加入SOA示踪的深圳大气PM2.5受体模型源解析

为厘清包括二次有机气溶胶（SOA）在内的深圳市区PM_2.5各种一次和二次来源贡献,本文于2017年9月2日~2018年8月29日在深圳市大学城点位开展PM_2.5样品采集,并进行化学组分和水溶性有机物（WSOM）质谱测量,共获得162组有效数据.观测期间深圳市大气PM_2.5平均质量浓度为26μg/m³,在传统PMF源解析的基础上加入羧基离子碎片（CO₂⁺）作为SOA的示踪物,加入水溶性有机氧（WSOO）用于计算各因子O/C,验证有机物解析效果.结果表明,SOA可以被独立解析出,其O/C明显高于其他一次污染源中有机物;机动车、二次硫酸盐、二次硝酸盐、SOA为最主要的4个源,对PM_2.5质量浓度的贡献分别为25%、23%、17%和10%,船舶、地面扬尘、老化海盐、建筑尘、生物质燃烧、燃煤和工业贡献均在5%以内.各个源的变化特征表明,机动车、二次硫酸盐、二次硝酸盐、SOA等源贡献呈现冬高夏低的季节特征,与冬季季风条件下源自内陆的污染传输密切相关.污染天气时,二次硝酸盐和SOA的贡献增加相对最显著,因此NOx和挥发性有机物是减排的关键.     

Cadmium removal from wastewater by sponge iron sphere prepared by charcoal direct reduction

Sponge iron sphere (SIS), made of concentrated iron powder and possessed high activity and intension, was prepared through the process of palletizing, roasting and direct reduction by charcoal. The sponge iron sphere could remove most of Cd²⁺ from wastewater. The results showed the Cd²⁺ removal followed the first order reaction. Initial pH value played an important role in Cd²⁺ removal. With original initial pH, Cd²⁺ removal decreased to the minimum and then increased slightly with the rising of original concentration. The removal rate constant was ?0.1263 and ?0.0711 h^?1, respectively, under the Cd²⁺ concentration of 50 and 200 mg/L. When the initial pH was adjusted to 3.0, the removal rate constant could increase to ?9.896 and ?4.351 h^?1, respectively. The removal percentage almost reached to 100% when Cd²⁺ concentration was below 100 mg/L. While Cd²⁺ concentration was above 100 mg/L, Cd²⁺ removal percentage decreased slightly. In dynamic experiments, the column filled with sponge iron sphere exhibited favorable permeability. There was no sphere pulverization and conglutination between spheres. In contrast to the static state experiments, the Cd²⁺ removal percentage in dynamic state experiment was lower, and the removal Cd²⁺ quantity was 1.749 mg/g.     

工作满意度对建筑工人不安全行为的矫正机制研究*

为探讨工作满意度对建筑工人不安全行为矫正机制,基于文献调研构建工作满意度对建筑工人不安全行为矫正机制理论模型,并通过验证性因子分析和结构方程模型分析,对理论模型进行实证检验。结果表明:工作满意度对建筑工人安全不服从行为和安全不参与行为有显著矫正作用,敬业度在工作满意度和建筑工人安全不服从行为与安全不参与行为间起完全中介作用。对于新生代建筑工人,工作满意度通过敬业度对安全不服从行为矫正效应小于对安全不参与行为的矫正效应,对于老一代建筑工人,矫正效应则相反。研究结果可为广大建筑施工企业矫正其工人的不安全行为提供依据。     

我国生态工业园区投融资及管理模式分析

通过投融资和运营管理角度分析我国生态工业园区建设和运行状况,总结其特点,分析我国生态工业园区投融资及运营管理的发展趋势,包括采取政府主导投资和运营管理的园区类型、行政监管的方式、管理主体对出资人意愿的落实、专业化运营的体现等。     

人工快渗技术在我国农村地区水污染治理中的应用研究

概述了我国农村地区水污染现状、排放特征、主要处理工艺及其优缺点,在对人工快渗系统工艺原理和污染物去除机理深入分析的基础上,总结归纳了人工快渗工艺的技术经济优势,并结合技术的工艺改进和完善,探讨了人工快渗技术的适用性。然后结合深圳市白花洞村、四川省绵阳市北川县及北京昌平区农村工程实践,分析了人工快渗技术在村级分散型污水处理工程中的实际运行效果。理论研究和工程实践均表明:人工快渗技术及其改进工艺组合系统具有工艺简单、建设运行成本低、污染物去除效率高、出水效果好等特点,可有效地解决目前农村地区因受到资金、技术、人才等因素限制造成的污水处理能力低的问题,是一项十分适合我国农村地区的污水处理技术。     

环评助推房地产业低碳发展的思考和对策建议

在全球变暖的趋势下,人们越来越重视碳排放问题,房地产业作为碳排放大户,履行节能减排、建筑低碳任务应首当其冲,本文从房地产项目的环评及其技术评估角度,论述了中国城市房地产项目建筑低碳化一般采取的措施和具体要求,探讨符合中国国情的城市低碳房地产发展的对策和建议。     

