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71.
Influence of pyrene combination state in soils on its treatment efficiency by Fenton oxidation 总被引:1,自引:0,他引:1
Interactions of hydrophobic organic compounds (HOCs) with soil organic matter (SOM) determine their combination state in soils, and therefore strongly influence their mobility, bioavailability, and chemical reactivity. Contact time (aging) of an HOC in soil also strongly influences its combination state and environmental fate. We studied Fenton oxidation of pyrene in three different soils to reveal the influences of SOM, contact time, and combination state on the efficiency of vigorous chemical reactions. Pyrene degradation efficiency depended strongly on the dose of oxidant (H(2)O(2)) and catalyst (Fe(2+)); the greatest degradation was achieved at an oxidant to catalyst molar ratio of 10:1. Pyrene degradation differed among the three soils, ranging from 65.4% to 88.9%. Pyrene degradation efficiency decreased with increasing SOM content, and the aromatic carbon content in SOM was the key parameter. We hypothesize that pyrene molecules that combine with the compact net structure of aromatic SOM are less accessible to Fenton oxidation. Furthermore, pyrene degradation efficiency decreased considerably after aged for 30 days, but further aging to 60 and 180 days did not significantly change degradation efficiency. The Fenton oxidation efficiency of pyrene in both unaged and aged soils was greater than the corresponding desorption rate during the same period, perhaps because Fenton reaction can make pyrene more accessible to the oxidant through the enhancement of HOCs' desorption by generating reductant species or by destroying SOM through oxidation. 相似文献
72.
Qianni Zhou Chunlei Cheng Suxia Yang Minghao Yuan Jingjing Meng Haifeng Gong Qien Zhong Yao Zhang Yutong Xie Zhen Zhou Mei Li 《环境科学学报(英文版)》2022,34(1):185-196
Black carbon(BC) plays an important role in air quality and climate change, which is closely associated with its mixing state and chemical compositions. In this work the mixing state of BC-containing single particles was investigated to explore the evolution process of ambient BC particles using a single particle aerosol mass spectrometer(SPAMS) in March 2018 in Zhengzhou, China. The BC-containing particles accounted for 61.4% of total detected ambient single particles and were classified into f... 相似文献
73.
When mobility makes sense: A qualitative and longitudinal study of the daily mobility of the elderly 总被引:1,自引:0,他引:1
Sébastien Lord Carole Després Thierry Ramadier 《Journal of environmental psychology》2011,31(1):52-61
A majority of North Americans hopes to grow old in the suburbs. This aspiration depends upon their ability to drive and their access to a car. Because it is essential for everyday travel, car-mobility in the suburbs is becoming a symbolic goal. The meanings of mobility for elderly will evolve over time, notably as a result of changes in autonomy. However, the mobility of older adults is mainly understood in terms of daily trips. Little research has considered the temporal dimension of aging as an evolving process. This study aimed at understanding with a qualitative and longitudinal perspective how older people stay (auto-)mobile in their house and their neighborhood against the need to adapt to reduced autonomy and mobility over time. A group of 22 suburbanites aged from 62 to 89 was interviewed in 1999 and in 2006. The results show that even if older people succeed in increasing their mobility, they are headed for inevitable immobility. Among the environmental adaptation strategies that were observed, the constructed behaviors, the dependencies demanding additional supports as well as the social life modulate different evolving experiences of the city: the shrinking city, the fragmented city, and the city by proxy. The built environment is at the heart of a complex process in which the adaptation of mobility contributes to the emergence of new residential experiences. 相似文献
74.
为加强对工人不安全行为的管理,保障建筑施工安全,利用结构方程模型(SEM)建模方法研究建筑工人个体安全能力与影响因素间的效用关系。从个体特质和工作环境2方面进行分析,得到技能素质、心理状态、生理状态等16个影响因素。以工作环境的8个影响因素作为外源潜伏变量,其余8个影响因素作为内生潜伏变量,构建建筑工人个体安全能力SEM。利用问卷调查所得数据对模型进行拟合与修正,实现影响因素效用的客观量化。研究结果表明:建筑工人的个体安全能力主要取决于其技能素质;工作环境中,效用最大的因素是施工现场的安全资源配备;当前建筑行业的安全培训与安全文化建设工作还有待进一步开展。 相似文献
75.
唱斗 《中国个体防护装备》2011,(5):18-19
本文主要介绍了职业应激的概念,以及高温、噪声、辐射、压力这些应激原给炼钢工人健康带来的影响,并提出了预防措施。 相似文献
76.
Osnat Malka Shiri Shnieor Abraham Hefetz Tamar Katzav-Gozansky 《Behavioral ecology and sociobiology》2007,61(3):465-473
In most social insects, worker sterility is reversible, and in the absence of the queen, at least some workers develop ovaries and lay male-destined eggs. In the honeybee, reproductive workers also produce queen-characteristic mandibular and Dufour’s pheromones. The evolution of worker sterility is still under debate as to whether it is caused by queen manipulation (queen-control hypothesis) or represents worker fitness maximization (worker-control hypothesis). In this study, we investigated whether worker fertility and royal pheromone production are reversible under the queen influence. To that effect, we induced ovary activation and queen pheromone production in workers by rearing them as queenless (QL) groups. These workers were subsequently reintroduced into queenright (QR) microcolonies for 1 week, and their ovary status and queen pheromone levels were monitored. Workers reintroduced into QR, but not QL colonies, showed a clear regression in ovary development and levels of the queen pheromones. This is the first demonstration that worker sterility and/or fertility is reversible and is influenced by the queen. These results also emphasize the robustness of the coupling between ovary activation and royal pheromone production, as well as lending credence to the queen-control hypothesis. The dynamics of queen pheromone production in QL workers supports the role of Dufour’s gland pheromone as a fertility signal and that of the mandibular gland pheromone in dominance hierarchies.The two authors, Osnat Malka and Shiri Shnieor, contributed equally to this work. 相似文献
77.
