Storage stability of biocrude oils from fast pyrolysis of poultry litter

The unstable nature of biocrude oils produced from conventional pyrolysis of biomass is one of the properties that limits its application. In the disposal of poultry litter via pyrolysis technology, the biocrude oil produced as a value-added product can be used for on farm applications. In this study, we investigated the influence of bedding material (wood shavings) on the storage stability of biocrude oils produced from the fast pyrolysis of poultry litter. The biocrude oils produced from manure, wood (pine and oak), and mixtures of manure and wood in proportions (75:25 50:50, and 25:75 w/w%) were stored under ambient conditions in sealed glass vials for a period of 6 months and their stability were monitored by measuring the changes in viscosity over time. The manure oil had the lowest rate of viscosity change and thus was relatively the most stable and the oils from the 50:50 w/w% litter mixtures were the least stable. The rate of viscosity change of the manure biocrude oil was 1.33 cP/day and that of the 50/50 litter mixture was 7.6 cP/day for pine and 4.17 cP/day for oak.The spectrometric analyses of the biocrude oils showed that the presence of highly reactive oxygenated functionalities in the oil were responsible for the instability characteristic of the litter biocrude oils. The poor stability of the biocrude oil from the 50:50 w/w% litter mixtures was attributed to reactions between nitrogenous compounds (amides) from protein degradation and oxygenated compounds from the decomposition of polysaccharides and lignin. The addition of 10% methanol and 10% ethanol to the oil from 50% manure and 50% pine reduced the initial viscosity of the oil and was also beneficial in slowing down the rate of viscosity change during storage.     

细旦涤纶的氧等离子体改性清洁工艺研究

采用氧低温等离子体技术对细旦涤纶进行改性以提高其染色上染率，并探讨了氧等离子体放电时间、放电气压和放电功率对细旦涤纶各项性能的影响规律。     

Performance of Pultruded Jute Fibre Reinforced Phenolic Composites as Building Materials for Door Frame

The pultruded jute/phenolic composites were aged under various humidity, hydrothermal and weathering conditions. Aging-induced effect of these conditions on the jute profiles was studied in terms of their physico-mechanical properties. It is observed that dimensional change of the profiles was only upto 4% even in an accelerated water aging condition. The effect of absorbed moisture/water on the jute profile was more pronounced in an accelerated water aging than the samples are being exposed to high humidity and alternate wetting and drying cycles. The changes in the values of internal bond strength of the profiles could be used as an indicator because of its sensitivity towards aging. Accentuation of fibres on the weathered samples along with severe resin erosion has suggested to layer the surface of the profiles with rich resin prior to use in the outdoor. The properties of jute profile door frame were satisfactory when compared with the requirements mentioned in IS: 4021–83 – Indian standard specification for timber door, window and ventilator frames. Performance of the installed door frame has shown no sign of dimensional instability in terms of warping and bulging after 3 years. It is suggested that jute door frames could be used as an alternative to the wooden door frames in buildings.     

Distinct potential aerosol masses under different scenarios of transport at a suburban site of Beijing

In order to evaluate the secondary aerosol formation potential at a suburban site of Beijing,in situ perturbation experiments in a potential aerosol mass(PAM) reactor were carried out in the winter of 2014.The variations of secondary aerosol formation as a function of time,OH exposure,and the concentrations of gas phase pollutants and particles were reported in this study.Two periods with distinct secondary aerosol formation potentials,marked as Period Ⅰ and Period Ⅱ,were identified during the observation.In Period Ⅰ,the secondary aerosol formation potential was high,and correlated well to the air pollutants,i.e.,SO_2,NO_2,and CO.The maximal secondary aerosol formation was observed with an aging time equivalent to about 3 days of atmospheric oxidation.In period Ⅱ,the secondary aerosol formation potential was low,with no obvious correlation with the air pollutants.Meanwhile,the aerosol mass decreased,instead of showing a peak,with increasing aging time.Backward trajectory analysis during the two periods confirmed that the air mass in Period Ⅰwas mainly from local sources,while it was attributed mostly to long distance transport in Period Ⅱ.The air lost its reactivity during the long transport and the particles became highly aged,resulting in a low secondary aerosol formation potential.Our experimental results indicated that the in situ measurement of the secondary aerosol formation potential could provide important information for evaluating the contributions of local emission and long distance transport to the aerosol pollution.     

Stress,burnout and diminished safety behaviors: An argument for Total Worker Health® approaches in the fire service

Introduction: Firefighting is stressful work, which can result in burnout. Burnout is a safety concern as it can negatively impact safety outcomes. These impacts are not fully understood within the fire service. Further, the fire service needs support that safety strategies are needed to protect and promote the health and wellbeing of firefighters. Methods: Structural equation modeling was completed to examine a hypothesized model that linked stress and burnout to diminished safety behavior outcomes among a sample of career firefighters. Results: Findings support a full mediation model. Firefighter stress perceptions were positively associated with burnout and burnout was negatively associated with safety compliance behavior, personal protective equipment behavior, safe work practices, and safety citizenship behavior. Conclusions: These results illustrate the negative impact of health impairment on firefighter safety behaviors. Practical Applications: These outcomes suggest that interventions aimed at protecting and promotion firefighter health are needed. Total Worker Health® (TWH) approaches may provide the framework for these interventions.     

