基于循环特性的镍氢和锂离子电池环境影响机制分析

为了了解镍氢电池和锂离子电池在生产、使用、废弃或回收过程中的环境影响,建立了一种简单快速的二次电池环境影响机制分析方法。通过生命周期评价(LCA)方法,采用Eco-indicator99体系,综合考虑电池循环容量衰减和循环次数的影响,建立了二次电池环境影响机制分析模型,并运用此模型对两种实验用二次电池(镍氢电池和锂离子电池)的环境影响机制进行了研究。结果表明:1)在所选取的两种二次电池当中,锂离子(Li-ion)电池的环境影响明显比镍氢(Ni-MH)电池的低;2)随着循环次数的增加Li-ion电池环境影响衰减比Ni-MH电池的明显,即随着使用循环次数的增加,Li-ion电池对环境的影响会降低到更多。综合来说,所选取的Li-ion电池比Ni-MH电池更具环境可持续性。文中所提出的环境影响机制分析模型同样可以应用于其他二次电池,以期为环境友好型二次电池的开发提供帮助。     

Synthesis, characterization, and adsorption performance of Pb（Ⅱ）-imprinted polymer in nano-TiO2 matrix

Surface ion-imprinted in combination with sol-gel process was applied to synthesis a new Pb(II)-imprinted polymer for selective separation and enrichment of trace Pb(II) from aqueous solution. The prepared material was characterized by using the infrared spectra, X-ray di ractometer, and scanning electron microscopy. The batch experiments were conducted to study the optimal adsorption condition of adsorption trace Pb(II) from aqueous solutions on Pb(II)-imprinted polymer. The equilibrium was achieved in approximately 4.0 h, and the experimental kinetic data were fitted the pseudo second-order model better. The maximum adsorption capacity was 22.7 mg/g, and the Langmuir equation fitted the adsorption isotherm data. The results of selectivity experiment showed that selectively adsorbed rate of Pb(II) on Pb(II)-imprinted polymer was higher than all other studied ions. Desorption conditions of the adsorbed Pb(II) from the Pb(II)-imprinted polymer were also studied in batch experiments. The prepared Pb(II)-imprinted polymer was shown to be promising for the separation and enrichment of trace Pb(II) from water samples. The adsorption and desorption mechanisms were proposed.     

A restoration-promoting integrated floating bed and its experimental performance in eutrophication remediation

Numerous studies on eutrophication remediation have mainly focused on purifying water first, then restoring submerged macrophytes. A restoration-promoting integrated floating bed （RPIFB） was designed to combine the processes of water purification and macrophyte restoration simultaneously. Two outdoor experiments were conducted to evaluate the ecological functions of the RP1FB. Trial 1 was conducted to compare the eutrophication purification among floating bed, gradual-submerging bed （GSB） and RPIFB technologies. The results illustrated that RPIFB has the best purification capacity. Removal efficiencies of RPIFB for TN, TP,NH4＋-N, NO3-N, CODcr, Chlorophyll-a and turbidity were 74.45%, 98.31%, 74.71%, 88.81%, 71.42%, 90.17% and 85%, respectively. In trial 2, influences of depth of GSB and photic area in RPIFB on biota were investigated. When the depth of GSB decreased and the photic area of RPIFB grew, the height of Potamogeton crispus Linn. increased, but the biomass of Canna indica Linn. was reduced. The mortalities of Misgurnus anguillicaudatus and Bellamya aeruginosa in each group were all less than 7%. All results indicated that when the RPIFB was embedded into the eutrophic water, the regime shift from phytoplankton-dominated to macrophyte-dominated state could be promoted. Thus, the RPIFB is a promising remediation technology for eutrophication and submerged macrophyte restoration.     

微波及其组合工艺强化污泥厌氧消化研究

为提高剩余污泥的厌氧消化效能和脱水性能,考察了微波及其组合污泥预处理工艺的强化污泥厌氧消化效果,同时考察了预处理-厌氧消化过程的污泥理化特征及其脱水性能.结果表明,微波及其组合工艺可以强化污泥厌氧消化产甲烷,其中微波-过氧化氢-碱(0.2)的强化效果最为显著,不仅30 d累计产甲烷量比对照组增加了13.34%,而且产甲烷速率也得到了提升.与单独微波处理相比,过氧化氢、碱的投加显著提高了溶解性COD的释放量,这表明微波、过氧化氢、碱之间的协同作用能有效破碎污泥,进而强化厌氧消化效果;微波-酸预处理后的污泥具有良好的脱水性能,毛细吸水时间(CST)只有9.85 s,污泥脱水性能的改善与其表面电性、粒径分布的变化密切相关;不同预处理条件下的污泥经过厌氧消化后,污泥脱水性能较为接近.     

斯特林发动机性能模拟研究

斯特林发动机作为当今社会能源问题主要话题之一,如何高效的其利用能源,成为其研究的主要目的。本文根据斯特林分析法,模拟研究了某型斯特林发动机的参数性能,为以后斯特林发动机的研发及实验提供参考。     

地裂缝上框架结构的抗震性能分析

地裂缝是严重影响我国人类生活、生产建设的主要地质灾害之一,是一种独特的地质灾害,近年来已引起人们的关注,它广泛分布于全国许多地方。框架结构是一种广泛使用的结构形式。由于人类活动或地质构造运动形成地裂缝,进而造成房屋开裂或倾斜。该文针对位于抗震设防区的框架结构房屋,分别用底部剪力法和PKPM静力分析法,来定量研究在地裂缝影响下框架结构的抗震性能,为双重灾害影响下结构抗震鉴定加固提供依据。     

智利经验对中国的启示:高质量建筑减少地震伤亡

2月27日,智利发生里氏8.8级地震,其释放的能量是海地1月发生的7级地震的501倍,但幸运的是,智利的死亡人数却相对不多。据海地政府估计,有22万人死于地震。但是智利政府3月2日公布的数据显示,智利的死亡人数是795人。为什么会出现智利地震震级更高、而破坏程度却低于海地地震的现象?专家分析,一方面是因为智利震中周围地区人口稀少,而海地震中靠近人口稠密区。此外,建筑的较高质量也是原因之一。     

袋式除尘器和静电除尘器在电厂除尘系统中运用的性能对比分析

针对目前火电厂除尘系统应用现状和当前环保要求,通过对袋式除尘器和静电除尘器在火电厂燃煤锅炉除尘系统中的应用,对袋式除尘器和静电除尘器在技术性能上的差异作了简单的对比分析,以指导除尘器在目前火电厂燃煤锅炉除尘系统中的具体应用。     

呼吸器官防护用品系列——供气式呼吸器的选购

从2010年第1期开始,我刊开设"个体防护"栏目。通过对个体防护用品进行科学的质量性能比较,为读者提供科学的选择、使用、保管方案。本期我们介绍呼吸器官防护用品的相关知识。     

新型汽车空调制冷剂CMR-O2与R12、R134a性能比较

介绍一种新型制冷剂CMR-02。为分析其应用于汽车空调的可行性,比较了CMR-02与R134a和R12三种制冷剂在热工性能、环境性能、安全性与共沸性等方面的优劣,并比较了CMR-02和R134a的压缩机性能,发现CMR-02的单位质量制冷量增加显著(68.10%),单位容积制冷量增加14.38%,符合环保要求,且成本低廉,可以作为R12的一种较好的过渡性替代物。