Katrin Strauss Holger Scharpenberg Robin M. Crewe Felix Glahn Heidi Foth Robin F. A. Moritz 《Behavioral ecology and sociobiology》2008,62(9):1523-1531
Queen pheromones interfere with worker reproduction in social insects. However, there is still an unresolved question as to
whether this pheromone acts as an “honest” signal for workers, giving a reliable indication of the queen’s reproductive value,
or as a suppressive agent, inhibiting worker reproduction independent of the queen’s reproductive capacity. In honeybees (Apis mellifera), the queen’s mandibular gland secretion, a mix of fatty acids and some aromatic compounds, is crucial for regulating the
reproductive division of labor in the colony inhibiting ovary development in workers. We quantified the mandibular gland secretions
of virgin, drone-laying, and naturally mated queens using gas chromatography to test whether the queens’ mating, ovary activation,
or the reproductive value for workers correlated with the composition of the secretion. Although the absolute amounts of the
“queen substance” 9-oxo-2(E)-decenoic acid (9-ODA) were similar among the three groups, the proportions of 9-ODA decreased
with increasing reproductive quality. Furthermore, the ratios of queen to worker compounds were similar in all three treatment
groups, irrespective of the reproductive capacity. A multivariate analysis including all six compounds could not separate
drone-laying queens from naturally mated ones, both with active ovaries but only the latter ensuring colony survival. We suggest
that the mandibular gland pheromones are unlikely to function as reliable indicators of queen reproductive value and rather
operate as an agent to suppress worker reproduction. This does not exclude the possibility that other “honest” pheromone signals
exist in the honeybee colony, but these would have to arise from other semiochemicals, which could be produced by both the
queen and the brood. 相似文献
78.
Gunnela Westlander Birgit Pingel 《International journal of occupational safety and ergonomics》2013,19(1-2):59-76
The study reports the results of a follow-up evaluation, conducted in 1994, of the impact of a training program for female unskilled metal workers that was implemented at the end of the 1970s. The program was designed to promote occupational skills development, and was first evaluated in 1979. On both occasions of evaluation the investment in training was examined from two perspectives, those of the training participants and management. Data were collected through semistructured personal interviews with key members of personnel management and through a group conversation session with a majority of the original course attendees. Supplementary background information was obtained from documents and records maintained by the organization. At some points, there was a convergence of views on the significance of the training program for occupational skills development, at others a divergence. These convergences and divergences are finally discussed and the findings of the study are related to other research on this particular kind of intervention. 相似文献
79.
Lesch MF 《Journal of Safety Research》2003,34(5):495-505
Problem: Prior research indicates that many warning symbols are poorly understood, particularly by the elderly. Method: The effectiveness of three different training conditions to improve comprehension and memory for warning symbols was assessed for younger (18–35 years of age) and older (50–67 years of age) participants. All three conditions paired the symbols with associated text during training; however they differed in the extent to which they further elaborated on the meanings of the symbols. Results: Training substantially improved accuracy and speed of responding on a comprehension test; however there was little difference among conditions. Additionally, while the magnitude of the training effect was similar for both age groups, older participants performed much more poorly than younger participants, both before (37% vs. 52% correct) and after training (68% vs. 88% correct on the immediate post-test), and found it more difficult to reject incorrect meanings (55% vs. 68% correct). Conclusion: Relatively simple training conditions can dramatically improve accuracy and speed of responding to warning symbols. Impact on industry: Training should be used to improve warning symbol comprehension since failures to adequately understand warning information may lead to injury or death. Furthermore, attempts should be made to address individual differences in warning processing such as those related to changes in cognitive processing across the lifespan. 相似文献
80.
INTRODUCTION: Many injury prevention interventions require changes in human behavior to reduce self-risk or risk to others. Promising injury prevention interventions may be discarded if they lack power to create a significant difference in outcomes when judging their ability to "move a person from nonaction or negative action to positive action (safety)." The transtheoretical model of change (TMC) allows greater sensitivity in detecting along the change process where an intervention may be effective. The stages of change consist of precontemplation, contemplation, preparation, action, maintenance, and termination. Change is not viewed as an "all or none phenomenon." METHOD: Use of the TMC was examined using a quasiexperimental, cross-over design involving high school agriculture students enrolled in 21 schools in Kentucky (n=9), Iowa (n=7), and Mississippi (n=5). A series of physical and narrative simulations (safety training exercises) were developed with a focus on preventing amputation, spinal cord injury, hypersensitivity pneumonitis, and noise-induced hearing loss. Contemplation and action, as part of the TMC, were measured using a 10-item, Likert-type, stages of change (SOC) instrument comprised of two subscales (reliability coefficients were.88 and.81, respectively). The final sample consisted of 790 students (373 treatment and 417 control). RESULTS: There was a significant group effect for both contemplation, F(1,732)=197.4; p<.0001, and action, F(1,730)=106.1; p<.0001. A convenience sample of 29 of the participating students was selected for follow-up farm visits 1 year postparticipation. Of these students, 25 (86%) had made safety behavior changes in their farm work. IMPACT ON INDUSTRY: The use of the TMC model can provide researchers with greater precision in examining intervention effectiveness in promoting change. 相似文献