Removal of formaldehyde over MnxCe1-xO2 catalysts: Thermal catalytic oxidation versus ozone catalytic oxidation

MnxCe1- xO2（x： 0.3–0.9） prepared by Pechini method was used as a catalyst for the thermal catalytic oxidation of formaldehyde（HCHO）. At x = 0.3 and 0.5, most of the manganese was incorporated in the fluorite structure of Ce O2 to form a solid solution. The catalytic activity was best at x = 0.5, at which the temperature of 100% removal rate is the lowest（270°C）. The temperature for 100% removal of HCHO oxidation is reduced by approximately 40°C by loading 5 wt.% Cu Oxinto Mn0.5Ce0.5O2. With ozone catalytic oxidation, HCHO（61 ppm） in gas stream was completely oxidized by adding 506 ppm O3 over Mn0.5Ce0.5O2 catalyst with a GHSV（gas hourly space velocity） of 10,000 hr-1at 25°C. The effect of the molar ratio of O3 to HCHO was also investigated. As O3/HCHO ratio was increased from 3 to 8, the removal efficiency of HCHO was increased from 83.3% to 100%. With O3/HCHO ratio of 8, the mineralization efficiency of HCHO to CO2 was 86.1%. At 25°C, the p-type oxide semiconductor（Mn0.5Ce0.5O2） exhibited an excellent ozone decomposition efficiency of 99.2%,which significantly exceeded that of n-type oxide semiconductors such as Ti O2, which had a low ozone decomposition efficiency（9.81%）. At a GHSV of 10,000 hr-1, [O3]/[HCHO] = 3 and temperature of 25°C, a high HCHO removal efficiency（≥ 81.2%） was maintained throughout the durability test of 80 hr, indicating the long-term stability of the catalyst for HCHO removal.     

空气涡轮制冷低温粉碎法回收废弃橡胶

利用带回冷循环的空气涡轮制冷系统，在低温条件下，将废旧橡胶进行冷冻、粉碎、制成６０目以上的精细胶粉。此法的冷冻能耗成本仅为国际上通用的液氮法的１／１０，整具工艺过程不产生二次污染，为废旧橡胶的综合利用提供了一条新途径。     

环境温度变化对低温试验箱性能的影响

从环境温度变化对低温试验箱低温性能的影响作一些具体的分析和介绍,并提出了几点措施,以供有关技术人员参考。     

新疆地区地温采暖技术的应用探讨

针对寒冷地区建筑物的采暖方式，介绍一种新型的区域供暖方式－－地温水源热泵（地温中央空调）供暖系统，为寻找新型供暖方式提出了环保安全、绿色节参采暖制冷新理念。     

环境中有机污染物的半导体光催化降解研究进展

应用半导体二氧化钛光催化剂促进氧化降解环境中常见有机污染物是一种有效的清洁处理技术,对光催化活性的半导体的必要性质,影响光催化效率的内在因素以及反应器,反应条件等方面的因素进行了讨论。     

冬季保健：以冷制冷

随着天气日渐转凉,很多老年人又裹上了厚厚的冬装,试图通过驱寒保暖来防病健身。其实,采取“以冷制冷”的方法,不但对身体无害,还有许多益处。     

国内外冷却服的发展现状及关键技术

本文论述了国内外冷却服的发展现状,介绍了3种制冷技术路线,指出了其各自的关键技术,有利于人们对冷却服的发展趋势进一步的了解和认识.     

硬度测试在小型制冷装置压力容器检验中的应用

随着工业经济的发展,小型制冷装置在工厂中的使用越来越多。由于企业管理方面的原因,往往会碰到设备资料缺损或遗失的情况,这些情况导致特种设备检验人员在检验中,对容器安全状况的判断有很大的困难。如何保证这些设备安全运行的同时,又能减少企业不必要的损失。在检测小型制冷装置压力容器时,运用好硬度检测也是一种行之有效的方法。     

生物质型煤锅炉

由北京雄财技贸集团开发的生物质型煤锅炉适用于供暖、空调制冷、洗浴、饮用水. 主要技术内容 一、基本原理 型燃料环保节能热源属于常压热水锅炉,热源机的设计采用"双向逆流聚焰燃烧"原理.