武汉市幼儿园降尘Pb污染特征及其生物有效性

幼儿园降尘铅污染是儿童对环境铅暴露的重要途径.从武汉市不同功能区幼儿园采集69个降尘样品,分析了其中铅的含量与空间分布,同时根据体外模拟实验方法（PBET）研究降尘中铅的生物可给行,目的是阐明武汉市幼儿园降尘铅的分布特征、污染程度,评估降尘中的铅对人体（尤其是儿童）的生物有效性.结果表明,武汉市幼儿园降尘中全铅含量为36.3～1 523mg.kg-1,平均值为169 mg.kg-1;与国内外部分城市对比发现,武汉市降尘中铅含量水平较低.武汉市降尘中铅分布空间差异大,局部污染严重.降尘铅在胃和小肠阶段的生物可给性分别为35%±15%和7.6%±5.8%.采用国际上认可度较高的综合暴露吸收生物动力学模型（IEUBK）,预测儿童（0～6）岁群体环境铅暴露后血铅几何均值2.73μg.dL-1;超过10μg.dL-1的概率〈0.001%,超过5μg.dL-1的概率为3.32%.     

中俄联合监测水质中总磷测定实验的方法与结果对比分析

近年来,中俄双方开展了对等联合监测,但由于国域差别,两个国家在一个项目上采取了不同的实验方法,常出现同一个样品中俄双方出现不同的实验结果,为避免分歧,我国在少数几个站进行了中俄双方实验方法的对比实验,现就水质中总磷的测定将两国的实验方法和实验结果进行了分析。     

超市塑料袋使用行为的环境实验研究

塑料购物袋一直是社会关注的热点环境问题。文章以上海某超市为对象,采用现场观察实验方法记录了5 086份超市顾客塑料袋使用行为的样本,初步揭示了超市塑料袋使用情况和塑料袋使用的顾客行为特征,尝试为超市塑料袋的环境管理政策提供基础性的科学依据。结果表明:(1)超市中主要有3种塑料袋使用方式,依次为购买塑料袋、自带购物袋、使用免费手撕袋,其比例为15%、29%、9%,说明目前塑料袋使用行为具有一定的多样性;(2)影响顾客购买塑料袋的因素为是否有会员卡、是否徒手购物、购物金额,其偏相关系数依次为0.114、0.085、0.042。占总样本63.4%的单人购物情境中,购买塑料袋的影响因素为是否徒手购物、是否有会员卡、年龄、购物金额、性别,偏相关系数依次为0.849、0.486、0.329、0.291、0.180;说明影响塑料袋使用的因素具有综合性和复杂性。(3)顾客购物金额、购物件数、结账时间与塑料袋购买比例有密切的正相关关系;(4)按照购买塑料袋的倾向程度,可将顾客分为高、中、低3类特征群体。其中,购买倾向最高的顾客特征为无会员卡的男性中青年、非徒手购物,购物金额较高。文章研究为解决环境管理问题提供了一种基于现场观察实验方法的案例参考,建议将定量、可重复、可检验、以现场观察记录主的实验方法应用于各类环境问题研究和解决方案中,为环境管理提供更扎实的科学依据。     

神秘“上帝粒子”现踪影

欧洲科研人员13日宣布,他们可能“瞥见”希格斯玻色子,但现有数据无法确切证实。欧洲核子研究中心科研人员当天在日内瓦告诉媒体记者,两项强子对撞实验项目ALTAS和CMS有一些相似发现,让科研人员颇为兴奋。     

脱色剂Z60去除焦化废水色度的应用研究

在单因素影响试验基础上用正交实验法研究了脱色剂Z60对焦化废水色度的去除效果,对最佳反应时间、温度、药剂投加量进行了初步试验研究,试验表明：在搅拌强度满足均匀混合条件下,反应温度25oC,絮凝沉降时间40min,色度去除率达80％以上,色度低于50倍。     

一株微生物絮凝剂产生菌的培养基优化研究

利用单因子实验和部分因子实验对实验室保藏的产絮凝剂菌种C3的培养基进行优化,以提高C3菌所产生的微生物絮凝剂MBFC3的絮凝效果.实验结果表明,C3菌产MBFC3的最适培养基为: 蔗糖1.0 g,(NH4)2SO4 0.24 g,FeSO4 0.10 g,KH2PO4 0.40 g,MgSO4 0.01 g,NaCl 0.02 g,蒸馏水100 mL,pH值自然.在此培养条件下,C3菌所产生的微生物絮凝剂MBFC3对高岭土悬浮液的絮凝率可达到99.1%.实验中还发现,培养基中(NH4)2SO4和NaCl的用量是影响MBFC3絮凝效果的显著因素.     

