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排序方式: 共有9752条查询结果,搜索用时 234 毫秒
111.
CHANG Guo-hua CHEN Hao CHEN Hai-liu LI Wei PAN Gang State Key Laboratory of Environmemal Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing China. 《环境科学学报(英文版)》2007,19(9):1028-1031
Toxic effect of Zn(Ⅱ)on a green alga(ChloreUa pyrenoidosa)in the presence of sepiolite and kaolinite was investigated.The Zn-free clays were found to have a negative impact on the growth of C.pyrenoidosa in comparison with control samples(without adding any clay or Zn(Ⅱ)).When Zn(Ⅱ)was added,the algae in the presence of clays could be better survived than the control samples,which was actually caused by a decrease in Zn(Ⅱ)concentration in the solution owing to the adsorption of Zn(Ⅱ)on the clays.When the solution system was diluted,the growth of algae could be further inhibited as compared to that in a system which had the same initial Zn(Ⅱ)concentration as in the diluted system.This in fact resulted from desorption of Zn(Ⅱ)from the zinc-contaminated clays,although the effect varied according to the different desorption capabilities of sepiolite and kaolinite.Therefore the adsorption and desorption processes of Zn(Ⅱ)played an important part in its toxicity,and adsorption and desorption of pollutants on soils/sediments should be well considered in natural eco-environmental systems before their risk of toxicity to aquatic organisms was assessed objectively. 相似文献
112.
《环境科学学报(英文版)》2023,35(4):387-395
This study examined the effectiveness for degradation of hydrophobic (HPO), transphilic (TPI) and hydrophilic (HPI) fractions of natural organic matter (NOM) during UV/H2O2, UV/TiO2 and UV/K2S2O8 (UV/PS) advanced oxidation processes (AOPs). The changing characteristics of NOM were evaluated by dissolved organic carbon (DOC), the specific UV absorbance (SUVA), trihalomethanes formation potential (THMFP), organic halogen adsorbable on activated carbon formation potential (AOXFP) and parallel factor analysis of excitation–emission matrices (PARAFAC-EEMs). In the three UV-based AOPs, HPI fraction with low molecular weight and aromaticity was more likely to degradate than HPO and TPI, and the removal efficiency of SUVA for HPO was much higher than TPI and HPI fraction. In terms of the specific THMFP of HPO, TPI and HPI, a reduction was achieved in the UV/H2O2 process, and the higest removal rate even reached to 83%. UV/TiO2 and UV/PS processes can only decrease the specific THMFP of HPI. The specific AOXFP of HPO, TPI and HPI fractions were all able to be degraded by the three UV-based AOPs, and HPO content is more susceptible to decompose than TPI and HPI content. UV/H2O2 was found to be the most effective treatment for the removal of THMFP and AOXFP under given conditions. C1 (microbial or marine derived humic-like substances), C2 (terrestrially derived humic-like substances) and C3 (tryptophan-like proteins) fluorescent components of HPO fraction were fairly labile across the UV-based AOPs treatment. C3 of each fraction of NOM was the most resistant to degrade upon the UV-based AOPs. Results from this study may provide the prediction about the consequence of UV-based AOPs for the degradation of different fractions of NOM with varied characteristics. 相似文献
113.
土壤有机碳是控制土壤中多环芳烃的吸附解吸及其生物有效性的主要因素之一,土壤中硬碳类吸附剂是土壤有机碳中的重要部分,土壤中软碳类物质和硬碳类物质的相互作用对研究土壤中多环芳烃的解吸行为和生物有效性有重要影响。研究将溶解有机质胡敏酸,通过条件的变化使其转变为非溶解态,研究其对土壤碳质吸附剂(胡敏素和黑碳)吸附多环芳烃的解吸行为的影响。研究结果表明:非溶解态胡敏酸会显著降低土壤硬碳类物质中多环芳烃的解吸能力,解吸滞后性增加,作者认为非溶解态胡敏酸的添加会覆盖土壤硬碳类物质的表面吸附位点和填充吸附多环芳烃的孔隙,造成硬碳类有机质中的多环芳烃解吸能力下降,滞后性增强。研究还发现硬碳类有机质的比表面积和孔隙度和解吸能力的变化强度呈正相关关系。 相似文献
114.
