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811.
812.
813.
燃煤火电厂石灰石—石膏湿法烟气脱硫系统日常运行环保监督考核方法探讨 总被引:1,自引:0,他引:1
从二氧化硫总量减排环保监督管理的实际出发,结合日常监督工作的实例,分析影响烟气脱硫效率的因素,找出脱硫系统容易出现的故障,提出对脱硫系统日常监督考核的重点,探索建立烟气脱硫系统监督考核方法。 相似文献
814.
Characterization of organic matter in total suspended particles by
thermodesorption and pyrolysis-gas chromatography-mass spectrometry 总被引:1,自引:0,他引:1
ZHAO Jinping PENG Ping’an SONG Jianzhong MA Shexi SHENG Guoying FU Jiamo 《环境科学学报(英文版)》2009,21(12):1658-1666
The organic matter in tropospheric aerosol plays an important role in atmospheric physical and chemical processes. The bulk of
organic matter, representing a significant proportion of the total suspended particulate (TSP) mass, is bound to polymeric material
whose structure and properties are largely unknown. Here we used thermodesorption gas chromatography/mass spectrometry (Td-
GC/MS) to study organic compounds of low molecular mass and pyrolysis gas chromatography/mass spectrometry (Py-GC/MS) to
characterize the chemical structure of macromolecules in TSP samples collected in di erent seasons from di erent sites in Guangzhou.
n-Alkanes, fatty acids and nitriles were the predominant compounds in the thermodesorption products, whereas aromatics, fatty acids,
nitriles and n-alkanes/alkenes were the major compounds in the pyrolysates. The results indicated that aromatics were main units in
macromolecules. The fatty acids and nitriles formed from carboxylic ammonium salts were detected in both thermodesorption products
and pyrolysates at a certain concentration, indicating the importance of these compounds in TSP formation. The TSP source mainly
determined the occurrence of compounds in samples from urban, suburban and forest sites, whereas the TSP source and formation
process maybe controlled the seasonal variation in compounds detected. High levels of nitriles in summer samples from suburban and
forest sites coincide with the release of ammonium from the land and of fatty acids from vegetation at these sites. 相似文献
815.
电厂燃煤锅炉烟气脱硫是减少和控制酸雨的有效手段。LS氨法喷雾脱硫技术具有脱硫效率高、环境效益好、资源综合利用的特点。以合成氨生产装置回收的低浓度氨水为吸收剂,实施锅炉烟气脱硫技术改造.取得良好的应用效果。 相似文献
816.
Evaluation of mercury speciation and removal through air pollution control
devices of a 190 MW boiler 总被引:1,自引:0,他引:1
Chengli Wu Yan Cao Zhongbing Dong Chinmin Cheng Hanxu Li Weiping Pan 《环境科学学报(英文版)》2010,22(2):277-282
Air pollution control devices (APCDs) are installed at coal-fired power plants for air pollutant regulation. Selective catalytic reduction
(SCR) and wet flue gas desulfurization (FGD) systems have the co-benefits of air pollutant and mercury removal. Configuration
and operational conditions of APCDs and mercury speciation a ect mercury removal e ciently at coal-fired utilities. The Ontario
Hydro Method (OHM) recommended by the U.S. Environmental Protection Agency (EPA) was used to determine mercury speciation
simultaneously at five sampling locations through SCR-ESP-FGD at a 190 MW unit. Chlorine in coal had been suggested as a factor
a ecting the mercury speciation in flue gas; and low-chlorine coal was purported to produce less oxidized mercury (Hg2+) and more
elemental mercury (Hg0) at the SCR inlet compared to higher chlorine coal. SCR could oxidize elemental mercury into oxidized
mercury when SCR was in service, and oxidation e ciency reached 71.0%. Therefore, oxidized mercury removal e ciency was
enhanced through a wet FGD system. In the non-ozone season, about 89.5%–96.8% of oxidized mercury was controlled, but only
54.9%–68.8% of the total mercury was captured through wet FGD. Oxidized mercury removal e ciency was 95.9%–98.0%, and there
was a big di erence in the total mercury removal e ciencies from 78.0% to 90.2% in the ozone season. Mercury mass balance was
evaluated to validate reliability of OHM testing data, and the ratio of mercury input in the coal to mercury output at the stack was from
0.84 to 1.08. 相似文献
817.
纳米催化剂Pd/SnO_2的制备及催化还原硝酸盐反应的调控 总被引:1,自引:1,他引:0
采用热分解法制备了SnO2载体,并用浸渍法制备了Pd/SnO2催化剂.同时,采用X射线衍射仪(XRD)、透射电镜(TEM)、扫描电镜(SEM)及BET比表面积仪等对所制载体和催化剂材料进行了分析表征.结果表明,热分解法和浸渍法都能够获得纳米材料,SnO2及Pd/SnO2的粒径均在9~10nm左右,比表面积分别达到144.99m·2g-1和147.36m·2g-1.在以甲酸为还原剂的Pd/SnO2催化还原硝酸盐体系中,在Pd与SnO2负载比为2%~7%,反应温度为20~50℃和甲酸投加量4.0~24.0mmol·L-1的条件下,催化活性为0.70~9.48mg·min-·1g-1,且催化活性随着负载比、温度和甲酸投加量的增大而增大,随着pH的升高先升后降,最佳pH为3.反应温度升高及pH降低都能够提高Pd/SnO2的选择性.甲酸-Pd/SnO2催化还原硝酸盐体系中还原反应的调控策略为:反应温度宜控制在40~50℃内,这样可同时获得较高的催化活性和选择性,温度过高对催化活性和选择性影响很小,温度过低则会同时降低催化活性和选择性;控制pH为3时,可以获得最大的催化活性及较好的选择性,pH升高会降低Pd/SnO2的催化活性和选择性,pH降低会导致催化活性迅速降低,但对选择性影响不大;甲酸与硝酸盐的物质的量比宜大于4:1,此时可以有效地抑制pH的上升,同时获得较高的催化活性和选择性,甲酸与硝酸盐的物质的量比小于4:1时,会同时降低Pd/SnO2的催化活性和选择性. 相似文献
818.
《辽宁城乡环境科技》2009,(1):12-12
4吨农林废弃物制成“生态油”可替代1吨燃料油或柴油,将节省成本近40%,若我国所有耕地的农林废弃物都用来制备“生态油”,将不再需要进口石油。广州首家海外上市公司迪森能源集团日前宣布,国内首个“生态油”技术在穗研制成功。“生态油”是利用各种农林废弃物(如秸秆、锯末、甘蔗渣、稻糠等)采用超高加热速率,1~2秒钟的超短产物停留时间及适中的裂解温度,通过特殊工艺制备而成的一种类似原油的清洁液体燃料。 相似文献
819.
820.