我国典型非木浆造纸二噁英排放研究

根据《中国履行〈关于持久性有机污染物的斯德哥尔摩公约〉国家实施计划》,制浆造纸行业是我国开展二英履约减排的六大重点行业之一,需要在规定的时间内达到减排要求.非木浆在我国原生纸浆生产和消费中一直占有重要比例,其生产过程中广泛使用的元素氯漂白工艺被认为是造成制浆造纸行业二噁英产生的重要来源.非木纤维制浆将在我国长期存在,摸清该领域二噁英排放情况,对于我国履约和实施二噁英的减排措施有重要意义.通过对竹子、麦草、芦苇和蔗渣这4种非木纤维的典型制浆企业的漂白全过程开展二噁英排放情况的检测,并结合各企业的浆水平衡数据,得到我国应用氯化碱处理次氯酸盐(CEH)三段漂白典型工艺的草浆、苇浆、竹浆及蔗渣浆生产的外排水所含二噁英的浓度(以I-TEQ计,下同)分别为:41.8、72.7、7.46和19.7 pg.L-1,尽管都在国家规定的新排放标准附近(30 pg.L-1),但随着我国对制浆造纸行业吨耗水要求的日益严格和以上新标准的实施,相关浓度很容易超标.为了实现国内、国际环境管理的要求,认为我国有必要尽快推动该行业研究并应用二噁英减排的最佳可行技术和最佳环境实践(best available techniques/best environmental practices,BAT/BEP).同时,结合监测数据,还初步估算了非木浆元素氯漂白相关的二噁英排放因子,可为联合国环境署补充相关因子提供有意义的参考.     

Measuring maintenance culture and maintenance core task with CULTURE-questionnaire––a case study in the power industry

Organisational culture has become a focus of much attention in industry in general and the nuclear industry in particular. In maintenance work, the research has addressed mainly human error issues or strategic decision making and optimisation. The present study utilises the CULTURE-questionnaire that is designed to measure the different cultural aspects of complex organisations. Functioning of the questionnaire and the results obtained in a case study at a maintenance organisation of a nuclear power plant are reported in this paper. The questionnaire consisted of four instruments: measures of values, psychological job characteristics, individual perceptions and organisational core task. Three of the instruments were factor analysed and 13 summated scales were formed. The core task instrument was used in a cluster analysis to separate the respondents into groups on the basis of their orientation towards the maintenance work. Differences between the work tasks, section, age and length of service were studied. Hierarchical position in the company influenced perceptions of values. Core task orientation influenced the perception and subjective feelings towards one's organisation. Several partially overlapping subcultures were thus identified. The implications of the different work orientations for effective maintenance are discussed.     

外加磷提高生物预处理效果的试验研究

利用国内研究较多的生物陶粒滤池预处理工艺,在我国北方某水库原水中添加微量的磷,考察磷对生物预处理的促进作用通过生物分析方法,发现在原水水样中添加50μg/L的PO₄^3--P(NaH₂PO₄)后,可以促进原水中细菌的生长,BDOC也有所增加,证明了原水中磷对细菌生长的限制因子作用陶粒滤池的实际运行结果表明,对于本试验所用原水,添加25μg/L的PO₄^3--P(H₃PO₄)后,生物陶粒滤池对水中CODMn的去除率平均提高4.7个百分点,UV254和TOC的去除率分别提高3.6和5.7个百分点.由此为提高生物预处理的运行效果提供了一个新的思路,也说明磷在饮用水中的作用需要引起重视.     

The effect of commuting microenvironment on commuter exposures to vehicular emission in Hong Kong

Vehicular exhaust emission has gradually become the major air pollution source in modern cities and traffic related exposure is found to contribute significantly to total human exposure level. A comprehensive survey was conducted from November 1995 to July 1996 in Hong Kong to assess the effect of traffic-induced air pollution inside different commuting microenvironments on commuter exposure. Microenvironmental monitoring is performed for six major public commuting modes (bus, light bus, MTR, railway, tram, ferry), plus private car and roadside pavement. Traffic-related pollutants, CO, NO_x, THC and O₃ were selected as the target pollutants. The results indicate that commuter exposure is highly influenced by the choice of commuting microenvironment. In general, the exposure level in decreasing order of measured pollutant level for respective commuting microenvironments are: private car, the group consisting light bus, bus, tram and pavement, MTR and train, and finally ferry. In private car, the CO level is several times higher than that in the other microenvironments with a trip averaged of 10.1 ppm and a maximum of 24.9 ppm. Factors such as the body position of the vehicle, intake point of the ventilation system, fuel used, ventilation, transport mode, road and driving conditions were used in the analysis. Inter-microenvironment, intra-microenvironment and temporal variation of CO concentrations were used as the major indicator. The low body position and low intake point of the ventilation system of the private car are believed to be the cause of higher intake of exhaust of other vehicles and thus result in high pollution level in this microenvironment. Compared with other metropolis around the world and the Hong Kong Air Quality Objectives (HKAQO), exposure levels of commuter to traffic-related air pollution in Hong Kong are relatively low for most pollutants measured. Only several cases of exceedence of HKAQO by NO₂ were recorded. The strong prevailing wind plus the channeling effect created by the harbor, the fuel used, the relative abundance of new cars and the successful implementation of the vehicle emission control program are factors that compensate the effect of the emission source strength and thus lead to low exposure levels.