Yan Xu Danyi Zhang Qingju Xue Chibin Bu Yajun Wang Benchi Zhang Ying Wang Qingdong Qin 《环境科学学报(英文版)》2023,35(4):1-16
To understand the long-term performance of bioretention systems under sulfamethoxazole (SMX) stress, an unplanted bioretention system (BRS) and two modified BRSs with coconut-shell activated carbon (CAC) and CAC/zero-valent-iron (Fe0) granules (CAC-BRS and Fe/CAC-BRS) were established. Both CAC-BRS and Fe/CAC-BRS significantly outperformed BRS in removing total nitrogen (TN)(CAC-BRS:82.48%; Fe/CAC-BRS:78.08%; BRS:47.51%), total phosphorous (TP)(CAC-BRS:79.36%; Fe/CAC-BRS:98.26%; BRS:41.99%),and... 相似文献
115.
采用粒径<200μm、在酸碱介质中溶胀率小且能稳定存在的壳聚糖/PVA微粒对Cu2+的吸附进行了研究,结果表明,在pH 6,室温条件下,其饱合吸附量达56.0mg/g,随温度升高,吸附量降低.通过计算不同温度下各热力学参数△G0、△H0和△S0,证实该吸附为自发的放热过程.对实验数据运用相关数学模型拟合,显示等温吸附平衡符合Langmuir模型,吸附过程动力学更适合二级反应,被吸附在壳聚糖/PVA微粒上的Cu2+,可被0.01mo/L的EDTS或HNO3溶液快速地脱附出来,其洗脱率分别为85.3%和65.9%. 相似文献
116.
二叠纪—三叠纪之交的环境恶化事件不但导致了生物大绝灭,而且造成了自然界正常的碳循环崩溃。为了研究三叠纪早期生物复苏过程中的环境特征、碳氧同位素演化上的地层学意义,对巢湖平顶山西坡剖面下三叠统碳酸盐岩取样分析。研究结果表明,巢湖平顶山西坡剖面早三叠世碳氧同位素地层曲线与已知的平顶山北坡剖面碳氧同位素地层曲线相似。δ13C值在Induan阶、Olenekian阶底部首先表现为大幅度负漂,随后呈上升趋势。δ18O值除了表现出1Ma的周期性波动之外,与δ13C低值区对应处也具负偏趋势。δ13C、δ18O值的演化趋势反映了早三叠世海洋环境恶化、生物复苏十分缓慢。 相似文献
117.
IntroductionAdsorptionofherbicidesonsoilfromwaterisanimportantfactoraffectingtheirfate,biologicalactivity,andpersistenceinsoil watersystem .Itisoftenaffectedbyseveralpropertiesofsoil.Betterunderstandingofadsorptionanditsaffectingfactorswillmakeitpossibletoadjusttheherbicidedosageaccordingtosoilproperties,thusreducingtheenvironmentalpollutionofherbicidesintheenvironment.Fig .1 StructuresofthreetriazineherbicidesAmongthepost emergentherbicides,triazineherbicidesaremostcommonlyusedworldwideonco… 相似文献
118.
119.
PW—W膜分离式活性污泥法处理中小规模高浓度有机废水 总被引:3,自引:0,他引:3
阐述PW-W膜分离式活性污泥法处理高浓度有机废水的原理、工艺流程及特点。处理系统集生化处理功能和固液分离于一体,对高浓度有机废水的处理取得了良好的效果,且剩余污泥量少,处理水质稳定,维护管理方便,运行费用低。 相似文献
120.