铝、铁共聚作用的化学特征及晶貌研究

通过对铝，铁水解共聚物的合成制备及其水解共聚合过程电位滴定的研究，并通过扫描电镜对其共聚物样品的晶貌观测，ｎＡｌ／ｎＦｅ的点能谱及结构组成的红外光谱测定，对铝铁共聚作用的化学特征及其晶形貌象，共聚作用进行了研究及讨论，为深入研究铝无机共聚溶液体系化学形态组成及其絮凝剂的提供了的基础实验依据。     

阿舍勒块状铜锌硫化物矿床基本特征

新疆阿舍勒块状铜锌硫化物矿床在阿尔泰克兰海西褶皱带玛尔卡库里深断裂的东北侧,产于中泥盆统阿舍勒组英安岩及英安质火山碎屑岩中,与次火山岩关系密切,矿床具有明显的分带性。矿体下盘矿化和围岩蚀变强烈。认为是与海底火山作用有关的黑矿型块状铜锌硫化物矿床。     

铝盐沉淀法去除酸性矿井水中SO4^2—的试验研究

在投加铝盐条件下，钙、铝和硫酸根结合成复合物沉淀，使煤矿酸性矿井水中ＳＯ４＾２－得以去除。实验结果表明，本方法处理后出水ＳＯ４＾２－含量低于３００ｍｇ／ｌ；影响ＳＯ４＾２－去除率因素有：ｐＨ值、外加铝盐浓度及原水ＳＯ４＾２－的含量；最佳操作参数为：ｐＨ＝１０．５￣１２．０，ＳＯ４＾２－／Ａｌ＾３＋摩尔比为１．７。     

再生锌潜力巨大

据专家解释，如果锌的回收率达到消费量的30％，意味着我国每年可回收90万t锌，这将在很大程度上缓解锌资源的压力。     

锌对聚生角毛藻生长影响的研究

采用14C示踪法和细胞计数法研究了海水中锌对聚生角毛藻生长的影响,分析了EDTA、腐殖酸、水合氧化铁等介质环境及铜、锌共存下锌毒性效应的变化,讨论了藻类生长过程中各种形态锌相对含量的变化。结果表明,锌在藻类细胞内的积累与其毒性效应密切相关。     

小麦发芽期锌的毒害作用和钙的去毒害作用研究

试验表明,较高浓度的Zn~(2+)对小麦种子的发芽和α-淀粉酶的活性有抑制作用.设置了胚芽鞘长/胚芽鞘粗和主胚根长/主胚根粗两项相对生长指标,发现:随Zn~(2+)处理浓度的提高,两项指标均逐渐下降.饱和CaCO_3和0.5％CaCl_2溶液对80ppmZn~(2+)处理过的小麦幼苗的毒害具一定解毒作用.对Ca~(2+)和pH条件与种子发芽时的形态建成和α-淀粉酶活性之间的关系进行了讨论.     

Water solubility enhancements of PAHs by sodium castor oil sulfonate microemulsions

Water solubility enhancements of naphthalene( Naph), phenantherene(Phen) and pyrene(Py) in sodium castor oil sulfonate(SCOS) microemulsions were evaluated. The apparent solubilities of PAHs are linearly propertional to the concentrations of SCOS microemulsion, and the enhancement extent by SCOS solutions is greater than that by ordinary surfactants on the basis of weight solubilization ratio(WSR). ThelogKcm values of Naph, Phen, and Py are 3.13, 4.44 and 5.01 respectively, which are about the same as the logKow values. At 5000 mg/L of SCOS conccentration, the apparent solubilities are 8.80, 121, and 674 times as the intrinsic solubilities for Naph, Phen, and Py. The effects of inorganic ions and temperature on the solubilization of solutes are also investigated. The solubilization is improved with a moderate addition of Ca^2 , Na^ , NH4^ and the mixture of Na^ , K^ , Ca^2 , Mg^2 and NH4^ . WSR values are enhanced by 22.0% for Naph,23.4% for Phen, and 24.6% for Py with temperature increasing by 5~C. The results indicated that SCOS microemulsions improve the performance of the surfactant-enhanced remediation(SER) of soil, by increasing solubilities of organic pollutants and reducing the level of surfactant pollution and remediation expenses.     

混凝沉淀法处理锰锌铁氧体生产废水

锰锌铁氧体生产废水采用混凝沉淀法处理 ,悬浮物去除率可达 99.9% ,浊度去除率可达 99% ,出水水质达到国家排放标准。