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131.
132.
Extracellular polymeric substances (EPS) were extracted from Aspergillus fumigatus using cationic exchange resin technique. The EPS were mainly composed of polysaccharide and low quantities of protein and nucleic acid. Biosorption of Cd(II), Pb(II), and Cu(II) of EPS was investigated as a function of pH using differential pulse polarography and the Ruzic model. Results showed that the EPS biosorption capacity determined using either the direct titration curves i?=?f(C M) or the method proposed by Ruzic (Analytica Chimica Acta 140:99–113, 1982) were coincident. Cu(II) had the highest affinity with EPS followed by Pb(II) and Cd(II). The total number of binding sites for Cu(II) and Cd(II) increased with pH in the range of 4.0–7.0. Similar trend was observed for Pb(II) at pH?4.0–5.0, while precipitates were observed at pH?6.0 and 7.0. The conditional binding constants of these three metals displayed low levels of fluctuation with pH and ranged from 4.02?±?0.02 to 5.54?±?0.05. 相似文献
133.
在淋洗液中加入H2O2和三乙醇胺配制成吸收液,通过离子色谱法同时测定废印刷电路板真空热解气相产物中HBr、NO_2和SO_2的含量,方法简单、快速、准确。当用50 m L吸收液、采样体积为30 L时,3种污染物的检出限分别为0.000 005 7、0.000 003 4、0.000 002 9 mg/L。该方法加标回收率为95.7%~104.8%,完全能满足废印刷电路板真空热解气相污染物中HBr、NO_2和SO_2的同时测定要求。利用该方法和行标方法同时测定环境空气中的HBr、NO_2和SO_2,再利用Excel分析工具对测定数据进行F检验和t检验,检验结果表明2种测定方法无显著差异。 相似文献
134.
针对我国当前广泛使用的2种高速公路噪声预测模型《06规范》预测模型与《09导则》预测模型在预测时比较研究,重点利用环境现状监测数据分别对2种模型验证与对比分析.结果表明,2种模型预测值与实测值相差3dB ~5dB,车流量> 300辆/h,《09导则》更接近实测值;在夜间车流量<300辆/h,《06规范》更接近实测值,2种模型结合采用《06规范》计算的车速,距离衰减考虑车流量的大小,在此基础上应用《09导则》,预测结果与实测值更为接近. 相似文献
135.
Stefan Bachu Mehran Pooladi-Darvish Huifang Hong 《International Journal of Greenhouse Gas Control》2009,3(4):468-473
Laboratory experiments reported in a companion paper were carried out to examine the chromatographic partitioning of impurities contained in a stream of CO2 injected into a deep saline aquifer. The solubility of the impurity gas in the CO2 stream compared to that of CO2, the in situ conditions of pressure, temperature and water salinity, and the concentration of the impurity gas affect the partitioning of the two gases. For CO2 streams containing H2S, numerical simulations reported here have successfully replicated the laboratory results including the breakthrough of CO2 ahead of H2S. Sensitivity analysis performed with the numerical model has shown that flow conditions, controlled by such parameters as medium permeability, pressure gradient, dispersion, gas mobility and flow direction, affect the breakthrough time and separation of the two gases, leading to delayed or earlier breakthrough, and increasing or decreasing the time lag between the breakthrough of the two gases. Vertical bottom-up flow leads to earlier breakthrough, while top-down flow leads to delayed breakthrough. These results are important in establishing monitoring strategies at CO2 storage sites and in evaluating the risks associated with the possible leakage of injected CO2 that contains impurities. 相似文献
136.