Soil sterilization affects aging-related sequestration and bioavailability of p,p′-DDE and anthracene to earthworms

Laboratory experiments investigated the effects of soil sterilization and compound aging on the bioaccumulation of spiked p,p′-DDE and anthracene by Eisenia fetida and Lumbricus terrestris. Declines in bioavailability occurred as pollutant residence time in both sterile and non-sterile soils increased from 3 to 203 d. Accumulation was generally higher in sterile soils during initial periods of aging (from 3-103 d). By 203 d, however, bioavailability of the compounds was unaffected by sterilization. Gamma irradiation and autoclaving may have altered bioavailability by inducing changes in the chemistry of soil organic matter (SOM). The results support a dual-mode partitioning sorption model in which the SOM components associated with short-term sorption (the ‘soft’ or ‘rubbery’ phases) are more affected than are the components associated with long-term sorption (the ‘glassy’ or microcrystalline phases). Risk assessments based on data from experiments in which sterile soil was used could overestimate exposure and bioaccumulation of pollutants.     

Health and Safety Perception of Workers in Turkey: A Survey of Construction Sites

This study reports the general health and safety (HS) conditions in the Turkish construction industry from the perspective of construction labor. Toward this aim, a questionnaire survey was carried out with 800 workers employed in 32 construction projects in Turkey. Contractors were found to neglect their legal liabilities in paying workers’ insurance premiums. Also, they overlooked safety training and were reluctant to hiring physicians at construction sites and investing in personal protective equipment (PPE). As the real constructors of projects, workers did not attach adequate importance to occupational training. In addition, they were not willing to use some PPE. Key participants of HS affairs such as workers, contractors, unions, and government should comprehend their drawbacks to overcome the current dangerous view of the industry. In this regard, related government bodies should compel contractors and workers to adapt to the relatively new regulations on occupational HS.     

Cardiovascular Strain of Sawmill Workers in South-Western Nigeria

This study aimed to assess cardiovascular strain during sawmilling operations in terms of physical workload, based on heart rate changes. We measured resting and working heart rates and calculated cardiovascular load (%CVL), cardiovascular strain (%CVS) and relative heart rate (%RHR) in 35 sawmill workers. Based on heart rate only, the work in sawmills was classified as very heavy and extremely heavy. Similarly, a high-level category was recorded for %CVL and a very high range for %CVS. Thus, the workload in sawmill operations is usually very high and can lead to physiological strain of the workers. There is a need to redesign the work content of this occupation to prevent excessive strain in the workers, as this will increase their productivity and reduce their health risk.     

Percutaneous Exposure Incidents Among Australian Hospital Staff

We investigated all reported percutaneous exposure incidents (PEI) among staff from a large Australian hospital in the 3-year period, 2001-2003. There were a total of 373 PEI, of which 38.9% were needlestick injuries, 32.7% were cutaneous exposures and 28.4% sharps-related injuries. Nurses were the most commonly affected staff members, accounting for 63.5% of the total, followed by doctors (18.8%) and other staff ( 17.7%). Needlestick injuries were responsible for the majority of nurses’ PEI (44.7%). Sharps injuries constituted the major category for doctors (44.3%). Most needlestick injuries (67.6%) were caused by hollow-bore needles, while the majority of cutaneous exposures involved blood or serum (55.8%). Most sharps injures were caused by unknown devices (35.9%) or suture needles (34.9%). Overall, our investigation suggests that PEI is a considerable burden for health care workers in Australia. Further research is now required to determine the relationships, if any, between workers who suffer PEI and those who do not.     

基于场动力理论的建筑工人人格特质、情绪与不安全行为关系研究*

为深入探讨建筑工人人格特质、情绪与不安全行为之间的作用关系,提高建筑工人安全认知能力,以293名一线建筑工人为调查对象,基于场动力理论,构建人格特质和情绪对不安全行为影响机制的理论模型,实证检验人格特质和情绪对不安全行为的预测作用以及情绪调节效应。研究结果表明:外倾性、神经质、开放性3种人格正向预测不安全行为显著;正负性情绪对不安全行为水平具有显著影响,正性情绪在外倾性-不安全行为和神经质-不安全行为间具有显著调节效应,负性情绪在责任心-不安全行为和开放性-不安全行为间具有显著调节效应。研究结果可为建筑施工企业根据工人个性化心理特征,溯源工人自身安全问题,为后续开展分类干预管理和矫正不安全行为提供理论支持。