Experimental investigation of the e ect of flow turbulence and sediment transport patterns on the adsorption of cadmium ions onto sediment particles

The mechanism of flow turbulence,sediment supply conditions,and sediment transport patterns that affect the adsorption of cadmiumions onto sediment particles in natural waters are experimentally simulated and studied both in batch reactors and in a turbulencesimulation tank.By changing the agitation conditions,the sediment transport in batch reactors can be categorized into bottom sediment-dominated sediment and suspended sediment-dominated sediment.It is found that the adsorption rate of bottom sediment is much lessthan that of suspended sediment,but the sediment transport pattern does not affect the final(equilibrium)concentration of dissolvedcadmium.This result indicates that the parameters of an adsorption isotherm are the same regardless of the sediment transport pattern.Inthe turbulence simulation tank,the turbulence is generated by harmonic grid-stirred motions,and the turbulence intensity is quantifiedin terms of eddy diffusivity,which is equal to 9.84F(F is the harmonic vibration frequency)and is comparable to natural surfacewater conditions.When the turbulence intensity of flow is low and sediment particles stay as bottom sediment,the adsorption rateis significantly low,and the adsorption quantity compared with that of suspended sediment is negligible in the 6 h duration of theexperiment.This result greatly favors the simplification of the numerical modeling of heavy metal pollutant transformation in naturalrivers.When the turbulence intensity is high but bottom sediment persists,the rate and extent of descent of the dissolved cadmiumconcentration in the tank noticeably increase,and the time that is required to reach adsorption equilibrium also increases considerablydue to the continuous exchange that occurs between the suspended sediment and the bottom sediment.A comparison of the results ofthe experiments in the batch reactor and those in the turbulence simulation tank reveals that the adsorption ability of the sediment,andin particular the adsorption rate,is greatly over-estimated in the batch reactor.     

种植苜蓿草的生态环境效益和经济效益分析——苜蓿草在台安县洪家农牧场种植实验

2004年台安县洪家农牧场引进加拿大优质苜蓿草进行种植实验.通过清种、林地间作和不种苜蓿草对比实验,对土壤速效氮、速效磷、速效钾、有机质、PH值、含水量进行分析,得出种植苜蓿草所产生的生态环境效益和经济效益.此项实验结论说明,紫色苜蓿是牧草之王,可促进养殖业的发展,对改善生态环境,防止土壤沙化和水土流失,改善农业结构,实现生态良性循环起到积极的促进作用,对改善生态环境起到了良好的示范作用.     

Silver impregnated carbon for adsorption and desorption of elemental mercury vapors

The Hg0 vapor adsorption experimental results on a novel sorbent obtained by impregnating a commercially available activated carbon (Darco G60 from BDH) with silver nitrate were reported. The study was performed by using a fundamental approach, in an apparatus at laboratory scale in which a synthetic flue gas, formed by Hg0 vapors in a nitrogen gas stream, at a given temperature and mercury concentration, was flowed through a fixed bed of adsorbent material. Breakthrough curves and adsorption isotherms were obtained for bed temperatures of 90, 120 and 150°C and for Hg0 concentrations in the gas varying in the range of 0.8–5.0 mg/m3. The experimental gas-solid equilibrium data were used to evaluate the Langmuir parameters and the heat of adsorption. The experimental results showed that silver impregnated carbon was very effective to capture elemental mercury and the amount of mercury adsorbed by the carbon decreased as the bed temperature increased. In addition, to evaluate the possibility of adsorbent recovery, desorption was also studied. Desorption runs showed that both the adsorbing material and the mercury could be easily recovered, since at the end of desorption the residue on solid was almost negligible. The material balance on mercury and the constitutive equations of the adsorption phenomenon were integrated, leading to the evaluation of only one kinetic parameter which fits well both the experimentally determined breakthrough and desorption curves.