广州市地面塌陷的形成原因与时空分布 总被引:6,自引:0,他引:6
地面塌陷是珠江三角洲城市地质灾害的主要类型之一。广州市地面塌陷灾害频繁发生,近10年来呈波动式上升趋势。其塌陷类型分为岩溶塌陷和工程地面塌陷两种,岩溶塌陷主要分布在广花盆地的花都区、白云区,工程地面塌陷主要分布在中心城区。地面塌陷灾害孕灾环境复杂、致灾因子多样,承灾体脆弱,灾害后果严重。人为因素是地面塌陷的主要诱发因素。岩溶塌陷主要是由于过量抽取地下水或矿山疏干排水、地下采空、暴雨触发所致;工程塌陷主要是人类工程行为所致,其主要致灾因子包括排水疏干与突水(突泥)作用、人工加载、人工振动、人工开挖桩基、地表渗水、地铁等地下工程盾构掘进等。 相似文献
137.
Dinh Hieu Vu Kuen-Sheng Wang Jung-Hsing Chen Bui Xuan Nam Bui Hoang Bac 《Waste management (New York, N.Y.)》2012,32(12):2306-2314
Along with the gradually increasing yield of the residues, appropriate management and treatment of the residues have become an urgent environmental protection problem. This work investigated the preparation of a glass–ceramic from a mixture of bottom ash and fly ash by petrurgic method. The nucleation and crystallization kinetics of the new glass–ceramic can be obtained by melting the mixture of 80% bottom ash and 20% fly ash at 950 °C, which was then cooled in the furnace for 1 h. Major minerals forming in the glass–ceramics mainly are gehlenite (Ca2Al2SiO7) & akermanite (Ca2MgSiO7) and wollastonite (CaSiO3). In addition, regarding chemical/mechanical properties, the chemical resistance showing durability, and the leaching concentration of heavy metals confirmed the possibility of engineering and construction applications of the most superior glass–ceramic product. Finally, petrurgic method of a mixture of bottom ash and fly ash at 950 °C represents a simple, inexpensive, and energy saving method compared with the conventional heat treatment. 相似文献
138.
139.
Characteristics of toluene decomposition and formation of nitrogen oxide (NOx) by-products were investigated in a dielectric barrier discharge (DBD) reactor with/without catalyst at room temperature and atmospheric pressure. Four kinds of metal oxides, i.e., manganese oxide (MnOx), iron oxide (FeOx), cobalt oxide (CoOx) and copper oxide (CuO), supported on Al2O3/nickel foam, were used as catalysts. It was found that introducing catalysts could improve toluene removal efficiency, promote decomposition of by-product ozone and enhance CO2 selectivity. In addition, NOx was suppressed with the decrease of specific energy density (SED) and the increase of humidity, gas flow rate and toluene concentration, or catalyst introduction. Among the four kinds of catalysts, the CuO catalyst showed the best performance in NOx suppression. The MnOx catalyst exhibited the lowest concentration of O3 and highest CO2 selectivity but the highest concentration of NOx. A possible pathway for NOx production in DBD was discussed. The contributions of oxygen active species and hydroxyl radicals are dominant in NOx suppression. 相似文献
140.
《Journal of Cleaner Production》2007,15(5):439-448
Generally, a refinery complex consists of process system and utility system. Process system not only produces liquefied petroleum gas, gasoline, diesel and so on, but also some byproducts, such as fuel gas and residual fuel oil, which supply utility system as fuel. The utility system converts fuel gas and fuel oil to high pressure or medium pressure steam and electricity to meet the energy demand of the process system. A novel approach to the integration of the process system and utility system for better energy utilization is presented in this paper. A plant-wide multi-period planning mathematical model is proposed and three improvements are identified. First, the process unit energy-consumed model is reformulated, because energy consumed by a unit not only relates the throughput of the unit, but also varies with the operation modes of the unit and season. Second, The MILP (Mixed Integer linear Programming) model of utility system is embedded in the plant-wide model to gain the overall optimization and for better energy efficiency. Third, steam, fuel oil and fuel gas are balanced in the whole plant. Finally, the proposed approach was used in a real industrial example to determine the optimal mass and energy flow and some important results have been obtained and are presented. 相似文献