、进水水质特征和水质净化效果,分析了温度、有机物负荷、氮负荷、磷负荷、可生化性、碳氮比、碳磷比、污泥产率、重金属离子浓度等因素对该污水处理厂运行的影响。结果表明:该污水厂进水水温适宜,可生化性好,碳源充足,同步脱氮除磷效果好,使该污水处理厂出水水质稳定达GB 18918-2002《城镇污水厂污染物排放标准》一级B标准。分析发现,该A2/O工艺对水中不同的重金属离子、表面活性剂、石油类有去除效果。重金属离子在活性污泥中产生富集现象,应重视污泥的处置等问题。     

挥发性氯代烃在湿润土壤中的平衡吸附研究

吸附是挥发性氯代烃(volatile chlorinated hydrocarbons,VCHs)赋存于土壤的主要机制之一.开展动态吸附实验,研究了4种常见VCHs污染物在我国8种典型土壤中的吸附平衡关系.结果表明,土壤在干燥条件下对VCHs气体的吸附能力要远大于湿润条件,且随含水率的升高吸附能力急剧下降,在含水率达到10%以后土壤吸附量趋于稳定.湿润土壤对三氯乙烯(TCE)、四氯乙烯(PCE)、1,1,1-三氯乙烷(MC)气体的吸附等温线符合Henry型吸附等温式,而1,1,2-三氯乙烷(1,1,2-TCA)符合Freundlich模型.VCHs在湿润土壤中的吸附量总体上与土壤有机碳(soil organic carbon,SOC)含量呈正相关,且受SOC类型和化合物极性影响较大.弱极性的TCE、PCE在土壤中的吸附能力与SOC含量呈严格正相关,而极性的MC、1,1,2-TCA在黑土等高碳土壤中不仅与SOC含量有关,还受到SOC物质组成的影响.建立了TCE和PCE在湿润土壤中的平衡吸附量预测模型,预测值与实测值相关性良好(n=80,R2=0.98).     

A potentiometric cobalt-based phosphate sensor based on screen-printing technology

A potentiometric cobalt-based screen-pritning sensor was fabricated by electroplating cobalt on the surface of a screen-printing electrode as the sensitive layer for the determination of dihydrogenphosphate （H2PO4） in wastewater samples. The electrochemical performance of this sensor was fully examined to determine its detection calibration, detection limit, response time, selectivity, and interference with pH, various ions, and dissolved oxygen （DO）. The cobalt-based phosphate sensor showed a phosphate-selective potential response in the range of 10 5mol·L^-1 to 10^-1 mol^-1, yielding a detection limit of 3.16 × 10μmol·L^l and a slope of -37.51 mV·decade＇ in an acidic solution （pH 4.0） of H2PO4-. DO and pH were found to interfere with sensor responses to phosphate. Ultimately, the performance of the sensor was validated for detecting wastewater samples from the Xiaojiahe Waste- water Treatment Plant against the standard speetrophotometric methods for HzPO4 analysis. The discrepancy between the two methods was generally ＋5% （relative standard deviation）. Aside from its high selectivity, sensitivity, and stability, which are comparable with conventional bulk Co-wire sensors, the proposed phosphate sensor presents many other advantages, such as low price, compactness, ease of use, and the possibility of integration with other analytical devices, such as flow injectors.     

抗生素化学合成生产废水可生化性改善试验研究

采用水解酸化与Fenton试剂分别处理高浓度抗生素化学合成废水的厌氧出水,并采用MBR验证其生化性的改善。试验表明:在废水ρ(COD)平均为4 084 mg/L时,水解酸化COD去除率平均为26.2%,ρ(BOD5)/ρ(COD)从0.23提高到0.31,但无法保证MBR出水ρ(COD)<120 mg/L。Fenton试剂反应条件为:ρ(H2O2)=5 000 mg/L,ρ(Fe2+)=4 000 mg/L,pH=7,反应时间1 h,COD去除率达50%。混合废水经MBR处理后,出水ρ(COD)平均为98.4 mg/L,可稳定达《制药工业水污染物排放标准》。     

我国工业园区生态化轨迹及政策变迁

本文梳理了我国工业园区生态化过程中,包括生态工业示范园区、循环经济园、低碳园区、绿色园区建设的政策变迁,总结出工业园区生态化的轨迹和特点,并分析了工业园区生态化过程中的不足和未来面临的挑战。我国工业园区生态化特点包括：试点-示范-推广的一般模式、学习型的政策、逐步多样的政策工具、参与政府部门的逐步多样化与最终整合的趋势、产业共生与多种环境管理措施并行的状态。未来的工业园区生态化工作需要注重理清产业共生的内涵,确定相应的政策目标、政策工具和评价体系,同时需要注重园区的能力建设。     

Applications of thermal hazard analyses on process safety assessments

In 2011, a large petrochemical complex in Taiwan incurred several fire and explosion accidents, which had considerable negative impact for the industry on both environmental and safety issues. Reactive substances are widely used in many chemical industrial fields as an initiator, hardeners, or cross-linking agents of radical polymerization process with unsaturated monomer. However, the unpredictable factors during the process having risk to runaway reaction, thermal explosion, fire, and exposure to harmful toxic chemicals release due to the huge heat and gas products by thermal decomposition could not be removed from the process. This study used differential technology of thermal analysis to characterize the inherent hazard behaviors of azo compounds and organic peroxides in the process, to seek the elimination of the source of the harmful effects and achieve the best process safety practices with zero disaster and sound business continuity plan.     

Modelling the interactions between nutrients and the submersed vegetation in the Orbetello Lagoon

The main problem in the Orbetello Lagoon is the control of the submersed vegetation, both in biomass and inventory, to manage a problematical coexistence between macroalgae and macrophytes. While macroalgae are liable to cause dystrophic crises, macrophytes oxygenate and stabilise the sediment and thus control the nutrient flux into the water. A mathematical model was required by the Orbetello Lagoon Managerial Office to predict the development of both groups and test the actions to favour macrophytes over macroalgae, in the context of a decision support system. This model, developed for this need, takes into account the interactions between nutrients and the submersed vegetation in a 2D spatial context including a hydrodynamic model for the water movements and an ecological model describing the interactions between nutrients and the submersed vegetation. In the spatial grid the model operates with two interlocked modules: each cell implements the kinetics of nutrients, vegetation and their interactions, running on an hourly basis to keep track of the circadian cycles, whereas an advection/diffusion mechanism running on a daily basis exchanges information among all the grid cells. The model output consists of daily variations in nutrient concentrations and vegetation biomass showing the relative abundance of either group as a consequence of environmental conditions. After a sensitivity assessment, the model has been calibrated with data from the Orbetello Lagoon, where it can now be used as a forecasting tool to predict the development of vegetation and the relative advantage that macrophytes may have upon macroalgae.     

Phosphate adsorption performance of a novel filter substrate made from drinking water treatment residuals

Phosphate is one of the most predominant pollutants in natural waters. Laboratory experiments were conducted to investigate the phosphate adsorption performance of a(NFS) made from drinking water treatment residuals. The adsorption of phosphate on the NFS fitted well with the Freundlich isotherm and pseudo second-order kinetic models. At p H 7.0, the maximum adsorption capacity of 1.03 mg/g was achieved at 15°C corresponding to the wastewater temperature in cold months, and increased notably to 1.31 mg/g at 35°C.Under both acidic conditions(part of the adsorption sites was consumed) and basic conditions(negative charges formed on the surface of NFS, which led to a static repulsion of PO43-and HPO42-), the adsorption of phosphate was slightly inhibited. Further study showed that part of the adsorption sites could be recovered by 0.25 mol/L Na OH. The activation energy was calculated to be above 8.0 k J/mol, indicating that the adsorption of phosphate on NFS was probably a chemical process. Considering the strong phosphate adsorption capacity and recoverability, NFS showed great promise on enhancing phosphate removal from the secondary treated wastewater in the filtration process.     

How to promote industrial park recycling transformation in China: An analytic framework based on critical material flow

As an important conduit of industrial development, industrial parks have contributed significantly to economic development, particularly through the construction of eco-industrial parks (EIPs). With the increase in the number and type of parks, industrial park recycling transformation (IPRT) has been pivotal in developing the circular economy concept at the regional level in China. Compared with EIPs, this study identifies the characteristics of IPRT as green, cyclic, efficient, shared, and sustainable. To effectively explore how to promote IPRT development, the concept of critical material flow with material flow analysis is introduced to trace materials that are critical to high consumption areas with significant environmental impacts. The paper also suggests that cleaner production audits of enterprises can provide a basis for critical material flow analysis. Analysis of critical material flow pathways can facilitate the establishment of reverse logistics, which is important for achieving closed-loop IPRT through imitation of natural ecosystem cycles. In addition, an information system and database management platform are required to support critical material flow analysis in IPRT. Using a case study of the Tianjin Economic-Technological Development Area, the findings reveal that IPRT can be promoted from enterprises at the micro-level to parks at the macro-level based on critical material flow analysis. These results provide a methodological and practical reference for improving the stability of the industrial symbiosis of EIPs and contribute to IPRT research. Moreover, an analytic framework is provided that demonstrates how to promote IPRT in practice.